the coking properties of coal at elevated pressures. - Argonne ...

the coking properties of coal at elevated pressures. - Argonne ... the coking properties of coal at elevated pressures. - Argonne ...

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10. 11. 12. 13. 14. 15. 16. 17. 18. R.W. Linton, P. Williams, C.A. Evans, Jr., and D.S.F. Natusch, Anal. Chem. 9, 965 (1977). L.D. Hulett and A.J. Weinberger, Environ. Sci. & Technol. 5, 965 (1980). L.D. Hansen, D. Silberman, and G.L. Fisher, Environ. Sci. & Technol. 15, 1057 (1981). Enrichment factors are obtained by normalizing to the bulk composition of the large particles (say > 30 um). C.A. Mims, N. Neville, R.J. Quann, and A.F. Sarofim, "Laboratory Studies of Trace Element Transformation During Coal Combustion," Presented at the 87th AIChE Meeting, August 1979, Boston, Mass. C.D. Stinespring and G.W. Stewart, Atmos. Environ. 15, 307 (1981). G.W. Stewart and A. Chakrabarti, High Temperature-High Pressure (In press) (1982). A. Chakrabarti, D.W. Bonnell, G.W. Stewart, and J.W. Hastie, To be published (1981). J.W. Hastie, E.R. Plante, and D.W. Bonnell, Interim Report No. NBSIR 81-2279, U.S. Department of Commerce, National Bureau of Standards, Washington, DC 20234 (1981). 142 I I

\ i SURFACE AND BULK ENRICHMENT OF COAL COMBUSTION ASH FOR SELECTED ELEMENTS ELEMENT As Cd Cr Pb Sb Se TP, W Zn AI Ca CI1 cs Fe K Pfc: Mn Na Rb Ti I * BULK ENRI CHbENT BULK** **,k SURFACE 9.4 13.4 --_ ___ ___ 11.5 2.4 3.8 7.9 10.4 __- 7.1 7.8 1.0 1.1 1.1 1.2 1.3 1.1 1.3 1.5 1.5 1.1 1.2 Be 1.6 cu I 2.3 6.2 8.4 --- 5.4 4.9 --- 6.2 1.6 1.0 1.0 ___ 1.3 1.3 --- 1.7 --_ 1.7 1.2 --- 2.2 3.3 11.0 1.1 1.6 ___ ___ 0.8 7.6 0.9 6.4 15.2 _-- V I 3.8 2.7 2.0 ''Bulk enrichment defined as the ratio of the concentration ina 1U particles to that in an 18.5~ particle, from D.G. Coles, R.C. Ragaini, J.M. Ondov, G.L. Fisher, D. Silberman, B.A. Prentice, Environ. Sci. & Tech., 13, 455 (1979). >k ?< Bulk enrichment defined as the ratio of the concentration in a 0.15~ particle to that in a 20p particle, from R.D. & Comb. Sci., 6, 53 (1980). Smith, Prog. in Energy **?? Surface enrichment defined as the ratio of the surface composition divided by the composition at 500 8, from R.W. Linton, P. Williams, C.A. Evans, Jr., and D.S.F. Natusch, Anal. Chem., - 49, 1514 (1977). 143 0.9 6.0

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17.<br />

18.<br />

R.W. Linton, P. Williams, C.A. Evans, Jr., and D.S.F. N<strong>at</strong>usch,<br />

Anal. Chem. 9, 965 (1977).<br />

L.D. Hulett and A.J. Weinberger, Environ. Sci. & Technol. 5, 965<br />

(1980).<br />

L.D. Hansen, D. Silberman, and G.L. Fisher, Environ. Sci. &<br />

Technol. 15, 1057 (1981).<br />

Enrichment factors are obtained by normalizing to <strong>the</strong> bulk<br />

composition <strong>of</strong> <strong>the</strong> large particles (say > 30 um).<br />

C.A. Mims, N. Neville, R.J. Quann, and A.F. Sar<strong>of</strong>im, "Labor<strong>at</strong>ory<br />

Studies <strong>of</strong> Trace Element Transform<strong>at</strong>ion During Coal Combustion,"<br />

Presented <strong>at</strong> <strong>the</strong> 87th AIChE Meeting, August 1979, Boston, Mass.<br />

C.D. Stinespring and G.W. Stewart, Atmos. Environ. 15, 307 (1981).<br />

G.W. Stewart and A. Chakrabarti, High Temper<strong>at</strong>ure-High Pressure (In<br />

press) (1982).<br />

A. Chakrabarti, D.W. Bonnell, G.W. Stewart, and J.W. Hastie, To be<br />

published (1981).<br />

J.W. Hastie, E.R. Plante, and D.W. Bonnell, Interim Report No. NBSIR<br />

81-2279, U.S. Department <strong>of</strong> Commerce, N<strong>at</strong>ional Bureau <strong>of</strong> Standards,<br />

Washington, DC 20234 (1981).<br />

142<br />

I<br />

I

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