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Documentation of the Evaluation of CALPUFF and Other Long ...

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• The maximum observed concentration along <strong>the</strong> arc or observed fitted centerline plume<br />

concentration was underestimated by ‐42% to ‐72% <strong>and</strong> <strong>the</strong> plume widths overestimated<br />

by 47% to 293%.<br />

• The <strong>CALPUFF</strong> underestimation bias <strong>of</strong> <strong>the</strong> observed maximum concentration tends to be<br />

improved using CALMET runs with no meteorological observations.<br />

• The use <strong>of</strong> <strong>the</strong> PG dispersion option tends to exacerbate <strong>the</strong> plume width overestimation<br />

bias relative to using <strong>the</strong> CAL or AER turbulence dispersion option.<br />

• The <strong>CALPUFF</strong> predicted plume centerline tends to be <strong>of</strong>fset from <strong>the</strong> observed value by 9<br />

to 20 degrees, with <strong>the</strong> largest centerline <strong>of</strong>fset (> 15 degrees) occurring when no<br />

meteorological observations are used with ei<strong>the</strong>r CALMET or MMIF .<br />

• The 1998 <strong>CALPUFF</strong> runs overestimated <strong>the</strong> observed CWIC by 15% <strong>and</strong> 30% but <strong>the</strong><br />

current study’s BASEA configuration, which was designed to emulate <strong>the</strong> 1998 EPA study,<br />

underestimates <strong>the</strong> observed CWIC by ‐14% <strong>and</strong> ‐38%.<br />

The inability <strong>of</strong> most (~90%) <strong>of</strong> <strong>the</strong> current study’s <strong>CALPUFF</strong> sensitivity tests to reproduce <strong>the</strong><br />

1998 EPA study tracer test residence time on <strong>the</strong> 600 km receptor arc is a cause for concern.<br />

For example, <strong>the</strong> 1998 EPA study <strong>CALPUFF</strong> simulation using <strong>the</strong> CAL dispersion option estimates<br />

a tracer residence time on <strong>the</strong> 600 km receptor arc <strong>of</strong> 13 hours that compares favorably to<br />

what was observed (12 hours). However, <strong>the</strong> current study <strong>CALPUFF</strong> BASEA_CAL configuration,<br />

which was designed to emulate <strong>the</strong> 1998 EPA <strong>CALPUFF</strong> configuration, estimates a residence<br />

time <strong>of</strong> almost half <strong>of</strong> <strong>the</strong> 1998 EPA study (7 hours). One notable difference between <strong>the</strong> 1998<br />

EPA <strong>and</strong> <strong>the</strong> current study <strong>CALPUFF</strong> modeling for <strong>the</strong> GP80 600 km receptor arc was <strong>the</strong> use <strong>of</strong><br />

<strong>the</strong> slug option in <strong>the</strong> 1998 EPA study. Ano<strong>the</strong>r notable difference was <strong>the</strong> ability <strong>of</strong> <strong>the</strong> current<br />

version <strong>of</strong> <strong>CALPUFF</strong> to perform puff splitting, which EPA has reported likely extends <strong>the</strong><br />

downwind distance applicability <strong>of</strong> <strong>the</strong> <strong>CALPUFF</strong> model (EPA, 2003). Thus, a series <strong>of</strong> <strong>CALPUFF</strong><br />

sensitivity tests were conducted using <strong>the</strong> BASEA_CAL <strong>CALPUFF</strong>/CALMET <strong>and</strong> MMIF_12KM CAL<br />

<strong>and</strong> PG <strong>CALPUFF</strong>/MMIF configurations that invoked <strong>the</strong> slug option <strong>and</strong> performed puff<br />

splitting. Two types <strong>of</strong> puff splitting were analyzed, default puff splitting (DPS) that turns on <strong>the</strong><br />

vertical puff splitting flag once per day <strong>and</strong> all hours puff splitting (APS) that turns on <strong>the</strong> puff<br />

splitting flag for every hour <strong>of</strong> <strong>the</strong> day. The following are <strong>the</strong> key findings from <strong>the</strong> <strong>CALPUFF</strong><br />

slug <strong>and</strong> puff splitting sensitivity tests for <strong>the</strong> GP80 600 km receptor arc:<br />

• Use <strong>of</strong> puff splitting had no effect on <strong>the</strong> tracer test residence time (7 hours) in <strong>the</strong><br />

<strong>CALPUFF</strong>/CALMET (BASEA_CAL) configuration.<br />

• Use <strong>of</strong> <strong>the</strong> slug option with <strong>CALPUFF</strong>/CALMET increased <strong>the</strong> tracer residence time on <strong>the</strong><br />

600 km receptor arc from 7 to 15 hours, suggesting that <strong>the</strong> better performance <strong>of</strong> <strong>the</strong><br />

1998 EPA <strong>CALPUFF</strong> simulations on <strong>the</strong> 600 km receptor arc was due to invoking <strong>the</strong> slug<br />

option.<br />

• On <strong>the</strong> o<strong>the</strong>r h<strong>and</strong>, <strong>the</strong> <strong>CALPUFF</strong>/MMIF sensitivity tests were more sensitivity to puff<br />

splitting than <strong>CALPUFF</strong>/CALMET with <strong>the</strong> tracer residence time increasing from 6 to 8<br />

hours using DPS <strong>and</strong> to 17 hours using APS when <strong>the</strong> CAL dispersion option was specified.<br />

• The use <strong>of</strong> <strong>the</strong> slug option on top <strong>of</strong> APS has very different effect on <strong>the</strong> <strong>CALPUFF</strong>/MMIF<br />

residence time along <strong>the</strong> 600 km receptor depending on which dispersion option is<br />

utilized, with slug reducing <strong>the</strong> residence time from 17 to 15 hours using <strong>the</strong> CAL <strong>and</strong><br />

increasing <strong>the</strong> residence time from 11 to 20 hours using PG dispersion options.<br />

10

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