secondary cells with lithium anodes and immobilized fused_salt

Irredie tion
Time, mi&)
106.
Table 3. PREPARATION OF 0,+BF4-a)
Ratio F2:02
Irradiatedc)
02bF4-
Produced,
mg
15
1: 1
27
1.6 8.9
30
1: 1 53
3 8.8
60 1:l 96
6
7.9
60
2:l
129
12 11.0
60
3: 1
1%
16 10.6
60
5:1
127
2h 10.5
60
7:l
113
27
8.9
60
1:6
444
1.5 4.1
60e)
1: 1
45
2.7 14.9
120
3: 1
216
26 8.6
180
1:l
231
14
6.3
180
5: 1
248 47 6.9
12of
3: 1
21
2.6 0.2
a) 14 moles )f BF3 wes adde after irrai ition.
b) Dose rate of 100 negarads/hour.
c)
d)
Millimoles of oxygen used with F2:02 ratios was:
1:l = 14 moles; 2:l = 8.75 moles; 3:l = 7.0 moles;
5:1 = 4.4 moles; 7:1 = 3.5 moles; 1:6 = 21.9 moles.
A second compound was formed vhich decomposed at 133%
yielding about 3 moles of noncondensable gases.
e) Dose rate of 25 megarads/hour.
f) 10.5 moles of BF3 added to the reaction tube before
irradiation.
g) Molecules of product formed per 100 ev absorbed energy.
,