secondary cells with lithium anodes and immobilized fused_salt
secondary cells with lithium anodes and immobilized fused_salt secondary cells with lithium anodes and immobilized fused_salt
aa . - The rrost difficult rctionele is the formation of the AsF6 in the reaction. Admittedly a multiplicity of diverse reertion seqaences could be proposed rost of which k'oul? be difficlllt to experimentally verify. 3ne possible path offerd involves the dissoci?tion of C10 AsF C1 into its cocponents with :he suSsesuent reactions noted: 2 5 C102AsF5C1 __$ FC102 + AsFdC1 (6) 3AsF4C1- -> AaF?C12 + AsF 5 AsF + PC102 -* C102AsF6 5 .b?,Cl + Cl20 _j AsF,O + 2C1 , 2 2 (9) ' It is rer.dily seen tnst the suc of eluztiong d through 9, suitably veishted, .qivez equ?:io? 1. The ide:itity of ASOF, w.97 t!ot estPSlished as n product since it is ti non-volatile1° X-rs.v'nmor=hous s3lid. In addition. we did ~ o wish t to further eo-nlicete nrtters by studying the renction of AsF C1 with Cl 0 QS a test ox" sTyftion 8 inasmuch as AsF,Cl "Foes ionic" 2nd 1s ?ornulate$ as + - . Ve did feel, howeve$, ghat a suitrble test of equation 8 Ad14 AsF F. woull be 'he re?ction of PF3C12 2nd C1 0. Indeed, the mpid conversion of PF CI to KF : i r ~ ~1 ila in e;!urtion ?o: 3 7 3 2 : ?F,C12 + Cl20 ?OF + 2C12 (10) 3 stron&:ly suceestn t!wt "covRlent" AF' C1 would react sinilerly. The 3 2 re;:ction conditiohs "e s:ich th?t the reory:!nizstion of AsF C1, postulated -9 rin interr.ediere in e.:uation 6, would Tive initially the 8ovzlent strwture. The initinl resort on the prep?r-tions of "C rerc:ion of NO -9 P proof of the rrlical ?resent 7 ClOAsF + 2LC2 ::C),i.sF + C11i07 (11) 5 L 5 T?,e Ftvistence of "0 As" h?s r.lresdy been ?uestioned Periously and apparently disarovedt2: 'Fur?her. the formntion of soze ClNO? should be expected f'r(;c ..i- ~~..,,-. :.--> , c. ..,- i NO in.-s-uc!: 2s thc r?oc:icn of C:07 2nd NO rives ~t 2 i? ~ uite likely thnt the reaction oSaerve3. by Scgmeisser &. ciiio, - - * - . (7) ia) ---- ---- -----
I I I 1 i ' was the initi.1 displacenent of C102 from C102AsF6 by NO, followed by - a reection of C10, with NO2, the overall reaction being: 89. - C102AsF6 + 2N02 ___t NG2AsF6 + CINOg + 1/2 O2 (12) Except for the formation of the oxygen, the reaction in equation 12 has the s?me stoichiometry of KO2 to "solid" RS that reported in equation 11. Thus, the proof of "C10AsF5" through its reactions or its synthesis is not ccnclusive. ,
- Page 38 and 39: - Literature Cited 38 1. Gordon, K
- Page 40 and 41: 40 z - B 30 w 6 20 yl w U 10 40. 10
- Page 42 and 43: Z 0 In 80 CK W > 6 60- 0 I- 40- Z W
- Page 44 and 45: 44. 2.0 I 1.2 - 0 2 1.0- 0.8 i TIME
- Page 46 and 47: - 2.81 1.NITROGEN 2. SULFUR 3. GASO
- Page 48 and 49: 48. The oil from the separator is v
- Page 50 and 51: . 50 . Table I . Properties of Pitc
- Page 52 and 53: 52. Coke yield A - - - - 0 800 900
- Page 54 and 55: FIGURE 8. 54. t 0.5 1 800 900 1,000
- Page 56 and 57: Introduction 56. FLUORODINITROETUNO
- Page 58 and 59: chloride extractant without other h
- Page 60 and 61: 60. identified (Reference 7) as the
- Page 62 and 63: 62. to FEFO -e quite high (80 to 85
- Page 64 and 65: 64. RECENT CHEMISTRY OF THE OXYGEN
- Page 66 and 67: polymers for the conventional fuel
- Page 68 and 69: 68. In summary, two general methods
- Page 70 and 71: 70. Table XI1 Differential Thermal
- Page 72 and 73: vapor Pressure (psia) Figure 4. Vap
- Page 74 and 75: C H -0-C-NHF, - 2 5 II 0 74. H 9304
- Page 76 and 77: 76. The infrared spectrum is descri
- Page 78 and 79: , 78. PREPARATION AND POLYMERIZATIO
- Page 80 and 81: . .- . - ..... . . I ,caving the re
- Page 82 and 83: If it ~ 3 ~ o~t 7 s Y'2t the therm1
- Page 84 and 85: Chlorine Fentafluaride T q D OC 252
- Page 86 and 87: , 86. Zeections of Cl30 and AsF5. M
- Page 90 and 91: 90. DENSITY, VISCOSITY AND SURFACE
- Page 92 and 93: 92. If it is assumed that the syste
- Page 94 and 95: 94. After condensation of oxidizer
- Page 96 and 97: Stirring Solenoid LHe 7. Cryostat 9
- Page 98 and 99: Introduction 98. RFACTIONS OF OxYcm
- Page 100 and 101: , Acknowledgement 100. This work wa
- Page 102 and 103: 102. volume and then by pumping to
- Page 104 and 105: 104. The x-ray powder pattern (Tabl
- Page 106 and 107: Irredie tion Time, mi&) 106. Table
- Page 108 and 109: I. Introduction 108. RE7IIEw OF ADV
- Page 110 and 111: 1.40 w F O/) 103-4O 'F 110. /H 0 21
- Page 112 and 113: !P, "c -- -2118.5 -195 -172 -16.1 .
- Page 114 and 115: 114. weaker than those in NF02. The
- Page 116 and 117: Compound C102F ~ 1 , 0 ~ -146 ~ 116
- Page 118 and 119: 118. fom such salts as cS+m8- have
- Page 120 and 121: 120. DETONABILITY TESTING AT NONAMB
- Page 122 and 123: I 122. top) is closed with caps whi
- Page 124 and 125: 124. five pieces of MDF, each 20.00
- Page 126 and 127: 126. auxiliary equipment. For conve
- Page 128 and 129: 128. reliability. Details of most o
- Page 130 and 131: 130. The time required for the deto
- Page 132 and 133: 132. Fig. 2 Typical Witness Plate
- Page 134 and 135: I ll 134. L, ALUMINUM 011+ ‘7 I-
- Page 136: W (3 3 a (3 W m 3 0 v) W E k- / W 3
I I<br />
I<br />
1<br />
i '<br />
was the initi.1 displacenent of C102 from C102AsF6 by NO, followed by -<br />
a<br />
reection of C10, <strong>with</strong> NO2, the overall reaction being:<br />
89.<br />
-<br />
C102AsF6 + 2N02 ___t NG2AsF6 + CINOg + 1/2 O2 (12)<br />
Except for the formation of the oxygen, the reaction in equation 12 has<br />
the s?me stoichiometry of KO2 to "solid" RS that reported in equation 11.<br />
Thus, the proof of "C10AsF5" through its reactions or its synthesis is<br />
not ccnclusive.<br />
,
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