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secondary cells with lithium anodes and immobilized fused_salt

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c<br />

105,<br />

Table 1. YIELDS nF FpOr AND FpOa FR@M IRRADIATIONa) OF FLUORINE/O%XXN b!IxTW<br />

Ratio,<br />

- F2h2<br />

1<br />

3<br />

5<br />

7<br />

1<br />

1<br />

1.<br />

3<br />

5<br />

7<br />

-<br />

F2<br />

_I_<br />

14.0<br />

21.0<br />

22.8<br />

24.5<br />

10.5<br />

10.5<br />

10.5<br />

15.7<br />

17.5<br />

18.4<br />

n<br />

-<br />

:, 10(<br />

b)<br />

c)<br />

d)<br />

illimoles<br />

02 i Ar<br />

14.0; -<br />

7.0 -<br />

4.6 -<br />

3.5 -<br />

10.5 -<br />

10.5 7.0<br />

10.5 7.0<br />

5.3 7.c i 3.51 7.C<br />

2.6; 7.c<br />

megarads, 1 hr.<br />

- 1.72<br />

- 1-93<br />

- 1.86<br />

7 -0<br />

-<br />

- 1.65<br />

- 1.62<br />

- 1.62<br />

- I 1.62<br />

0.13, 0.087 f 0.02<br />

0.085 0.05 f 0.02<br />

0.105 0.055 f 0.02<br />

0.14 0.075 f 0.015<br />

(d) n.d.<br />

(d) n.d.<br />

0.07 0.042 f 0.02<br />

0.14 10.09 f 0.02<br />

0.105 0.065 t 0.02<br />

I<br />

0.09 0.055 f 0.02<br />

yield data accurate to ca f 0.03 mole.<br />

Molecules of product formed per 100 ev absorbed energy.<br />

Amount of F204 not reliably determined because of a slight<br />

detonation on .,.arming the system to decompose F204.<br />

oxygen<br />

1.89 127.0<br />

2.14 146.6<br />

0<br />

2.14 61.2<br />

1.26 12.0<br />

1.73 16.5<br />

1.79 17.1<br />

1.90 35.9<br />

1.83 52.3<br />

1.79 . 68.9<br />

Table 2. DIFFRACTION PATTERNS OF NO%F4- AND 02+BF4-<br />

NO-<br />

Interplanar<br />

Spacing<br />

A<br />

5.50<br />

4.41<br />

3.96<br />

3.76<br />

3-51<br />

3.25<br />

3-13<br />

2.82<br />

2-75<br />

2.52<br />

2.40 ,<br />

2-99<br />

2.26<br />

Intensity<br />

of '<br />

Reflection<br />

24<br />

40<br />

8<br />

12<br />

100<br />

12<br />

80<br />

60<br />

12<br />

40<br />

3<br />

8.<br />

60<br />

C<br />

Interplanar<br />

Spacing<br />

A<br />

5.50<br />

4.33<br />

3.91<br />

3.74<br />

3.47<br />

3.27<br />

3.10<br />

2.82<br />

2.74<br />

2.49<br />

2.43<br />

2.35<br />

2.24<br />

BF* -<br />

Intensity<br />

of<br />

Reflection<br />

16<br />

9<br />

5<br />

9<br />

100<br />

16<br />

88<br />

75<br />

12<br />

44<br />

7<br />

7<br />

63<br />

hkl<br />

110<br />

101<br />

111<br />

120<br />

021<br />

210<br />

121<br />

211<br />

220<br />

112<br />

131<br />

022<br />

122<br />

-<br />

21;2<br />

17.1<br />

,

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