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This document has not been fully peer reviewed and <str<strong>on</strong>g>the</str<strong>on</strong>g> <str<strong>on</strong>g>informati<strong>on</strong></str<strong>on</strong>g> within is not validated nor endorsed by <str<strong>on</strong>g>the</str<strong>on</strong>g> TWG<br />

<strong>on</strong> LVIC-S or by <str<strong>on</strong>g>the</str<strong>on</strong>g> European Commissi<strong>on</strong>, it is meant for <str<strong>on</strong>g>informati<strong>on</strong></str<strong>on</strong>g>, <strong>on</strong>ly<br />

There are no special features or limiting factors to be menti<strong>on</strong>ed [89, CEFIC-INCOPA, 2004].<br />

There is a wide range of air and water emissi<strong>on</strong>s. This depends <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> type of gas scrubber.<br />

Some scrubbers can recycle water by c<strong>on</strong>centrating hydrochloric acid and re-using it in <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

process. Therefore, waste water emissi<strong>on</strong> from scrubber water is minimised.<br />

1.1.2 Aluminium chloride (soluti<strong>on</strong>)<br />

1.1.2.1 General <str<strong>on</strong>g>informati<strong>on</strong></str<strong>on</strong>g><br />

Product Name : Aluminium chloride soluti<strong>on</strong><br />

CAS number : Not established for aluminium chloride soluti<strong>on</strong><br />

Aluminium chloride is a very comm<strong>on</strong> aluminium salt, <str<strong>on</strong>g>the</str<strong>on</strong>g> major uses of which are:<br />

4<br />

Use Applicati<strong>on</strong><br />

Water treatment As a coagulant for drinking, industrial waste and municipal waste water<br />

About 25000 t<strong>on</strong>nes of aluminium chloride (as inorganic coagulant) were produced in 2002 at<br />

three locati<strong>on</strong>s.<br />

1.1.2.2 Process descripti<strong>on</strong><br />

Aluminium chloride soluti<strong>on</strong> is formed directly by <str<strong>on</strong>g>the</str<strong>on</strong>g> digesti<strong>on</strong> of aluminium hydroxide and<br />

hydrochloric acid in a stoichiometric reacti<strong>on</strong>. The reacti<strong>on</strong> is carried out at a temperature<br />

between 100 and 110 °C. After <str<strong>on</strong>g>the</str<strong>on</strong>g> reacti<strong>on</strong>, insoluble aluminium hydroxide is removed by<br />

filtrati<strong>on</strong> and is used again at <str<strong>on</strong>g>the</str<strong>on</strong>g> beginning of <str<strong>on</strong>g>the</str<strong>on</strong>g> process. The clear liquid is c<strong>on</strong>diti<strong>on</strong>ed with<br />

water to become <str<strong>on</strong>g>the</str<strong>on</strong>g> finished product of a well defined quality.<br />

Al(OH)3 + 3HCl F AlCl3 + 3H2O<br />

The process flow diagram for <str<strong>on</strong>g>the</str<strong>on</strong>g> manufacture of aluminium chloride soluti<strong>on</strong> is given in<br />

Figure 1.3.<br />

Al(OH) 3<br />

HCl<br />

Reacti<strong>on</strong> Filtrati<strong>on</strong><br />

Unreacted Al(OH) 3<br />

Figure 1.3: Process flow diagram – manufacture of aluminium chloride soluti<strong>on</strong><br />

[89, CEFIC-INCOPA, 2004]<br />

AlCl 3

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