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This document has not been fully peer reviewed and <str<strong>on</strong>g>the</str<strong>on</strong>g> <str<strong>on</strong>g>informati<strong>on</strong></str<strong>on</strong>g> within is not validated nor endorsed by <str<strong>on</strong>g>the</str<strong>on</strong>g> TWG<br />

<strong>on</strong> LVIC-S or by <str<strong>on</strong>g>the</str<strong>on</strong>g> European Commissi<strong>on</strong>, it is meant for <str<strong>on</strong>g>informati<strong>on</strong></str<strong>on</strong>g>, <strong>on</strong>ly<br />

The producti<strong>on</strong> of sodium sulphate should itself be c<strong>on</strong>sidered as a polluti<strong>on</strong> c<strong>on</strong>trol process, as<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> waste stream would o<str<strong>on</strong>g>the</str<strong>on</strong>g>rwise go to effluent [64, CEFIC-SSPA, 2004]. The quantity of <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

sodium sulphate by-product depends <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> producti<strong>on</strong> capabilities of <str<strong>on</strong>g>the</str<strong>on</strong>g> primary product and,<br />

in principle, all <str<strong>on</strong>g>the</str<strong>on</strong>g>se processes use Glauber’s salt as <str<strong>on</strong>g>the</str<strong>on</strong>g> raw material. The calcinati<strong>on</strong> of<br />

Glauber’s salt, followed by <str<strong>on</strong>g>the</str<strong>on</strong>g> crystallisati<strong>on</strong> and drying of <str<strong>on</strong>g>the</str<strong>on</strong>g> sodium sulphate always<br />

depends <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> individual layout and technical arrangements of <str<strong>on</strong>g>the</str<strong>on</strong>g> installati<strong>on</strong>s, as well as<br />

linkages to various sources of energy. Polluti<strong>on</strong> of <str<strong>on</strong>g>the</str<strong>on</strong>g> envir<strong>on</strong>ment <str<strong>on</strong>g>during</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> producti<strong>on</strong> of<br />

sodium sulphate from Glauber’s salt is very low.<br />

It should be noted, however, that <str<strong>on</strong>g>the</str<strong>on</strong>g> six main process routes for Na2SO4 producti<strong>on</strong> which have<br />

been formerly described as ‘Techniques to c<strong>on</strong>sider in <str<strong>on</strong>g>the</str<strong>on</strong>g> determinati<strong>on</strong> of BAT’ in <str<strong>on</strong>g>the</str<strong>on</strong>g> LVIC-S<br />

BREF secti<strong>on</strong> <strong>on</strong> sodium sulphate, have, in principle (with some excepti<strong>on</strong> regarding <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

Mannheim process), <str<strong>on</strong>g>the</str<strong>on</strong>g> same envir<strong>on</strong>mental benefit (i.e. <str<strong>on</strong>g>the</str<strong>on</strong>g>y use a by-product Na2SO4 which<br />

o<str<strong>on</strong>g>the</str<strong>on</strong>g>rwise would have to be discharged to waste waters). This means that <str<strong>on</strong>g>the</str<strong>on</strong>g>y reduce <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

envir<strong>on</strong>mental impact of <str<strong>on</strong>g>the</str<strong>on</strong>g> industries in which Na2SO4 is formed as a waste (or by-product)<br />

stream.<br />

They are, <str<strong>on</strong>g>the</str<strong>on</strong>g>refore, techniques to c<strong>on</strong>sider in <str<strong>on</strong>g>the</str<strong>on</strong>g> determinati<strong>on</strong> of BAT for <str<strong>on</strong>g>the</str<strong>on</strong>g> industries in<br />

which Na2SO4 is formed as a waste stream. They do not reduce <str<strong>on</strong>g>the</str<strong>on</strong>g> emissi<strong>on</strong> and energy<br />

c<strong>on</strong>sumpti<strong>on</strong> levels of <str<strong>on</strong>g>the</str<strong>on</strong>g> Na2SO4 producti<strong>on</strong> processes <str<strong>on</strong>g>the</str<strong>on</strong>g>mselves (as given in <str<strong>on</strong>g>the</str<strong>on</strong>g> ‘Current<br />

emissi<strong>on</strong> and energy c<strong>on</strong>sumpti<strong>on</strong> levels’ Secti<strong>on</strong> above) and, <str<strong>on</strong>g>the</str<strong>on</strong>g>refore, <str<strong>on</strong>g>the</str<strong>on</strong>g>y are NOT<br />

techniques to c<strong>on</strong>sider in <str<strong>on</strong>g>the</str<strong>on</strong>g> determinati<strong>on</strong> of BAT for <str<strong>on</strong>g>the</str<strong>on</strong>g> producti<strong>on</strong> of sodium sulphate.<br />

As no clear BAT c<strong>on</strong>clusi<strong>on</strong>s could be drawn for <str<strong>on</strong>g>the</str<strong>on</strong>g> producti<strong>on</strong> of sodium sulphate, it was<br />

c<strong>on</strong>sidered reas<strong>on</strong>able to remove <str<strong>on</strong>g>the</str<strong>on</strong>g> six ‘Techniques to c<strong>on</strong>sider in <str<strong>on</strong>g>the</str<strong>on</strong>g> determinati<strong>on</strong> of BAT’<br />

from <str<strong>on</strong>g>the</str<strong>on</strong>g> BAT Reference Document <strong>on</strong> LVIC-S, and to move <str<strong>on</strong>g>the</str<strong>on</strong>g> whole secti<strong>on</strong> <strong>on</strong> sodium<br />

sulphate from <str<strong>on</strong>g>the</str<strong>on</strong>g> BREF <strong>on</strong> LVIC-S to this “<str<strong>on</strong>g>Additi<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>Informati<strong>on</strong></str<strong>on</strong>g> <str<strong>on</strong>g>submitted</str<strong>on</strong>g> <str<strong>on</strong>g>during</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

<str<strong>on</strong>g>informati<strong>on</strong></str<strong>on</strong>g> <str<strong>on</strong>g>exchange</str<strong>on</strong>g> <strong>on</strong> Large Volume Inorganic Chemicals – Solid and O<str<strong>on</strong>g>the</str<strong>on</strong>g>rs Industry”<br />

document, which is associated with and closely related to <str<strong>on</strong>g>the</str<strong>on</strong>g> BREF <strong>on</strong> LVIC-S.<br />

30

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