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the coking properties of coal at elevated pressures. - Argonne ...

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all <strong>the</strong> initial values <strong>of</strong> x for which xt > 0. Suppose an initial diameter y is<br />

defined so th<strong>at</strong> all particles with an initial diameter x < yo would have buzed<br />

away completely after a time t, <strong>the</strong>n <strong>the</strong> mass fraction <strong>of</strong> carbon in <strong>the</strong> bed <strong>at</strong><br />

this time t is<br />

m<br />

m. - =<br />

x=x,<br />

x= z<br />

' $ $(x)dx<br />

where z = x1 if yO&xl<br />

and z = y if yo>xl<br />

X<br />

By substituting y in equ<strong>at</strong>ion 6) we have<br />

t<br />

f 2<br />

F(C)dt = eyo + - y<br />

i 2 0<br />

0<br />

Combining equ<strong>at</strong>ions 6), 8) and 10) gives<br />

x= z<br />

Burnout time<br />

To derive an expression for <strong>the</strong> burn-out time we need to investig<strong>at</strong>e<br />

dm/dt or d(m/mi)/dt. From an oxygen balance on <strong>the</strong> bed (7) we have<br />

3<br />

where C is <strong>the</strong> inlet oxygen concentr<strong>at</strong>ion (mole/m ).<br />

dm/dt<br />

Therefore C = Co + -<br />

P F(Uo)<br />

.J<br />

X<br />

where F(Uo) = 12A[Uo -(Uo-Umf) (exp(-B)) 3<br />

It can <strong>the</strong>refore be shown th<strong>at</strong><br />

Also, from equ<strong>at</strong>ion 13)<br />

r 1<br />

dm/dyo can be found using <strong>the</strong> ma<strong>the</strong>m<strong>at</strong>ical identity,<br />

297

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