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This document has not been fully peer reviewed and ong>theong> ong>informationong> within is not validated nor endorsed by ong>theong> TWG on LVIC-S or by ong>theong> European Commission, it is meant for ong>informationong>, only 16 Chlorination tower Iron ore HCl REACTOR FILTRATION Cl 2 (g) FeCl 3 2/3 FeCl 3 , 1/3 FeCl 2 Oxydising reactor Sludge H 2 O 2 or NaClO 3 Figure 1.9: Process diagram – production of FeCl3 based on iron ore and HCl and oxidation [CEFIC-INCOPA, 2004 #112] 1.4.3 Current consumption and emission levels Consumption and emission values in ong>theong> production of ferrous chloride are given in Table 1.8: Energy and water consumption Energy consumption GJ/t product 0.012 to 0.3 Water consumption m 3 /t product 0.25 to 13 Emissions to air CO2 Hydrogen Hydrogen chloride Iron Zinc Heavy metals Emission kg/t product 2 to 12 0.73 to 13 0.0007 to 0.01 Emissions to water Emission kg/t product 0.05 to 5 0.005 to 1.5

This document has not been fully peer reviewed and ong>theong> ong>informationong> within is not validated nor endorsed by ong>theong> TWG on LVIC-S or by ong>theong> European Commission, it is meant for ong>informationong>, only 1.4.5 Techniques to consider in ong>theong> determination of BAT Ferric chloride can be made by a variety of processes. This leads to a wide range of environmental performances. The process based on ong>theong> use of spent acid (pickle liquor) and ong>theong> process using iron ore are ong>theong> most common technologies. In ong>theong> case of ferric chloride, ong>theong> variety of equipment used is limited as ong>theong> processes are generally simple. Therefore, within a particular process, ong>theong> type and ong>theong> technology of a particular item of equipment (i.e a filter) can greatly affect ong>theong> overall performance of ong>theong> process from an environmental point of view. 1.4.6 Emerging techniques As filtration is used in almost every process, ong>theong> equipment that minimises emissions to water can be considered and, if possible, included in a new plant set-up. The manufacturing of ferric chloride is exoong>theong>rmic, ong>theong>refore heat recovery options can be examined and, if possible, included in a new process scheme. Emissions to air can be controlled via a scrubbing technique. An area for future research and development would be ong>theong> recycling of ong>theong> hydrogen. 17

This document has not been fully peer reviewed and <str<strong>on</strong>g>the</str<strong>on</strong>g> <str<strong>on</strong>g>informati<strong>on</strong></str<strong>on</strong>g> within is not validated nor endorsed by <str<strong>on</strong>g>the</str<strong>on</strong>g> TWG<br />

<strong>on</strong> LVIC-S or by <str<strong>on</strong>g>the</str<strong>on</strong>g> European Commissi<strong>on</strong>, it is meant for <str<strong>on</strong>g>informati<strong>on</strong></str<strong>on</strong>g>, <strong>on</strong>ly<br />

1.4.5 Techniques to c<strong>on</strong>sider in <str<strong>on</strong>g>the</str<strong>on</strong>g> determinati<strong>on</strong> of BAT<br />

Ferric chloride can be made by a variety of processes. This leads to a wide range of<br />

envir<strong>on</strong>mental performances.<br />

The process based <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> use of spent acid (pickle liquor) and <str<strong>on</strong>g>the</str<strong>on</strong>g> process using ir<strong>on</strong> ore are <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

most comm<strong>on</strong> technologies.<br />

In <str<strong>on</strong>g>the</str<strong>on</strong>g> case of ferric chloride, <str<strong>on</strong>g>the</str<strong>on</strong>g> variety of equipment used is limited as <str<strong>on</strong>g>the</str<strong>on</strong>g> processes are<br />

generally simple. Therefore, within a particular process, <str<strong>on</strong>g>the</str<strong>on</strong>g> type and <str<strong>on</strong>g>the</str<strong>on</strong>g> technology of a<br />

particular item of equipment (i.e a filter) can greatly affect <str<strong>on</strong>g>the</str<strong>on</strong>g> overall performance of <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

process from an envir<strong>on</strong>mental point of view.<br />

1.4.6 Emerging techniques<br />

As filtrati<strong>on</strong> is used in almost every process, <str<strong>on</strong>g>the</str<strong>on</strong>g> equipment that minimises emissi<strong>on</strong>s to water<br />

can be c<strong>on</strong>sidered and, if possible, included in a new plant set-up.<br />

The manufacturing of ferric chloride is exo<str<strong>on</strong>g>the</str<strong>on</strong>g>rmic, <str<strong>on</strong>g>the</str<strong>on</strong>g>refore heat recovery opti<strong>on</strong>s can be<br />

examined and, if possible, included in a new process scheme.<br />

Emissi<strong>on</strong>s to air can be c<strong>on</strong>trolled via a scrubbing technique.<br />

An area for future research and development would be <str<strong>on</strong>g>the</str<strong>on</strong>g> recycling of <str<strong>on</strong>g>the</str<strong>on</strong>g> hydrogen.<br />

17

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