Solar Grade-Silicon, Ingot, Wafer Technology and Market Trend
Solar Grade-Silicon, Ingot, Wafer Technology and Market Trend
Solar Grade-Silicon, Ingot, Wafer Technology and Market Trend
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<strong>Solar</strong> <strong>Grade</strong>-<strong>Silicon</strong>, <strong>Ingot</strong>, <strong>Wafer</strong> <strong>Technology</strong> <strong>and</strong> <strong>Market</strong> <strong>Trend</strong> (2008~2012)<br />
Figure 2.19. Tube Reactor in Joint <strong>Solar</strong> <strong>Silicon</strong> (JSSi) Process<br />
Source: Joint <strong>Solar</strong> <strong>Silicon</strong><br />
All Contents of this report remain the property of Displaybank<br />
The traditional Siemens process decomposes silane in silicon seed (U-rod),<br />
whereas the Joint <strong>Solar</strong> <strong>Silicon</strong> reactor decomposes silane in reactor’s interior<br />
space that it is called “free space reactor method”. The method supplies<br />
hydrogen <strong>and</strong> silane to the reactor’s interior <strong>and</strong> enters heat to walls to<br />
decompose silane away from the walls. Like in the Siemens process, the free<br />
space reactor method does not require equipments for silicon seed preheating<br />
<strong>and</strong> is able to prevent pollutions from graphite which composes the preheating<br />
equipments. The method uses monosilane rather than chlorosilane for raw<br />
materials because the monosilane enables low temperature processes <strong>and</strong><br />
decomposes well that it converts gasses to silicon in reactors with single<br />
process. However, the monosilane may possibly explode when it is in contact<br />
with oxygen that reactors must be designed carefully to prevent such outcome.<br />
It is also more expensive than trichlorosilane. The thermal decomposition<br />
reaction of silane is like the following.<br />
SAMPLE<br />
SiH4 -> SiH2+H2<br />
SiH2 + SiH4–> Si2H6<br />
SiH2 +Si2H6 -> Si3H8<br />
The silicon powder manufactured through reactors undergoes high density<br />
process for easy h<strong>and</strong>ling, delivery, <strong>and</strong> loading. Here, the density increases<br />
from 50g/L to 500g/L. The figure below shows silicon powder that finished the<br />
high density process. The powder is melted <strong>and</strong> produced into ingot to be<br />
manufactured into final products.<br />
Jan’09