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Guideline for the Design and Use of Asphalt Pavements for ...

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LIQUID ASPHALT<br />

Cutback <strong>Asphalt</strong><br />

Cutback asphalts are liquid asphalts which are manufactured by adding (cutting back) petroleum solvents<br />

(also called cutter stock or diluents) to asphalt cements. They are made to reduce <strong>the</strong> asphalt viscosity <strong>for</strong><br />

lower application temperatures. Application to aggregate or pavement causes <strong>the</strong> solvent to escape by<br />

evaporation, thus leaving <strong>the</strong> asphalt cement residue on <strong>the</strong> surface. Based on <strong>the</strong> relative rate <strong>of</strong><br />

evaporation, cutback asphalts are classified into three types: Rapid Cure (RC), Medium Cure (MC) <strong>and</strong><br />

Slow Cure (SC).<br />

The type <strong>of</strong> distillate (solvent) used in <strong>the</strong>ir production determines <strong>the</strong> grade <strong>of</strong> <strong>the</strong> cutback asphalt. Rapid<br />

Cure grades are typically blended with light, highly volatile diluents, such as naphtha, that will evaporate<br />

quickly <strong>and</strong> leave a hard, viscous-base asphalt to function with <strong>the</strong> aggregate on <strong>the</strong> road. Medium Cure<br />

grades are “cutback” with a less volatile kerosene-type <strong>of</strong> solvent which evaporates more slowly leaving a<br />

base asphalt <strong>of</strong> medium hardness or viscosity. Slow-Curing blends contain a low-volatility fuel-oil type<br />

solvent <strong>and</strong> thus require <strong>the</strong> longest curing period. They leave a s<strong>of</strong>t, low-viscosity asphalt on <strong>the</strong> aggregate.<br />

Slow Cure grades are not used as much as <strong>the</strong> Rapid Cure <strong>and</strong> Medium Cure grades as it typically takes<br />

many months <strong>for</strong> <strong>the</strong>se heavy diluents to evaporate <strong>and</strong> cure. The various sub-grades within a grade <strong>of</strong><br />

cutback asphalts are determined by <strong>the</strong> amount <strong>of</strong> solvent used in <strong>the</strong>ir production.<br />

Some <strong>of</strong> <strong>the</strong> types <strong>and</strong> characteristics <strong>of</strong> cutback asphalts are also noted in Table 1-1. The table also lists<br />

some <strong>of</strong> <strong>the</strong> available grades <strong>of</strong> cutbacks.<br />

The use <strong>of</strong> cutback asphalt <strong>and</strong> its availability has been greatly reduced due to environmental restrictions<br />

(solvents evaporating into <strong>the</strong> atmosphere, causing air pollution).<br />

Emulsified <strong>Asphalt</strong><br />

An asphalt emulsion is produced by combining asphalt cement, water <strong>and</strong> an emulsifying agent through a<br />

high-shear device called a colloid mill. Hot AC is pumped into <strong>the</strong> colloid mill where it is sheared into very<br />

small droplets, typically within <strong>the</strong> range <strong>of</strong> one to ten microns in diameter. Simultaneously, an emulsifying<br />

agent, dispersed in water, is pumped into <strong>the</strong> colloid mill. The emulsifying agent is both hydrophilic (likes<br />

water) <strong>and</strong> lipophilic (likes oil/asphalt). The lipophilic part attaches itself to <strong>the</strong> asphalt particle <strong>and</strong> <strong>the</strong><br />

hydrophilic side suspends <strong>the</strong>se particles in <strong>the</strong> water medium. From <strong>the</strong> colloid mill, <strong>the</strong> asphalt emulsion is<br />

<strong>the</strong>n directed to its respective storage tank. The asphalt cement makes up from 55 to 70 percent <strong>of</strong> <strong>the</strong><br />

emulsion. Most emulsions are made with asphalt in <strong>the</strong> 100-250 penetration range.<br />

As usage <strong>and</strong> grade dictate, asphalt emulsions may contain additional stabilizers, coating enhancers, antistripping<br />

agents, solvents <strong>and</strong> break control agents that can be ei<strong>the</strong>r co-milled during production or postadded<br />

into <strong>the</strong> emulsion.<br />

There are three categories <strong>of</strong> emulsified asphalt, Anionic, Cationic <strong>and</strong> Nonionic. The emulsifying agents<br />

impart minute electrical charges on <strong>the</strong> emulsion droplets. If <strong>the</strong> droplet charge is negative, <strong>the</strong> emulsion is<br />

Anionic. A positively charged emulsion is a Cationic emulsion. Nonionic emulsions are neutral, <strong>and</strong> <strong>the</strong>ir<br />

droplets have no electrical charge. Most asphalt emulsions used in <strong>the</strong> paving industry are ei<strong>the</strong>r Anionic or<br />

Cationic. Nonionic emulsions are seldom used.

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