liquefaction pathways of bituminous subbituminous coals andtheir

liquefaction pathways of bituminous subbituminous coals andtheir liquefaction pathways of bituminous subbituminous coals andtheir

25.04.2013 Views

0.a . . Temperamure ('C) Figure 1. Tan 6 DMA spectra obtained from 4 OUinin scans of as-received and predried (up to 200OC at 4 OC/min) Pittsburgh No. 8 coal pellet samples. Pellets were. made from -100 mesh powder aftex pressed at 15 kpsi for the duration as specified in the figure. Figure 2. Effect of sample drying on tensile loss modulus obtained at 4°C/min for Pittsburgh No. 8 coal. Sample pellets were made from -100 mesh powder pressed at 15 kpsi for 10 hr. 492 t

-0.01- . 04 5 -0.03- E 6 -0.0s- c) 6 Y 0 .- c) d .- - 0) 3.0 - 3 1.5v1 h 12it Y m 9- 8 J 6- m 2 Pyridine (b) Solvent swelling 1.0- ' 1 ' 8 . I , I . 15 3- 2nd.3rd 1st-2nd lstdrd 0 100 200 300 400 500 Temperature ("C) Figure 3. Difference DSC thermograms as well as profiles of solvent swelling ratio and weight loss obtained at 8 "Umh from -100 mesh Pittsburgh No. 8 coal powder (swelling time:a 5 hr.0, 1 day;., 2 days;A,4 days;o,S days;m,6 days). 493

-0.01-<br />

. 04<br />

5 -0.03-<br />

E<br />

6 -0.0s-<br />

c)<br />

6<br />

Y<br />

0 .- c)<br />

d<br />

.-<br />

-<br />

0)<br />

3.0 -<br />

3 1.5v1<br />

h<br />

12it<br />

Y<br />

m 9-<br />

8<br />

J 6-<br />

m<br />

2<br />

Pyridine<br />

(b) Solvent swelling<br />

1.0- ' 1 ' 8 . I , I .<br />

15<br />

3-<br />

2nd.3rd<br />

1st-2nd<br />

lstdrd<br />

0 100 200 300 400 500<br />

Temperature ("C)<br />

Figure 3. Difference DSC thermograms as well as pr<strong>of</strong>iles <strong>of</strong> solvent swelling ratio and weight<br />

loss obtained at 8 "Umh from -100 mesh Pittsburgh No. 8 coal powder (swelling time:a 5 hr.0,<br />

1 day;., 2 days;A,4 days;o,S days;m,6 days).<br />

493

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!