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The Geography of Phytochemical Races

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2.3 Europe 41<br />

Fig. 2.22 Map <strong>of</strong> northeastern<br />

Italy and adjacent regions<br />

from which specimens <strong>of</strong><br />

Valeriana <strong>of</strong>fi cialis were<br />

obtained<br />

Table 2.5 Selected terpenes from three populations <strong>of</strong> Valeriana <strong>of</strong>fi cinalis (from Coassini Lokar<br />

and Moneghini, 1989)<br />

Compound Alps Aa Alps B Karst<br />

α-Pinene 4.59b 23.91 0.10<br />

Limonene 0.44 0.23 2.55<br />

n-Butyl valerate 0.19 0.28 2.46<br />

1,8-Cineole 4.29 3.77 6.51<br />

α-Terpineol 0.95 3.54 7.54<br />

Bornyl acetate 21.59 33.39 0.40<br />

Borneol + isoborneol 30.73 22.90 3.64<br />

Valeranal 10.15 6.52 5.60<br />

Isobornyl isovalerate 13.07 11.25 47.80<br />

Valeranone 3.04 5.28 6.75<br />

a Alps A and B are from the Apuan Alps.<br />

b Percentage composition <strong>of</strong> leaf terpenes.<br />

2.3.9 Cistus (Cistaceae)<br />

As part <strong>of</strong> a study <strong>of</strong> the secondary chemistry <strong>of</strong> members <strong>of</strong> Cistus (the rockrose)<br />

in France, Robles and Garzino (1998) examined the essential oil <strong>of</strong> C. albidus<br />

L. Plants were sampled from two areas in Provence characterized by different soil<br />

types, calcareous sites west <strong>of</strong> Marseille, and siliceous sites near Pierrefeu-du-Var<br />

and Bormes les Mimosas (PF and BM, respectively, in Fig. 2.23), which lie about<br />

60 km and 80 km to the east, respectively, in the Massif les Maures. Regardless <strong>of</strong><br />

the soil type, α-zingiberene [88] (Fig. 2.24) was the dominant component. Concentrations<br />

<strong>of</strong> other major components <strong>of</strong> the plants varied between the two soil types,<br />

as summarized in Table 2.6. Many other compounds were present in lesser amounts,<br />

but varied little between the two areas. A more recent paper by the same workers<br />

(Robles and Garzino, 2000) described an analysis <strong>of</strong> C. monspeliensis L. leaf oils,<br />

the results <strong>of</strong> which are summarized in Table 2.7.

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