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1.7 Application of microwave in organic synthesis
Following reactions have been performed through microwave heating.
Sr. Reaction Ref. Sr Reaction Ref.
1 Acetylation reaction 27 18 Diel’s-Alder reaction 44
2 Addition reaction 28 19 Dimerization reaction 45
3 Alkylation reaction 29 20 Elimination reaction 28
4 Alkynes metathesis 30 21 Estrification reaction 46
5 Allylation reaction 31 22 Enantioselective reaction 47
6 Amination reaction 32 23 Halogenation reaction 48
7
Aromatic nucleophillic
substitution reaction
33 24 Hydrolysis reaction 59
8 Arylation reaction 34 25 Mannich reaction 50
9 Carbonylation reaction 35 26 Oxidation reaction 51
10 Combinatorial reaction 36 27 Phosphorylation synthesis 52
11 Condensation reaction 37 28 Polymerization reaction 53
12 Coupling reaction 38 29 Rearrangement reaction 54
13 Cyanation reaction 39 30 Reduction reaction 55
14 Cyclization reaction 40 31 Ring closing synthesis 56
15 Cyclo-addition reaction 41 32 Solvent free reaction 57
16 Deacetylation reaction 42 33 Transestrification reaction 46
17 Dehalogenation reaction 43 34 Transformation reaction 58
Figure 1.2: General View of Monomode CEM Discover (left) and Multimode
MILESTONE Start (right) Systems