chemical physics of discharges - Argonne National Laboratory
chemical physics of discharges - Argonne National Laboratory chemical physics of discharges - Argonne National Laboratory
1' &p 400 2.0 mm 300 100 0 4 0 " 5 10 15 20 ATOMS [NI2 x (atoms/cm3) ADDED T0- 452522-47 ~ Fig. 5 The rate of decay of the Vegard-Kaplan bands as a function of the square of the nitrogen atom concentration. 4 - 20 15 IO 5 0 0 0.5 1.0 . 1.5 2.0 PRESSURE-~~H~ TA-452522-44 Fig. 6 The ressure dependence of the rate,coefficient for atom destruction of the N3(A s Et) state. 2 -- - i < / i 1
I 300 r 1 - 200 i io ;' a cn I I. 0 5 IO 15 20 I . - Fig. 7 The buildup rate of the Vegard-Kaplan bands during the excitation discharge as a function of the square of the atomic nitrogen concentration. 4 \ I I . 2.50 2.00 1.50 [N] (otoms/crn3) 0 0.5 I .o 1.5 2.0 2.5~10'~ - I I I I - - 1.00 2 3 4 5 x1026 / [NI2 (a toms /c m3I2 - T8-452522-49 The. normalized inverse intensity of the Vegard-Kaplan bands during the excitation discharge as a function of added atomic nitrogen. The discharge was run continuously.
- Page 37 and 38: 37 In our laboratory a microwave di
- Page 39 and 40: + . 4 . r 39 as well as N in a cor0
- Page 41 and 42: ION-MOIECULE REACTION RATES MEASUFI
- Page 43 and 44: 43 excitntion 2onditions so that th
- Page 45 and 46: 45 In 2 like manner Fig. 3, showing
- Page 47: 47 Absorption Spectra of Transient
- Page 50 and 51: 50 maximum fiela. In this manner, a
- Page 52 and 53: 52 3 % %- %- 5- a- 7 h W P H 0 L v)
- Page 54 and 55: References I I . A.B.Callear, J.A.G
- Page 56 and 57: ._ . _-.. - , , . . ,. . The Pyrex
- Page 58 and 59: 58 0 0 0 VI J > I cv . u H a
- Page 60: .... . 0 2 e I / m 0 H F4 : 1
- Page 63 and 64: \ 0.9 0.8 0.7 06 0.5 0.4 0.3 0.2 01
- Page 65 and 66: 65 ' cause of the reduction in the
- Page 67 and 68: INTRODUCTION I' Attachment of polar
- Page 69 and 70: I 69 EXPERIMENTAL The mass spectrom
- Page 71 and 72: + Figure 1 Mixed water and methanol
- Page 73 and 74: 73 ' , radius might be expected bec
- Page 75 and 76: 75 Negative Ion Mass Spectra of Som
- Page 77 and 78: A b 1 1 I H I I I FILAMEN T CONTINU
- Page 79 and 80: 79 for positive and negative ions,
- Page 81 and 82: 51 out to answer some of the questi
- Page 83 and 84: 93 INTERACTIONS OF EXCITED SPECIES
- Page 85 and 86: L 4 I*C z 0'2 = a, a U x I m 4 m 0
- Page 87: I L I, ; > > E Fig. 3 I50 200 150 1
- Page 91 and 92: where DISCUSSION OF XESULTS PERTAIN
- Page 93 and 94: 93 where the bar indicates values c
- Page 95 and 96: 'I i 'I 0 2. 4 6 8 2 [ N]* x' I 0-2
- Page 97 and 98: Fig. 14 IO 8 6 4F [NO] x IO-" (mole
- Page 99 and 100: for chemiluminescent excitation in
- Page 101 and 102: 101 Chemiluminescent Reactions of E
- Page 103 and 104: 103 All gases were taken directly f
- Page 106 and 107: 10; He: + N2 -. 2He + h': (8) whi!?
- Page 108 and 109: description for both diffusion and
- Page 110 and 111: B. Ions and Electrons I Consider a
- Page 112 and 113: ' 112 axial diffusion through the d
- Page 114 and 115: the tube walls occurs continuously
- Page 116 and 117: E2R M ' $6"
- Page 118 and 119: 1. 2. 3. 4. 5. 6. 7. 8. 9- 10. u. -
- Page 120 and 121: 120 . Dlschorge zone Reactor zone 1
- Page 122 and 123: 122 In radiation chemistry the cust
- Page 124 and 125: 124 4. chemistry seem limited essen
- Page 126 and 127: 126 Conversion of Mixtures into Mor
- Page 128 and 129: Hydrazine Synthesis in A Silent dle
- Page 130 and 131: {;I . - . .. . - .., . . .. _- .. .
- Page 132 and 133: 1 \ \ \ , \ , \ \ Pmer hnrity K.W.
- Page 134 and 135: . I operating fact that the sloGe i
- Page 136 and 137: _- of ' . 8. - 7 6, Residence Time
I 300<br />
r<br />
1<br />
- 200<br />
i io<br />
;' a<br />
cn<br />
I I.<br />
0 5 IO 15 20<br />
I . -<br />
Fig. 7 The buildup rate <strong>of</strong> the Vegard-Kaplan bands during the excitation discharge<br />
as a function <strong>of</strong> the square <strong>of</strong> the atomic nitrogen concentration.<br />
4<br />
\<br />
I<br />
I .<br />
2.50<br />
2.00<br />
1.50<br />
[N] (otoms/crn3)<br />
0 0.5 I .o 1.5 2.0 2.5~10'~<br />
- I I I I -<br />
-<br />
1.00<br />
2 3 4 5 x1026<br />
/ [NI2 (a toms /c m3I2<br />
-<br />
T8-452522-49<br />
The. normalized inverse intensity <strong>of</strong> the Vegard-Kaplan bands during the<br />
excitation discharge as a function <strong>of</strong> added atomic nitrogen. The discharge<br />
was run continuously.
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