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Mihailova

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Our general goals<br />

Raman scattering and X-ray ray diffraction on single crystals<br />

PbSc0.5Ta0.5O3 (PST)<br />

and<br />

PbSc0.5Nb0.5O3 (PSN)<br />

A-site-doped PST and PSN,<br />

substitution of Ba 2+ , La 3+ , Bi 3+ for Pb 2+<br />

Nb-doped PST, substitution of Nb 5+ for Ta 5+<br />

High-pressure<br />

High pressure studies on relaxors of type PbB’ 0.5B” 0.5O3 :<br />

- atomic clustering under pressure<br />

- pressure-induced phase transitions<br />

AB’ 1/2 B” 1/2 O 3<br />

AB’ 1/3 B” 2/3 O 3<br />

- changes in the compression behaviour upon doping

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