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Engineering Materials and Metallurgy (65332) Lecturer

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An-Najah National University<br />

Faculty of <strong>Engineering</strong><br />

Industrial <strong>Engineering</strong> Department<br />

<strong>Engineering</strong> <strong>Materials</strong> <strong>and</strong><br />

<strong>Metallurgy</strong> (<strong>65332</strong>)<br />

<strong>Lecturer</strong>: Eng. Tamer H. Haddad<br />

Time: 10:00-11:00 & 15:00-16:00 (Sun, Tue, Thu)<br />

Locations: 111080 & 111060<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 1


COURSE MATERIALS<br />

Required text:<br />

• <strong>Materials</strong> Science <strong>and</strong> <strong>Engineering</strong>: An Introduction<br />

W.D. Callister, Jr., 7th edition, John Wiley <strong>and</strong> Sons,<br />

Inc. (2007).<br />

Course Objective...<br />

Introduce fundamental concepts in <strong>Materials</strong><br />

Science<br />

You will learn about:<br />

• material structure<br />

• how structure dictates properties<br />

• how processing can change structure<br />

This course will help you to:<br />

• use materials properly<br />

• realize new design opportunities with materials<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 2


Chapter 1 - Introduction<br />

• What is materials science?<br />

Investigating the relationships that exist between the<br />

structures <strong>and</strong> properties of materials<br />

• What is materials engineering?<br />

Designing or engineering the structure of a material to<br />

produce a predetermined set of properties<br />

• Structure & Property Definitions.<br />

• <strong>Materials</strong> drive our society<br />

– Stone Age<br />

– Bronze Age<br />

– Iron Age<br />

– Now?<br />

• Silicon Age?<br />

• Polymer Age? Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 3


Example – Hip Implant<br />

• With age or certain illnesses joints deteriorate.<br />

Particularly those with large loads (such as hip).<br />

Adapted from Fig. 22.25, Callister 7e.<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 4


• Requirements<br />

Example – Hip Implant<br />

– mechanical<br />

strength (many<br />

cycles)<br />

– good lubricity<br />

– biocompatibility<br />

Adapted from Fig. 22.24, Callister 7e.<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 5


Example – Hip Implant<br />

Adapted from Fig. 22.26, Callister 7e.<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 6


Hip Implant<br />

• Key problems to overcome<br />

– fixation agent to hold<br />

acetabular cup<br />

– cup lubrication material<br />

– femoral stem – fixing agent<br />

(“glue”)<br />

– must avoid any debris in cup<br />

Femoral<br />

Stem<br />

Adapted from chapter-opening photograph,<br />

Chapter 22, Callister 7e.<br />

Instructor: Eng. Tamer Haddad<br />

Ball<br />

Acetabular<br />

Cup <strong>and</strong> Liner<br />

Chapter 1 - 7


Structure, Processing, & Properties<br />

• Properties depend on structure<br />

ex: hardness vs structure of steel<br />

Hardness (BHN)<br />

600<br />

500<br />

400<br />

300<br />

200<br />

(a)<br />

30 mm<br />

(b)<br />

30 mm<br />

(c)<br />

4 mm<br />

100<br />

0.01 0.1 1 10 100 1000<br />

Cooling Rate (ºC/s)<br />

• Processing can change structure<br />

ex: structure vs cooling rate of steel<br />

Instructor: Eng. Tamer Haddad<br />

(d)<br />

30 mm<br />

Data obtained from Figs. 10.30(a)<br />

<strong>and</strong> 10.32 with 4 wt% C composition,<br />

<strong>and</strong> from Fig. 11.14 <strong>and</strong> associated<br />

discussion, Callister 7e.<br />

Micrographs adapted from (a) Fig.<br />

10.19; (b) Fig. 9.30;(c) Fig. 10.33;<br />

<strong>and</strong> (d) Fig. 10.21, Callister 7e.<br />

Chapter 1 - 8


Types of <strong>Materials</strong> (Depends on chemical makeup <strong>and</strong><br />

atomic structure)<br />

• Metals:<br />

– Strong, ductile<br />

– high thermal & electrical conductivity<br />

– opaque, reflective.<br />

• Polymers/plastics: Covalent bonding sharing of e’s<br />

– Soft, ductile, low strength, low density<br />

– thermal & electrical insulators<br />

– Optically translucent or transparent.<br />

• Ceramics: ionic bonding (refractory) – compounds of metallic<br />

& non-metallic elements (oxides, carbides, nitrides, sulfides)<br />

– Brittle, glassy, elastic, hard.<br />

– non-conducting (insulators)<br />

– High resistive to temperature <strong>and</strong> harsh envirinmenrs.<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 9


Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 10


• Composites: Utilized in high technology (CD/DVD Players)<br />

– Combination between the previous materials<br />

• Advanced <strong>Materials</strong>:<br />

– Semiconductors (Computer Industries).<br />

– Biomaterials (Human body components).<br />

– <strong>Materials</strong> of the future (Sensors).<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 -<br />

11


Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 12


Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 13


Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 14


Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 15


Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 16


The <strong>Materials</strong> Selection Process<br />

1. Pick Application Determine required Properties<br />

Properties: mechanical, electrical, thermal,<br />

magnetic, optical, deteriorative.<br />

2. Properties Identify c<strong>and</strong>idate Material(s)<br />

Material: structure, composition.<br />

3. Material Identify required Processing<br />

Processing: changes structure <strong>and</strong> overall shape<br />

ex: casting, sintering, vapor deposition, doping<br />

forming, joining, annealing.<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 17


Solid <strong>Materials</strong> Properties Classification<br />

ELECTRICAL<br />

• Electrical Resistivity of Copper:<br />

Resistivity, r<br />

(10 -8 Ohm-m)<br />

6<br />

5<br />

4<br />

3<br />

2<br />

1<br />

0<br />

-200 -100 0<br />

Adapted from Fig. 18.8, Callister 7e.<br />

(Fig. 18.8 adapted from: J.O. Linde,<br />

Ann Physik 5, 219 (1932); <strong>and</strong><br />

C.A. Wert <strong>and</strong> R.M. Thomson,<br />

Physics of Solids, 2nd edition,<br />

McGraw-Hill Company, New York,<br />

1970.)<br />

T (°C)<br />

• Adding “impurity” atoms to Cu increases resistivity.<br />

• Deforming Cu increases resistivity.<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 18


• Space Shuttle Tiles:<br />

--Silica fiber insulation<br />

offers low heat conduction.<br />

100mm<br />

THERMAL<br />

Adapted from chapteropening<br />

photograph,<br />

Chapter 19, Callister 7e.<br />

(Courtesy of Lockheed<br />

Missiles <strong>and</strong> Space<br />

Company, Inc.)<br />

Adapted from<br />

Fig. 19.4W, Callister<br />

6e. (Courtesy of<br />

Lockheed Aerospace<br />

Ceramics Systems,<br />

Sunnyvale, CA)<br />

(Note: "W" denotes fig.<br />

is on CD-ROM.)<br />

• Thermal Conductivity<br />

of Copper:<br />

--It decreases when<br />

you add zinc!<br />

Thermal Conductivity<br />

(W/m-K)<br />

400<br />

300<br />

200<br />

100<br />

Instructor: Eng. Tamer Haddad<br />

0<br />

0 10 20 30 40<br />

Composition (wt% Zinc)<br />

Adapted from Fig. 19.4, Callister 7e.<br />

(Fig. 19.4 is adapted from Metals H<strong>and</strong>book:<br />

Properties <strong>and</strong> Selection: Nonferrous alloys <strong>and</strong><br />

Pure Metals, Vol. 2, 9th ed., H. Baker,<br />

(Managing Editor), American Society for Metals,<br />

1979, p. 315.)<br />

Chapter 1 - 19


• Magnetic Storage:<br />

--Recording medium<br />

is magnetized by<br />

recording head.<br />

Fig. 20.23, Callister 7e.<br />

(Fig. 20.23 is from J.U. Lemke, MRS Bulletin,<br />

Vol. XV, No. 3, p. 31, 1990.)<br />

MAGNETIC<br />

• Magnetic Permeability<br />

vs. Composition:<br />

--Adding 3 atomic % Si<br />

makes Fe a better<br />

recording medium!<br />

Magnetization<br />

Instructor: Eng. Tamer Haddad<br />

Magnetic Field<br />

Fe+3%Si<br />

Fe<br />

Adapted from C.R. Barrett, W.D. Nix, <strong>and</strong><br />

A.S. Tetelman, The Principles of<br />

<strong>Engineering</strong> <strong>Materials</strong>, Fig. 1-7(a), p. 9,<br />

1973. Electronically reproduced<br />

by permission of Pearson Education, Inc.,<br />

Upper Saddle River, New Jersey.<br />

Chapter 1 - 20


• Transmittance:<br />

--Aluminum oxide may be transparent, translucent, or<br />

opaque depending on the material structure.<br />

single crystal<br />

OPTICAL<br />

polycrystal:<br />

low porosity<br />

Instructor: Eng. Tamer Haddad<br />

polycrystal:<br />

high porosity<br />

Adapted from Fig. 1.2,<br />

Callister 7e.<br />

(Specimen preparation,<br />

P.A. Lessing; photo by S.<br />

Tanner.)<br />

Chapter 1 - 21


• Stress & Saltwater...<br />

--causes cracks!<br />

Adapted from chapter-opening photograph,<br />

Chapter 17, Callister 7e.<br />

(from Marine Corrosion, Causes, <strong>and</strong><br />

Prevention, John Wiley <strong>and</strong> Sons, Inc., 1975.)<br />

DETERIORATIVE<br />

• Heat treatment: slows<br />

crack speed in salt water!<br />

crack speed (m/s)<br />

10 -8<br />

10 -10<br />

Adapted from Fig. 11.20(b), R.W. Hertzberg, "Deformation <strong>and</strong><br />

Fracture Mechanics of <strong>Engineering</strong> <strong>Materials</strong>" (4th ed.), p. 505, John<br />

Wiley <strong>and</strong> Sons, 1996. (Original source: Markus O. Speidel, Brown<br />

Boveri Co.)<br />

--material:<br />

7150-T651 Al "alloy"<br />

(Zn,Cu,Mg,Zr)<br />

Adapted from Fig. 11.26,<br />

Callister 7e. (Fig. 11.26 provided courtesy of G.H.<br />

Narayanan <strong>and</strong> A.G. Miller, Boeing Commercial<br />

Airplane Company.)<br />

Instructor: Eng. Tamer Haddad<br />

“as-is”<br />

“held at<br />

160ºC for 1 hr<br />

before testing”<br />

Alloy 7178 tested in<br />

saturated aqueous NaCl<br />

solution at 23ºC<br />

increasing load<br />

4 mm<br />

Chapter 1 - 22


Course Goals:<br />

SUMMARY<br />

• Use the right material for the job.<br />

• Underst<strong>and</strong> the relation between properties,<br />

structure, <strong>and</strong> processing.<br />

• Recognize new design opportunities offered<br />

by materials selection.<br />

Instructor: Eng. Tamer Haddad<br />

Chapter 1 - 23

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