secondary cells with lithium anodes and immobilized fused_salt
secondary cells with lithium anodes and immobilized fused_salt secondary cells with lithium anodes and immobilized fused_salt
Irredie tion Time, mi&) 106. Table 3. PREPARATION OF 0,+BF4-a) Ratio F2:02 Irradiatedc) 02bF4- Produced, mg 15 1: 1 27 1.6 8.9 30 1: 1 53 3 8.8 60 1:l 96 6 7.9 60 2:l 129 12 11.0 60 3: 1 1% 16 10.6 60 5:1 127 2h 10.5 60 7:l 113 27 8.9 60 1:6 444 1.5 4.1 60e) 1: 1 45 2.7 14.9 120 3: 1 216 26 8.6 180 1:l 231 14 6.3 180 5: 1 248 47 6.9 12of 3: 1 21 2.6 0.2 a) 14 moles )f BF3 wes adde after irrai ition. b) Dose rate of 100 negarads/hour. c) d) Millimoles of oxygen used with F2:02 ratios was: 1:l = 14 moles; 2:l = 8.75 moles; 3:l = 7.0 moles; 5:1 = 4.4 moles; 7:1 = 3.5 moles; 1:6 = 21.9 moles. A second compound was formed vhich decomposed at 133% yielding about 3 moles of noncondensable gases. e) Dose rate of 25 megarads/hour. f) 10.5 moles of BF3 added to the reaction tube before irradiation. g) Molecules of product formed per 100 ev absorbed energy. ,
, 107. REFERENCES 1. 0. Ruff and M. Menzel, 2. Anorg. Chem. 211, 204 (1933). 2. A. D, Kirshenbaum and A. V. Grosse, J. Am. Chem. SOC. 8l, 1277 (1959). 3. A. V. Grosse, A. C. Streng, and A. D. Kirshenbaum, ibid. 5, 1004 (1961). 4. 5. 6. 7. 8. 9. 10. 11. 12. 13 - 14. A. G. Streng and A. V. Grosse, ibid. 88, 169 (1966). I. J. Solomon, Adv. Oxid. Research, U.S. Dept. Comm., AD 640405, (19661, Ill. Inst. of Tech. or Chem. Abst. 66, 820a6f, (1967). A. D. Kirshenbaum, A. V. Grosse, and J. G. Aston, ibid. &, 6398 (1959). A. D. Kirshenbaum and A. G. Streng, J. Chem. Phys. 2, 1440 (1961). A. C. Streng, Chem. Revs. 3, 607 (1963). T. J. Idalone and H. A. Mc Gee, Jr., J. Phys. Chem. 9, 4338 (1965). T. J. Malone and H. A. Mc Gee, Jr., ibid. 71, 3060 (1967). A. G. Streng and A. V. Grosse, Adv. in &em. Series, No. 36, Am. Chem. SOC., iu'ashington, D.C., 1962, pp. 159-164. M. S. Cohen, J. Inorg. Chem. 1, 972 (1962). A. G. Streng, J. Am. Chem. SOC. a, 1380 (1963). A. R. Young, 11, T. Hirata, and S. I. Marrow, ibid. 86, 20 (1964). 15. I. J. Solorran, R. I. Brabets, R. K. Uenishi, J. N. Kei+A, and J. M. Mc Donough, J. Inorg. Chem. 2, 457 (1964). 16. 17. 18. S. I. Xarrov and A. R. Young, 11, ibid. k, 759 (1965). C. D. agner and V. A. Campanile, Nucleonics 17, (7), 99 (1959). Quad 200 Quadrupole Mass Spectrometer, Electronic Associates Inc., Palo Alto, California. 19. I. J. Solonian, Illinois Institute of Technology, Research Institute, private communication, October 1967, in press. 20. 21. 22. N. N. Greenv~oOd, J. Chem. SOC., 3811 (1959). N. Barlett and D. Lohman, J. Chem. SOC., 5253 (1962). A. D. Kirshenbaum and A. V. Grosse, unpublished work under Air Force Contract No. AF04(611) -9555, Temple University, December 1965. 23. I. J. Soloman, et el, unpublished vork under Air Force Contract No. AF49(63) -1175, Illinois Institute of Technology, Research Institute, December 1962. ,
- Page 56 and 57: Introduction 56. FLUORODINITROETUNO
- Page 58 and 59: chloride extractant without other h
- Page 60 and 61: 60. identified (Reference 7) as the
- Page 62 and 63: 62. to FEFO -e quite high (80 to 85
- Page 64 and 65: 64. RECENT CHEMISTRY OF THE OXYGEN
- Page 66 and 67: polymers for the conventional fuel
- Page 68 and 69: 68. In summary, two general methods
- Page 70 and 71: 70. Table XI1 Differential Thermal
- Page 72 and 73: vapor Pressure (psia) Figure 4. Vap
- Page 74 and 75: C H -0-C-NHF, - 2 5 II 0 74. H 9304
- Page 76 and 77: 76. The infrared spectrum is descri
- Page 78 and 79: , 78. PREPARATION AND POLYMERIZATIO
- Page 80 and 81: . .- . - ..... . . I ,caving the re
- Page 82 and 83: If it ~ 3 ~ o~t 7 s Y'2t the therm1
- Page 84 and 85: Chlorine Fentafluaride T q D OC 252
- Page 86 and 87: , 86. Zeections of Cl30 and AsF5. M
- Page 88 and 89: aa . - The rrost difficult rctionel
- Page 90 and 91: 90. DENSITY, VISCOSITY AND SURFACE
- Page 92 and 93: 92. If it is assumed that the syste
- Page 94 and 95: 94. After condensation of oxidizer
- Page 96 and 97: Stirring Solenoid LHe 7. Cryostat 9
- Page 98 and 99: Introduction 98. RFACTIONS OF OxYcm
- Page 100 and 101: , Acknowledgement 100. This work wa
- Page 102 and 103: 102. volume and then by pumping to
- Page 104 and 105: 104. The x-ray powder pattern (Tabl
- Page 108 and 109: I. Introduction 108. RE7IIEw OF ADV
- Page 110 and 111: 1.40 w F O/) 103-4O 'F 110. /H 0 21
- Page 112 and 113: !P, "c -- -2118.5 -195 -172 -16.1 .
- Page 114 and 115: 114. weaker than those in NF02. The
- Page 116 and 117: Compound C102F ~ 1 , 0 ~ -146 ~ 116
- Page 118 and 119: 118. fom such salts as cS+m8- have
- Page 120 and 121: 120. DETONABILITY TESTING AT NONAMB
- Page 122 and 123: I 122. top) is closed with caps whi
- Page 124 and 125: 124. five pieces of MDF, each 20.00
- Page 126 and 127: 126. auxiliary equipment. For conve
- Page 128 and 129: 128. reliability. Details of most o
- Page 130 and 131: 130. The time required for the deto
- Page 132 and 133: 132. Fig. 2 Typical Witness Plate
- Page 134 and 135: I ll 134. L, ALUMINUM 011+ ‘7 I-
- Page 136: W (3 3 a (3 W m 3 0 v) W E k- / W 3
,<br />
107.<br />
REFERENCES<br />
1. 0. Ruff <strong>and</strong> M. Menzel, 2. Anorg. Chem. 211, 204 (1933).<br />
2. A. D, Kirshenbaum <strong>and</strong> A. V. Grosse, J. Am. Chem. SOC. 8l, 1277 (1959).<br />
3. A. V. Grosse, A. C. Streng, <strong>and</strong> A. D. Kirshenbaum, ibid. 5, 1004 (1961).<br />
4.<br />
5.<br />
6.<br />
7.<br />
8.<br />
9.<br />
10.<br />
11.<br />
12.<br />
13 -<br />
14.<br />
A. G. Streng <strong>and</strong> A. V. Grosse, ibid. 88, 169 (1966).<br />
I. J. Solomon, Adv. Oxid. Research, U.S. Dept. Comm., AD 640405, (19661,<br />
Ill. Inst. of Tech. or Chem. Abst. 66, 820a6f, (1967).<br />
A. D. Kirshenbaum, A. V. Grosse, <strong>and</strong> J. G. Aston, ibid. &, 6398 (1959).<br />
A. D. Kirshenbaum <strong>and</strong> A. G. Streng, J. Chem. Phys. 2, 1440 (1961).<br />
A. C. Streng, Chem. Revs. 3, 607 (1963).<br />
T. J. Idalone <strong>and</strong> H. A. Mc Gee, Jr., J. Phys. Chem. 9, 4338 (1965).<br />
T. J. Malone <strong>and</strong> H. A. Mc Gee, Jr., ibid. 71, 3060 (1967).<br />
A. G. Streng <strong>and</strong> A. V. Grosse, Adv. in &em. Series, No. 36, Am. Chem. SOC.,<br />
iu'ashington, D.C., 1962, pp. 159-164.<br />
M. S. Cohen, J. Inorg. Chem. 1, 972 (1962).<br />
A. G. Streng, J. Am. Chem. SOC. a, 1380 (1963).<br />
A. R. Young, 11, T. Hirata, <strong>and</strong> S. I. Marrow, ibid. 86, 20 (1964).<br />
15. I. J. Solorran, R. I. Brabets, R. K. Uenishi, J. N. Kei+A, <strong>and</strong><br />
J. M. Mc Donough, J. Inorg. Chem. 2, 457 (1964).<br />
16.<br />
17.<br />
18.<br />
S. I. Xarrov <strong>and</strong> A. R. Young, 11, ibid. k, 759 (1965).<br />
C. D.<br />
agner <strong>and</strong> V. A. Campanile, Nucleonics 17, (7), 99 (1959).<br />
Quad 200 Quadrupole Mass Spectrometer, Electronic Associates Inc.,<br />
Palo Alto, California.<br />
19. I. J. Solonian, Illinois Institute of Technology, Research Institute,<br />
private communication, October 1967, in press.<br />
20.<br />
21.<br />
22.<br />
N. N. Greenv~oOd, J. Chem. SOC., 3811 (1959).<br />
N. Barlett <strong>and</strong> D. Lohman, J. Chem. SOC., 5253 (1962).<br />
A. D. Kirshenbaum <strong>and</strong> A. V. Grosse, unpublished work under Air Force<br />
Contract No. AF04(611) -9555, Temple University, December 1965.<br />
23. I. J. Soloman, et el, unpublished vork under Air Force Contract No.<br />
AF49(63) -1175, Illinois Institute of Technology, Research Institute,<br />
December 1962.<br />
,
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