chemical physics of discharges - Argonne National Laboratory
chemical physics of discharges - Argonne National Laboratory chemical physics of discharges - Argonne National Laboratory
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where DISCUSSION OF XESULTS PERTAINING TO ATOMIC NITROGEN The observations indi,cate that duriyg decay 1 1 - = - T 0 + K [NI2 [MI with K 2 4 x cm9/sec. Neither or can be the radiative lifetime of N2(A3X3 'which is 210 sec. The differential equation describing the time dependence of 3+ d[N2(A Eu) 1 dt = ' P - L. [N2(A 3 Eu)] + I 3+ [N2(A Zu)] is 3+ where L contains all factors other than [N2(A XU)] such as collision partner concentrations, rates of radiation or diffusion, s., that are involved in processes removing N2(A3Et), and where P is the rate of production. Substituting Eq. (1) in Eq. (3) gives or Then either 3 + -t/.'o 1 [N2(A Eu) lo e (L--) = P . (4) 'a 1 L = - Ta P 1 3+ (L - [N2(A Xu) lo a (3) and P = O (5) -t/Ta , = e (6) -t/Ta In the latter eventuality L > l/ia, since neither P nor e can be negative. If L is comparable to 1/~~, it must be essentially constant in time,' while if it is large compared to l/ia, Since all constitutents of the system probably decay when the power input is stopped, would be characteristic of the decay of a reactant concentration ia involved in P to a higher power than in L, while other reactant concentrations are either constant or common to both P and L. The previous statement would be true if a product of reactant concentrations replaces a single reactant concentration. Since 1 / changes ~ ~ by almost a factor of 10 over the range of [N] used, either L >> 1/~, for small [N] and hence P/L [N2(A3E;)lo = e-t/Ta, or L
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- Page 47: 47 Absorption Spectra of Transient
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- Page 54 and 55: References I I . A.B.Callear, J.A.G
- Page 56 and 57: ._ . _-.. - , , . . ,. . The Pyrex
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- Page 65 and 66: 65 ' cause of the reduction in the
- Page 67 and 68: INTRODUCTION I' Attachment of polar
- Page 69 and 70: I 69 EXPERIMENTAL The mass spectrom
- Page 71 and 72: + Figure 1 Mixed water and methanol
- Page 73 and 74: 73 ' , radius might be expected bec
- Page 75 and 76: 75 Negative Ion Mass Spectra of Som
- Page 77 and 78: A b 1 1 I H I I I FILAMEN T CONTINU
- Page 79 and 80: 79 for positive and negative ions,
- Page 81 and 82: 51 out to answer some of the questi
- Page 83 and 84: 93 INTERACTIONS OF EXCITED SPECIES
- Page 85 and 86: L 4 I*C z 0'2 = a, a U x I m 4 m 0
- Page 87 and 88: I L I, ; > > E Fig. 3 I50 200 150 1
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- Page 93 and 94: 93 where the bar indicates values c
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- Page 99 and 100: for chemiluminescent excitation in
- Page 101 and 102: 101 Chemiluminescent Reactions of E
- Page 103 and 104: 103 All gases were taken directly f
- Page 106 and 107: 10; He: + N2 -. 2He + h': (8) whi!?
- Page 108 and 109: description for both diffusion and
- Page 110 and 111: B. Ions and Electrons I Consider a
- Page 112 and 113: ' 112 axial diffusion through the d
- Page 114 and 115: the tube walls occurs continuously
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- Page 118 and 119: 1. 2. 3. 4. 5. 6. 7. 8. 9- 10. u. -
- Page 120 and 121: 120 . Dlschorge zone Reactor zone 1
- Page 122 and 123: 122 In radiation chemistry the cust
- Page 124 and 125: 124 4. chemistry seem limited essen
- Page 126 and 127: 126 Conversion of Mixtures into Mor
- Page 128 and 129: Hydrazine Synthesis in A Silent dle
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- Page 132 and 133: 1 \ \ \ , \ , \ \ Pmer hnrity K.W.
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- Page 136 and 137: _- of ' . 8. - 7 6, Residence Time
- Page 138 and 139: 135 Ionic Reactions in Corona Disch
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