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(Mg3.09 pe2+ 0.69 pe 0.~1~0.01~~0.98)~~7.~4~~0.66)-<br />

3+<br />

greater1 (3) their AMP is less aluminous and sodlc and<br />

022P0.11 OH)^,^^. Blue-green pleochroic rims me<br />

is caldc rather than sodic-calcic; and (4) calcite, plagioclase,<br />

and sphene accur in some samples. .Dffferdistinguished<br />

by enrichment in pe2+, pe3+, and Ca aces 1 through 3 suggest metamorphism at lower 2<br />

(table 13), add compositions range from magnesiohorn- and P for the Fairbanks eclogites, which Is consistent<br />

blende to tschermakitic hornblende.<br />

withThe estimates <strong>of</strong> 540' to 590'~ and 0.55 to 0.75<br />

GAR becomes slightly less calcic toward the GPa by Swainbank and Forbes (1975).<br />

grain margins (fig. 34). The least calelc composition,<br />

represented by the formula ~ e ~ ~ ~ ~ ~ g ~ ~ ~ ~ ~ n ~ . ~ ~<br />

~o.63"l.98~e~to6"2.95~*.050~2~ * lcom edge<br />

<strong>of</strong> a grain at its contact with a blue-green pleochroie<br />

AMP rim. The E'e3'/(~1 VI +Fe<br />

3+<br />

Ti+Cr) rntlo in clinozoisite<br />

(CZO) is small and ranges from 3.0 to 4.5 atom<br />

percent. White mica is muscovite showing considerable<br />

phengite substitution. The K/(K+Na+Ca) ratio<br />

ranges from 81.6 to 86.0 atom percent, and the<br />

ca/(K+~a+Ca) ratio is no more than 0.9 percent.<br />

On the basis <strong>of</strong> GAR composition (fig. 341, thb<br />

eclwte falls within group C (eclogltes from alpinetype<br />

orogenic terranes) <strong>of</strong> Coleman and others (1965)<br />

but is near the "contactn with group B (eclogite from<br />

gneiss and migmattte terranes). Coexisting GAR and<br />

omphecite compositions are also comparable to thase<br />

at the group Clgroup B boundary (compare fig. 34 with<br />

Coleman and others, 1985, fig. 11). On the basis <strong>of</strong><br />

omphacite composition, the ecloglte Is simUar to eclogites<br />

from highpressure fietamorphic terranes,<br />

whereas the distribution <strong>of</strong> Fe /Mg between GAR and<br />

PYX suggests amphibolite- or granulite-factes terranes<br />

(Miyashiro, 1973, figs. 124, 12-51.<br />

The occurrence <strong>of</strong> biotite+Peldspar+quartzCgarnet+whlte<br />

miea gneiss (sample 79AWr93, fig. 33)<br />

associated with eclogite-appearing rubble suggests<br />

group B affinities. Further petrographic and electronmicroprobe<br />

studies <strong>of</strong> the mineralogic variations in the<br />

eelogitic rocks represented and in the associated<br />

peUtic and felsic rocks are planned to test this<br />

hypothesis.<br />

Figure 35 ilIustrates our best estimate <strong>of</strong> the<br />

pressure() and temperature (3 <strong>of</strong> metamorphism on<br />

the basis <strong>of</strong> the experimental date presently available.<br />

The omphacite +quartz assembGe constrains P<br />

to above the jdq5 Isopleth for the reaction<br />

alq&eqadelte+quartz. T is constrained by the<br />

Pe /Mg distribution between GARand PYX but must<br />

be less than the high T estimates from the EUis and<br />

Green (1979) calibration because the eclogite appears<br />

to be intercalated with pelitic sahist, which would<br />

have partially melted if 2 were above that <strong>of</strong> the<br />

reaction muscovite+K-feldsparfalbf te+quartz+vapor =<br />

liquid-just above 600'~ for these pressures (Thompson<br />

and Algor, 1977, fig. 8). Using the muscoviteparegonite<br />

solvus <strong>of</strong> Eugger and others (1972) gives a<br />

minimum T <strong>of</strong> about 530 C, but the magnitude <strong>of</strong> the<br />

effect <strong>of</strong> phengite substitution on this solvus Is<br />

unknown.<br />

The only eclogites previously described from the<br />

Yukon-Tanana Upland are group C eclogites (Swainbank<br />

and Porbes, 1975) in the Fairbanks district, about<br />

39 km southwest <strong>of</strong> the eclogite locality near Twin<br />

Buttes (fig. 33). These Pairmks district ecl<br />

distinct from the sample studied in that:<br />

GAR is almandine richer but pyroq$ poorer; (2) their<br />

PYX Is jadeite poorer, and ED=(Pe /Wg)GAR/PY is<br />

Figwe 35.-Estimated pressure (9 and temperature (T)<br />

(within box) <strong>of</strong> metamorphism for sample 79~~rlO&<br />

(fig. 33). 52 stability for reaction albite=jsdeite+<br />

quartz b from Holland (1980). jdqO and jdq isopleths,<br />

repraentkng minimum and maximum jadel?e contents<br />

observed In omphacite, calculated from model <strong>of</strong><br />

Ho)#nd (1979, 1980). Lines <strong>of</strong> constant ED=<br />

Fe /~g)=- py representing minimum and<br />

maximum v8des %served, extrapolsted from Raheim<br />

and Green (1974) (dotted Unes) and Ellis and Green<br />

(1979) (dashed lines).<br />

Whole-rouk analyses or the Pairbanks district ec-<br />

logites indicate sedimentarg protoliths. However, the<br />

distinction in mineral assemblage (difference 4) md<br />

the field relations suggest that an Igneous protolith Is<br />

more probable for the eclogite nem Twin Buttes.<br />

Swainbank and Porbes (1975) suggested that the<br />

Fairbanks district eclogite terrane Is a tectonic wln-<br />

dow. Occurrence <strong>of</strong> brecciated rocks about 1J krn<br />

south <strong>of</strong> the eclogite and associated pelitlc schist and<br />

quartzite near Twin Buttes suggests a possible tectonlc<br />

contact with the pelltic, mafic, and calc schist end<br />

quartzite to the south. Fairly good preservation in the<br />

sample from near Twin Buttes except for formation <strong>of</strong><br />

cryptocrgstaLLIne material around the PYX and blue-<br />

green rims on the AMP (possibly associated with Ter-<br />

tiary plutonlsm) suggests that thL eclogite was ex-<br />

humed quickly. More detailed mapplng and petrologic<br />

study are required to test this hypothesis, to determine<br />

the relation <strong>of</strong> this eclogite and associated rocla to<br />

adjacent metamorphic terranes, including that <strong>of</strong> the<br />

Fairbanks district, and to further assess its geologic<br />

implications.

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