Download (8Mb) - Etheses - Saurashtra University

Yield: 84 %. 1 H NMR (300 MHz, DMSO-d6): δ = 10.68 (br s, 1H), 8.57 (s, 1H), 7.82
(d, J = 7.3 Hz, 2H), 7.61 (m, 2H), 7.43 (t, J = 7.6 Hz, 2H), 7.28 (m, 3H), 7.06 (m,
2H), 6.01 (br s, 1H), 4.63 (t, J = 6.1 Hz, 2H), 3.70 (m, 2H). 13 C NMR (75.5 MHz,
DMSO-d6): δ = 150.3, 146.1, 130.4, 128.8 (×4), 128.2, 127.7, 125.1, 125.0 (×4),
123.4, 121.7, 104.1, 49.3. 42.9. HRMS (EI) C19H18N6, calcd 330.1593, found :
330.1582.
5-(4-Bromophenyl)-N-(2-(4-p-tolyl-1H-1,2,3-triazol-1-yl)ethyl)-1H-imidazol-2amine
(BS-231)
Br
N
H
N
N
H
N
N
N
Yield: 73 %. 1 H NMR (300 MHz, DMSO-d6): δ = 10.66 (br s, 1H), 8.50 (s, 1H), 7.70
(d, J = 8.07 Hz, 2H), 7.57 (d, J = 8.31 Hz, 2H), 7.43 (d, J = 8.56 Hz, 2H), 7.22 (d, J =
8.07 Hz, 2H), 7.13 (s, 1H), 6.03 (br s, 1H), 4.61 (t, J = 5.80 Hz, 2H), 3.68 (m, 2H),
2.32 (s, 3H). 13 C NMR (75.5 MHz, DMSO-d6): δ = 150.4, 146.1, 136.9 (×2), 130.9
(×2), 129.3 (×4), 128.0, 125.3, 124.9 (×3), 121.2, 117.4, 49.2, 42,8, 20.7. HRMS (EI)
C20H19BrN6, calcd 422.0855, found : 422.0863.
N-(2-(4-(4-Butylphenyl)-1H-1,2,3-triazol-1-yl)ethyl)-5-(naphthalen-1-yl)-1Himidazol-2-amine
(BS-275)
N
H
N
N
H
N
N
N
C4H9 Yield: 64 %. 1 H NMR (300 MHz, DMSO-d6): δ = 10.9 (br s, 1H), 8.54 (s, 1H), 8.14
(s, 1H), 7.73 (m, 6H), 7.37 (m, 2H), 7.23 (m, 3H), 6.01 (m, 1H), 4.68 (m, 2H), 3.74
(m, 2H), 2.58 (t, J = 7.4 Hz, 2H), 1.56 (m, 2H), 1.32 (m, 2H), 0.89 (t, J = 7.4 Hz, 3H).
13
C NMR (75.5 MHz, DMSO-d6): δ = 150.7, 146.2, 141.8, 133.5, 131.3, 128.7 (×3),
128.3, 127.5, 127.3 (×3), 126.0, 125.0 (×3), 124.6, 123.2, 121.3, 120.2, 49.3, 42.9,
34.5, 32.9, 21.7, 13.7. HRMS (EI) C27H28N6, calcd 436.2375, found : 436. 2349.