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The Geography of Phytochemical Races

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2.7 North and Central America 99<br />

population near San Luis Potosi (22°10′N, 101°W) was shown to accumulate ilicic<br />

and costic acids (Higo et al., 1971) and have n = 36 (Payne, 1964).<br />

2.7.9 Gaillardia pulchella (Asteraceae)<br />

Gaillardia pulchella Foug. is a morphologically and cytologically diverse taxon that<br />

enjoys a wide distributional range, from the southeastern United States westward<br />

as far as Arizona (Fig. 2.62). Its chemistry has been the subject <strong>of</strong> numerous studies,<br />

revealing the existence <strong>of</strong> several chemotypes. <strong>The</strong> coastal chemotype, ranging<br />

from the southeastern seaboard through Florida to an area near Houston, Texas, is<br />

characterized by a set <strong>of</strong> alkaloidal derivatives exemplifi ed by pulchellidine [206]<br />

(see Fig. 2.63 for structures 206–209). <strong>The</strong> Rio Grande collection afforded the<br />

ambrosanolide spathulin [207]. Collections from Live Oak County, Texas revealed<br />

the guaianolide derivative gaillardin [208]. Plants collected in New Mexico and<br />

Fig. 2.62 Map <strong>of</strong> sites for the Gaillardia pulchella study<br />

Fig. 2.63 Compounds 206, an alkaloid, and 207–209, sesquiterpenes from Gaillardia pulchella.<br />

Compounds 210 and 211, triterpenes from Dudleya

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