the coking properties of coal at elevated pressures. - Argonne ...
the coking properties of coal at elevated pressures. - Argonne ...
the coking properties of coal at elevated pressures. - Argonne ...
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The Influence <strong>of</strong> Varying Oper<strong>at</strong>ional Parameters on Both <strong>the</strong> Combustion Efficiency<br />
in and <strong>the</strong> Emission <strong>of</strong> Pollutants from Fluidized Bed Plants 1)<br />
by:<br />
Dr.' H. Munzner, Dr. H.-D. Schilling VDI, Essen<br />
Bergbau-Forschung GmbH, P.O. Box 13 01 40, 4300 Essen 13, Fed.Rep. <strong>of</strong> Germany<br />
1. Methods and Appar<strong>at</strong>us<br />
Our method <strong>of</strong> determining <strong>the</strong> influence <strong>of</strong> different oper<strong>at</strong>ional ccnditions on<br />
fluidized bed plants consists in a stepwise alter<strong>at</strong>ion <strong>of</strong> one Single oper<strong>at</strong>ional para-<br />
meter while maintaining <strong>the</strong> o<strong>the</strong>rs as constant as possible (1). It is well known<br />
th<strong>at</strong> this is easiest on a labor<strong>at</strong>ory scale, whereas with increasing plant size <strong>the</strong><br />
procedure becomes more and more onerous. If beyond oper<strong>at</strong>ional parameters also<br />
<strong>the</strong> design concept and <strong>the</strong> size <strong>of</strong> a plant are varied, one obtains useful hints how<br />
to generalize and scale-up <strong>the</strong> results achieved.<br />
Present findings were obtained using several types <strong>of</strong> labor<strong>at</strong>ory equipment with<br />
<strong>the</strong>rmal performances between 2 and 20 kW as well as from a semi-technical plant<br />
<strong>of</strong> 300 kW. Figure 1 is a schem<strong>at</strong>ic drawing <strong>of</strong> <strong>the</strong> shapes and dimensions <strong>of</strong> fluidized<br />
bed reactors used. Appar<strong>at</strong>us no. I is a tube reactor <strong>of</strong> 6 cm diameter and 60 cm<br />
height on top <strong>of</strong> which has been arranged a freeboard <strong>of</strong> approx. 35 cm hight and<br />
10 cm diameter. Appar<strong>at</strong>us no. 11 is a tube reactor <strong>of</strong> 6 cm diameter and about<br />
120 cm high. Here <strong>the</strong> ash is retained by an integr<strong>at</strong>ed inertial separ<strong>at</strong>or. Appar<strong>at</strong>us<br />
no. 111 represents a two-stage secondary air reactor with <strong>the</strong> following dimensions:<br />
lower section : 6 cm diameter, 60 crn high,<br />
upper section : 10 cm diameter, 80 cm high,<br />
integr<strong>at</strong>ing an inertial separ<strong>at</strong>or. Unit no. IV is a pressurized reactor allowing<br />
combustion <strong>pressures</strong> up to 10 bar. Its reaction tube has a diameter <strong>of</strong> 6 cm and a<br />
height <strong>of</strong> 1 m, and incorpor<strong>at</strong>es an inertial separ<strong>at</strong>or. An early version <strong>of</strong> <strong>the</strong><br />
pressurized reactor, oper<strong>at</strong>ed <strong>at</strong> 4.5 bar, was <strong>of</strong> a similar shape and size as<br />
appar<strong>at</strong>us no. 1. The reactor space provided by <strong>the</strong> semi-technical plant, finally,<br />
has a cross-section <strong>of</strong> 40 by 80 cm, a height <strong>of</strong> approx. 1 m, with a freeboard <strong>of</strong><br />
80 by 80 cm cross-section and approx. 2 m height.<br />
The <strong>coal</strong> is fed pneum<strong>at</strong>ically, along with all <strong>of</strong> <strong>the</strong> combustion air, to <strong>the</strong> electri-<br />
cally pre-he<strong>at</strong>ed labor<strong>at</strong>ory units, whereas in <strong>the</strong> semi-technical plant <strong>coal</strong> is fed<br />
with a small fraction <strong>of</strong> <strong>the</strong> total air from one side into <strong>the</strong> fluidized bed. The<br />
<strong>at</strong>mospheric labor<strong>at</strong>ory units, due to <strong>the</strong>ir high surface-to-volume r<strong>at</strong>io, are<br />
equipped with a he<strong>at</strong> insul<strong>at</strong>ion allowing to maintain a combustion temper<strong>at</strong>ure as<br />
high as approx . 950 OC. The pressurized unit, however, requires a variable he<strong>at</strong><br />
exchanger for <strong>the</strong>rmal discharge since in this case <strong>the</strong> he<strong>at</strong> release r<strong>at</strong>e is higher<br />
by a factor <strong>of</strong> 10. As to <strong>the</strong> <strong>at</strong>mospheric semi-technical unit, it also needs he<strong>at</strong><br />
exchangers which are immersed in <strong>the</strong> fluidized bed.<br />
') The present project has been sponsored by <strong>the</strong> Federal Ministry <strong>of</strong><br />
Research and Technology (project no. ET 1024 B)<br />
218<br />
I