Marilena Ferbinteanu Cimpoesu Curriculum Vitae - Facultatea de ...

Marilena Ferbinteanu Cimpoesu
Curriculum Vitae
Nume CIMPOESU (FERBINTEANU)
Prenume MARILENA
Data si locul Bucuresti, 30.07.1968
nasterii
Grad didactic Lector
Titlul stiintific Doctor
Afiliere -Universitatea din Bucuresti, Facultatea de Chimie,
Catedra de Chimie Anorganica
-Membru al Societatii de Chimie din Romania
-Membru al Societatii de Chimie din Japonia
(CSJ-The Chemical Society of Japan)
-Membru al clubului “Alexander von Humboldt”,
Romania, in calitate de fost bursier Humboldt, Germania
Adresa Dumbrava Rosie 23, Bucuresti 70254, Romania
Telefon 004021-2103497 (office); 004021-6276943(home) 0040-
726757187 (mobile)
Fax -
e-mail mcimpoesu@yahoo.com
Domenii de cercetare:
Chimie coordinativa mono- si polinucleara: Sinteza sistemelor mono si polinucleare
cu particularitati structurale relevante analitic (afinitatea mutuala a liganzilor, sisteme cu
liganzi micsti, efecte ale chelarii, tensiunea in ciclu si topologia coordinarii). Proprietati
speciale: Cromotropism, Magnetism (lanturi alternate cu proprietati de magneti “singlechain”).
Metode speciale si strategii de sinteza in chimia coordinativa si organometalica.
Tehnici de masurare (SQUID) si interpretare a datelor magnetice (susceptibilitate,
magnetizare, DC, AC anizotropie, RPE). Analiza structurala, cristalografica si rutine
specifice metodelor de structura electronica (particularizare pe concepte ca legatura
coordinativa curba, dezalinierea perechii de electroni neparticipanti, hibridizare,
aromaticitatea ciclurilor chelatice).
Chimia clusterilor si chimie organometalica: Investigarea edificiilor moleculare
aparent contrare regulilor HSAB, ca strategie de obtinere a proprietatilor speciale.
Rationalizarea structurilor si reactiilor prin termeni esentiali ca Electronegativitate,
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Hardness, Hibridizare, Aromaticitate tridimensionala. Teorii electronice moderne (Tensor
Surface Harmonics Theory) aplicate in investigarea structurala a clusterilor.
Chimia starii solide: Termocromism si reactii in faza solida ale compusilor coordinativi.
Analiza termica si cinetica neizoterma. Studii experimentale si teoretice, modelarea
reactiilor in faza solida cu multiple etape initiate termic.
Analiza spectrala (spectre electronice, RPE, RMN, MS) a compusilor anorganici.
interpretare si modelare.
Carti (1-2 titluri):
1. Marilena Ferbinteanu, Fanica Cimpoesu, 2003, Compusi coordinativi cu
proprietati speciale, Editura Universitatii, Bucuresti, 220 pagini, ISSN 973-575-
674-9.
2. Marilena Ferbinteanu, Fanica Cimpoesu, 2002, Aspecte teoretice si practice in
chimia clusterilor, polimerilor si ciclurilor anorganice, Editura Universitatii,
Bucuresti, 150 pagini, ISSN 973-575-672-2.
Articole principale (lucrari reprezentative):
1. Ferromagnetic Single-Chain Magnet with Mn III -Mn III -Fe III Pattern Made by a Mn Salen
Analogue and Hexacyanoferrat, Marilena Ferbinteanu, H. Miyasaka, K. Nakata, F.
Cimpoesu, K. Hirao, K. Sugiura, and M. Yamashita, J. Am. Chem. Soc. 2004, submitted.
2. Mechanism of Ferromagnetic Coupling in Copper(II)-Gadolinium(III) Complexes,
J. Paulovic, F. Cimpoesu, Marilena Ferbinteanu, and K. Hirao,
J. Am. Chem. Soc. 2004, 126, 3321-3331.
3. Synthesis and Structural Studies of Two New Base Adducts of Bis (2,4pentanedionato)cobalt(II),
S. Tanase, E. Bouwman, J. Reedijk, W. L. Driessen, Marilena
Ferbinteanu, M. Huber, A. M. Mills, and A. L. Spek,
Eur. J. Inorg. Chem. 2004, 1963-1969.
4. Special Structural Features of Chelating Nitrite and β-diketonate Ligands in New
Nickel(II) Mixed Ligand Complexe., Marilena Ferbinteanu, K. Miyamoto, S. Tanase, T.
Tanaka, E. Horn and Y. Fukuda, the monography “Progress in Coordination and
Bioinorganic Chemistry”, Eds. M. Melnik and A. Sirota, Slovak Tech. Univ. Press,
Bratislava, 2003, 21-26.
5. Syntheses, Structures, and Surface Aromaticity of the new Carbaalane
[(AlH)6(AlNMe3)2(CCH2R)6] (R = Ph, CH2SiMe3) and a Stepwise Functionalization of the
Inner and Outer Sphere of the Cluster, A. Stasch, Marilena Ferbinteanu, J. Prust, W.
Zheng, F. Cimpoesu, H. W. Roesky, J. Magull, H.-G. Schmidt, M. Noltemeyer,
J. Am. Chem. Soc. 2002, 124, 5441-5448.
6. New Aspects of the Coordination Chemistry of Triazolato Ligands in The First (µ4-
Oxo)-Tetranuclear Magnesium Compound, N. C. Mösch-Zanetti, Marilena Ferbinteanu,
J. Magull, Eur. J. Inorg. Chem. 2002, 950-956.
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7. The First Basic Carboxylate with an Oxo-Centered Trinuclear Pattern of Aluminum:
[Al3(µ3-O)(µ-O2CCF3)6THF)3][(Me3Si)3CAl(O2CCF3)3]·C7H8, H. Hatop, Marilena
Ferbinteanu, H. W. Roesky, F. Cimpoesu, M. Schiefer, H.-G. Schmidt, M. Noltemeyer,
Inorg. Chem. 2002, 41, 1022-125.
8. New Synthetic and Structural Aspects in the Chemistry of Alkylaluminum-fluorides.
The Mutual Influence of Hard and Soft Ligands and the Hybridization as Rigorous
Structural Criterion, Marilena Ferbinteanu, H W. Roesky, F. Cimpoesu, M. Atanasov, S.
Köpke, R. Herbst-Irmer, Inorg. Chem. 2001, 40, 4947-4955.
9. Perspectives of the Bonding Effects in New Titanium-nitrogen Coordination
Compounds, Marilena Ferbinteanu, F. Cimpoesu, H. W. Roesky, G. Bai, N. C. Mösch-
Zanetti, in the monography “Challenges for Coordination Chemistry in the New century”,
Eds. M. Melnik and A. Sirota, Slovak Tech. Univ. Press, Bratislava, 2001, 127-132.
10. Synthesis, crystal structure and magnetic propel-ties of the cyano-bridged
heteropolynuclear complex [{(Cu(dien))2Co(CN)6}n][Cu(dien)(H2O)Co(CN)6]n 5nH2O,
Marilena Ferbinteanu, S. Tanase, M. Andruh, Y. Journaux , F. Cimpoesu, I. Strenger , E.
Riviere, Polyhedron 1999, 18(23), 3019-3025.
Comunicari stiintifice internationale:
1. Single Chain Magnets, Marilena Ferbinteanu, H. Miyasaka, M. Yamashita and F.
Cimpoesu, 4 th International Conference of the Chemical Societies of the South-East
European Countries on Chemical Sciences in Changing Times: Visions, Challenges and
Solutions, Belgrade, Serbia and Montenegro, 18-21 July 2004, oral.
2. The Mechanism of Ferromagnetic Coupling in Cu(II)-Gd(III) Complexes, F. Cimpoesu,
Marilena Ferbinteanu, K. Hirao, 4 th International Conference of the Chemical Societies of
the South-East European Countries on Chemical Sciences in Changing Times: Visions,
Challenges and Solutions, Belgrade, Serbia and Montenegro, 18-21 July 2004, poster.
3. New Orbital Mechanisms for Exchange Coupling in Jahn-Teller Type Complexes.
Vibronic and Spin Coupling. Models and Applications, F. Cimpoesu, K. Hirao H.
Miyasaka, M. Ferbinteanu, M. Yamashita, 1 th Asian Pacific Conference on Chemistry,
Okazaki, Japan, 12-15 May 2004, poster.
4. A Novel Single-Chain Magnet of Mn(III) Schiff-base Complex with Hexacyanometalate
(III) , Marilena Ferbinteanu, H. Miyasaka, K. Nakata, K. Sugiura, M. Yamashita, 84 th
Conference of the Japanese Chemical Society, Osaka, Japan, 26-29 March 2004,
poster.
5. A Novel Single-Chain Magnet of Mn(III) Schiff-Base Complex with
Hexacyanometalate(III), Marilena Ferbinteanu, invitated lecture in the 36 th Symposium
of Inorganic Materials, organizer Prof. Masahiro Yamashita, Tokyo Metropolitan
University, Department of Chemistry, Graduate School of Science, Tokyo, Japan, 27
January 2004.
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6. Chemical and Structural Particularities of New Complexes with Chelating Nitrite
Ligand, Marilena Ferbinteanu, K. Miyamoto, A. Shinohara, E. Horn, Y. Mitsutsuka and Y.
Fukuda, 53 rd International Conference on Coordination Chemistry, Yamagata, Japan,
24-26 September 2003, oral.
7. Synthesis and Chromotropic behaviour of Nickel (II) Mixed Ligand Complexes, M.
Sakamoto, K. Miyamoto, M. Ferbinteanu, C. Tanaka, E. Horn and Y. Fukuda,
53 rd International Conference on Coordination Chemistry, Yamagata, Japan, 24-26
September 2003, poster.
8. Structural studies on rigid nitrogen ligand bis[N-(2,6-diisopropylphenyl)imino]
acetonaphthene and its complexes with d 10 metal ions. U. El-Ayaan, Marilena
Ferbinteanu, S. Yamada and Y. Fukuda, 53 rd International Conference on Coordination
Chemistry, Yamagata, Japan, 24-26 September 2003, oral.
9. Particular Structural and Spectroscopic Properties in Distorted Coordination
Compounds. F. Cimpoesu, Marilena Ferbinteanu, Y. Fukuda, Y. Mitsutsuka and K. Hirao
International Conference on Molecular Spectroscopy, Kyoto, Japan, 24-27 September
2003, poster.
10. Perspectives of the bonding effects in new coordination compounds with ligands
providing a small-bite angle, Marilena Cimpoesu, invitated lecture in the 19 th Symposium
of Inorganic Materials, organizer Prof. Masahiro Yamashita
Tokyo Metropolitan University, Department of Chemistry, Graduate School of Science,
Tokyo, Japan, 21 August 2003.
11. Experimental Organometallic and Coordination Chemistry in the Key of Revisited
Fundamental Theoretical Concepts: Hybridisation, Aromaticity, Misdirected Lone Pairs,
Marilena Cimpoesu, invitated lecture in the Seminar of Inorganic Chemistry, organizer
Prof. Norimichi Kojima, The University of Tokyo, Graduate School of Arts and Sciences,
Tokyo, Japan, 26 July 2003.
12. Special Structural Features of Chelating Nitrite and β-Diketonate Ligands In The
New Nickel(II) Mixed Ligand Complexes, Marilena Ferbinteanu, K. Miyamoto, S. Tanase,
C. Tanaka, E. Horn and Y. Fukuda, 19 th International Conference On Coordination And
Bioinorganic Chemistry, Smolenice, Slovakia, 2-6 June 2003, oral.
13. Synthesis And Characterization (In Solid State and Solution) of Ni(II) Mixed Ligand
Complexes with N-alkylated Ethylenediamine (diam), β-diketonate(dike) and Halide
Anion (X), Ni(diam)(dike)X.n(solvent), M. Sakamoto, K. Miyamoto, Marilena Ferbinteanu,
C. Tanaka, E. Horn and Y. Fukuda, 19 th International Conference On Coordination And
Bioinorganic Chemistry, Smolenice, Slovakia, 2-6 June 2003, oral.
14. Structural Aspects in Distorted Coordination Compounds Formed with Small byte
angle Ligands, Marilena Ferbinteanu, invitated lecture, Workshop, organizer Prof. Ernst
Horn, Rikkyo University, Faculty of Chemistry, Department of Chemistry, Tokyo, Japan,
23 May 2003.
15. Inorganic Polymers Trough a Spectacular Case of Breaking C-O Bond by Lewis
Acidity of aluminu, Marilena Ferbinteanu, F.Cimpoesu, Herbert W. Roesky, 3rd
International Conference of the Chemical Societies of the South-Eastern European
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Countries on "Chemistry in the New Millennium-an Endless Frontier", Bucharest,
Romania, 22-25 September 2002, poster.
16. The Thermochromic Properties of the Coordination Compounds, Marilena Cimpoesu,
invitated lecture in the Sympozium of the Ochanomizu University, Tokyo, Japan, 20 June
2002.
17. Perspectives of the Bonding Effects in New Titanium-Nitrogen Coordination
Compound, Marilena Cimpoesu, F. Cimpoesu, H. W. Roesky, G. Bai, N. C. Mösch-
Zanetti, 18 th International Conference on Coordination and Bioanorganic Chemistry,
Smolenice, Slovakia, 4-8 June 2001, oral.
18. Hard and Soft Interactions in the Chemisray of Organo-Fluoro Metalates, Marilena
Ferbinteanu, H. W. Roesky, A. Stasch, F. Cimpoesu, S. Köpke, III rd International
Conference on Progress in Inorganic and Organometallic Chemistry, Polanica Zdroj,
Poland, 17-22September 2000, oral.
19. A Random Walk in the properties of metal Ion Compounds, Marilena Cimpoesu
invitated lecture in the Professor H. W. Roesky’s Group Seminar, Institut für
Anorganische Chemie, Göttingen, Deutschland, 19 June 2000.
20. Hard and Soft Interactions for Generating New Catalysts, Marilena Cimpoesu,
invitated lecture, Alexander von Humboldt, Chemie und Geowissenschaften Symposion,
Düsseldorf, Deutschland, 18-23 Februar 2000.
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