Spectral Unmixing Applied to Desert Soils for the - Naval ...
Spectral Unmixing Applied to Desert Soils for the - Naval ...
Spectral Unmixing Applied to Desert Soils for the - Naval ...
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Figure 3. From Green et al. (1998), this figure shows <strong>the</strong> concept behind imaging<br />
spectroscopy and how it measures a spectrum <strong>for</strong> each image component<br />
(pixel) in a satellite image.<br />
1. Electronic Processes<br />
Electronic processes are <strong>the</strong> result of changes in energy states of electrons when<br />
<strong>the</strong>y are emitted or absorbed by some material. The most common of <strong>the</strong>se are related <strong>to</strong><br />
<strong>the</strong> unfilled electron shells of transition elements such as Iron (Fe), also known as <strong>the</strong><br />
Crystal Field Effect (Clark, 1999). For transition elements, energy levels are split if an<br />
a<strong>to</strong>m is in <strong>the</strong> crystal field, allowing an electron <strong>to</strong> jump from a lower <strong>to</strong> higher energy<br />
state when an pho<strong>to</strong>n with enough energy <strong>to</strong> make up <strong>the</strong> difference between energy<br />
states is absorbed (Clark, 1999). Because <strong>the</strong> crystal field varies with <strong>the</strong> a<strong>to</strong>mic<br />
structure of <strong>the</strong> material, <strong>the</strong> splitting energy will also vary causing spectral signatures<br />
unique <strong>to</strong> an individual material (Clark, 1999; Jensen, 2007). O<strong>the</strong>r material specific<br />
electronic processes are associated with color centers, charge transfers, and conduction<br />
bands (Clark, 1999; Jensen, 2007). Charge transfers occur when <strong>the</strong>re are inter-element<br />
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