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the coking properties of coal at elevated pressures. - Argonne ...

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SURFACE AND BULK ENRICHMENT OF COAL COMBUSTION ASH FOR SELECTED ELEMENTS<br />

ELEMENT<br />

As<br />

Cd<br />

Cr<br />

Pb<br />

Sb<br />

Se<br />

TP,<br />

W<br />

Zn<br />

AI<br />

Ca<br />

CI1<br />

cs<br />

Fe<br />

K<br />

Pfc:<br />

Mn<br />

Na<br />

Rb<br />

Ti<br />

I<br />

*<br />

BULK<br />

ENRI CHbENT<br />

BULK**<br />

**,k<br />

SURFACE<br />

9.4 13.4<br />

--_<br />

___<br />

___<br />

11.5<br />

2.4<br />

3.8<br />

7.9<br />

10.4<br />

__-<br />

7.1<br />

7.8<br />

1.0<br />

1.1<br />

1.1<br />

1.2<br />

1.3<br />

1.1<br />

1.3<br />

1.5<br />

1.5<br />

1.1<br />

1.2<br />

Be 1.6<br />

cu I 2.3<br />

6.2<br />

8.4<br />

---<br />

5.4<br />

4.9<br />

---<br />

6.2<br />

1.6<br />

1.0<br />

1.0<br />

___<br />

1.3<br />

1.3<br />

---<br />

1.7<br />

--_<br />

1.7<br />

1.2<br />

---<br />

2.2<br />

3.3<br />

11.0<br />

1.1<br />

1.6<br />

___<br />

___<br />

0.8<br />

7.6<br />

0.9<br />

6.4<br />

15.2<br />

_--<br />

V I 3.8 2.7 2.0<br />

''Bulk enrichment defined as <strong>the</strong> r<strong>at</strong>io <strong>of</strong> <strong>the</strong> concentr<strong>at</strong>ion ina 1U particles<br />

to th<strong>at</strong> in an 18.5~ particle, from D.G. Coles, R.C. Ragaini, J.M. Ondov,<br />

G.L. Fisher, D. Silberman, B.A. Prentice, Environ. Sci. & Tech., 13, 455<br />

(1979).<br />

>k ?<<br />

Bulk enrichment defined as <strong>the</strong> r<strong>at</strong>io <strong>of</strong> <strong>the</strong> concentr<strong>at</strong>ion in a 0.15~<br />

particle to th<strong>at</strong> in a 20p particle, from R.D.<br />

& Comb. Sci., 6, 53 (1980).<br />

Smith, Prog. in Energy<br />

**??<br />

Surface enrichment defined as <strong>the</strong> r<strong>at</strong>io <strong>of</strong> <strong>the</strong> surface composition divided<br />

by <strong>the</strong> composition <strong>at</strong> 500 8, from R.W. Linton, P. Williams, C.A. Evans, Jr.,<br />

and D.S.F. N<strong>at</strong>usch, Anal. Chem., - 49, 1514 (1977).<br />

143<br />

0.9<br />

6.0

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