chemical physics of discharges - Argonne National Laboratory

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.... . 0 2 e I / m 0 H F4 : 1
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)i 1 reesonably complete and accura
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3 inquire about the component of ve
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4 I I 5 To find (t2)av, we assume t
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\ vnich, it is noted can be negativ
Page 9 and 10: I 7 than or smaller than the second
Page 11 and 12: i I i I I I ) ) i L , I I . INT1:OD
Page 13 and 14: 13 field per electron is and per co
Page 15 and 16: . 11. 5. CharRe-Transfer and Ion-Mo
Page 17 and 18: 17 In the followin:: sections much
Page 19 and 20: above. With that EIN, an estimate o
Page 21 and 22: 21 region in w!iich large, nighlv l
Page 23 and 24: i ’ understanding: 23 (a) Electro
Page 25 and 26: Obviously, the secondary ion must h
Page 27 and 28: 27 (22) Franklin, J. L., Munson, M.
Page 29 and 30: Tables 1-6 present examples of rela
Page 31 and 32: Table 8 Some Ions Formed by Process
Page 33 and 34: 33 velocity of the reacting partn r
Page 35 and 36: 35 must be added to the Langevin cr
Page 37 and 38: 37 In our laboratory a microwave di
Page 39 and 40: + . 4 . r 39 as well as N in a cor0
Page 41 and 42: ION-MOIECULE REACTION RATES MEASUFI
Page 43 and 44: 43 excitntion 2onditions so that th
Page 45 and 46: 45 In 2 like manner Fig. 3, showing
Page 47: 47 Absorption Spectra of Transient
Page 50 and 51: 50 maximum fiela. In this manner, a
Page 52 and 53: 52 3 % %- %- 5- a- 7 h W P H 0 L v)
Page 54 and 55: References I I . A.B.Callear, J.A.G
Page 56 and 57: ._ . _-.. - , , . . ,. . The Pyrex
Page 58 and 59: 58 0 0 0 VI J > I cv . u H a
Page 62 and 63: 62 The effect of adding O.O* xenon
Page 64 and 65: 64 for the probe facing the cathode
Page 66 and 67: 66 ATTACHMENT OF MOLECULES WITH HIG
Page 68 and 69: free energy and entropy change of s
Page 70 and 71: 70 RESULTS AND DISCUSSION + 1. Comp
Page 72 and 73: 72 One might suspect that under the
Page 74 and 75: z 0 c a 60 2 40 0 2 U + 2 5 20 M 0
Page 76 and 77: 76 variable from 0 - 100 volts. The
Page 78 and 79: z" 0- a? Q zc c rr) 'I
Page 80 and 81: 80 Possible Modes of Fragmentation
Page 82 and 83: 82 12. R. W. Kiser, Introduction to
Page 84 and 85: 84 This paper describes experiments
Page 86 and 87: Pig. 2 z w l- 4 W a 1.0 0.9 0.8 0.7
Page 88 and 89: 1' &p 400 2.0 mm 300 100 0 4 0 " 5
Page 90 and 91: E E
Page 92 and 93: 92 closely follows 1 / in ~ depende
Page 94 and 95: 94 deactivation. Hence, some specie
Page 96 and 97: [NO] x IO-" (molecules/cm3) . 18- 4
Page 98 and 99: O-‘ The initial decrease of the s
Page 100 and 101: 100 The existence of the 6 bands an
Page 102 and 103: 1.8 0.21 I Titrotion with Np 01 391
Page 104: should be possible to evaluate k an
Page 107 and 108: THE MATHEMATICS OF STEADY-STATE DIF
Page 109 and 110: divided into four c.ases: Case I. D
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VI. I+ = 2 [ 1 - p2 ] 4 111 when: I
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I I 1 I I I \ Thus, kA(c - c;) = 2
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Ywalls;s lo-', y'end plate = and kh
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117 V. NOTATION Del operator (vecto
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L - 2 A = - R MI2 - L T = a+- R v R
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c i I I t \ 121 I Radiation Chemist
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123 3. energy and electronic.energy
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Inorganic Synthesis with Electric D
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i \ ’. I i t 127 Atoms arid radic
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+xiip.ni +xmi.ng ca iscity of trie
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I I t I, '\ I 'a downstream from th
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. a b c liqqid *iea.ctor L.!n/iLWH
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On the other hand, if hydrazine is
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i 137 A'ae rcsu'l'cs, lor tiie ca.
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139 latter to attain a constant val
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N2 + + H20 d H20 19 + N2, c?H = -3.
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I Ii ZT PRESSURE IN TORR FOR 02+ IO
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As expected from the previous secti
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\ . 147 In Our experimental work, w
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i I / ' I ", m a 2 k F4 a I cu
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151 identity of each cf the fractio
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0 0 AI r 0 z a rc) I Z c. * I 0 z 0
Page 156 and 157:
156 The Dissociation of Metal Halid
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Table 2 Dissociation of NaCl in H2
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160 Group I11 compounds. No in esti
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162 EXPERIMENTAL WORK Apparatus. Th
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164 apparatus for 10 min to remove
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166 (a) Filament Emerging From Brok
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la lb H&i GASFLOW GROUND IC ‘-0 G
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1 6 170 Fig. 5 Filaments Produced a
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172 the formation of small particle
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Fig. 6 Longitudinal Cross Section o
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4 176 Fig. 8 Boron-Coated Quartz Mo
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5. F. Weintraub, Trans. Am. Electro
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160 change in field through the cor
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Deposition Utilizing Altcrnating Cu
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184 Bromine was a product when heli
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125 I I The C'orol;:~. In tiic Iiig
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188 obtained in the experiments pre
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0 5 .d 3 v) * .d 3 0 u a 6 .d E *g
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192 (a) 604x Fig. 7 Boron Deposit o
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N LI Y 0) ucd + 194 mol 0 rl 7 s I
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(-1) \'ariation of 1'l;iting Condit
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H2 --1 DE-OXO DRYING TOWER TAKE-UP
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.- c 0 c m A ' r n rn C .d 44 C 0 V
Page 202 and 203:
202 CONCLUSIONS Chemical reacticns
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and type of reaction products, (2)
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206 RESULTS AND DISCUSSION Prelimin
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chamber within the boundaries of th
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21 0 References 1. R. A. Mickelson,
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212 the principal axis 43 cm from t
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214 states of molecular oqgen are a
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. 216 the output coil further reduc
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- Tracer Fe59 Fe59 ' ~e75 se75 ,887
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220 THE EFFECT OF CORONA ON THE REA
Page 222 and 223:
222 Figure 1.- Unit for studying ch
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224 Figure 3.- Siemen's type reacto
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J 4 226 ( 1 Table 1.- Factorial des
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228 W h 3 tn .r( w rn 5 w W > 3 U 9
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230 The decrease in equilibrium con
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232 9. Glockler, G., and S.C. Lind.
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234 The Plasma Induced Reaction of
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236 Results and Discussion When hyd
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238 The extensive literature of "ac
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( rot-1 -!y-roccrbon) 240 xprr2nc &
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242 result is well within the range
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244 RESULTS Figure 1 shows the resu
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20 15 IO 5 0 0 0 L 0 0 I 2 3 4 TIME
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d r- 0 r- ,-I d N 2 N 2 co Ln N 0 m
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250 TABLE 2. - Effect of adding wat
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252 One unusual finding of Epple an
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254 RADIOFREQUENCY ELECTRODELESS SY
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256 with a helium mass spectrometer
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Spectroscopy Run 70 Element Found C
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Acknowledgement 260 The authcrs are
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2152 TOLUENE ULTRAVIOLET EMISSION P
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254 A summary of the products forme
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1. 266 PARTIAL MASS SPECTRA OF mn B
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significant reaction int-ermedia te
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270 R .ACTION OF 'bI.4LEI.C J.NI?Y?
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~ tation 272 It is reasonable to ex
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274 The Polymerization of Benzene i
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276 Figure 1 czb Raoio Frequency Di
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h B C D 2-'? Figure 2. Infrared Spe
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280 Both ionic and free radical mec
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INTRODUCTION Chemistrv of Electrica
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254 removed from the glass surfaces
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t- z W 0 LL W 4 2 LL w 1.0 O.! 5 -
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'603 ~---~ _-_- T_--r.- Figure 5 10
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230 . . One of the unexpected resul
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i .; Chemical Engineering Aspects o
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ELECTRODE ARRANGEMENT PLRALLEL CO-A
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295 '' that they can be sustained a
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\ , , ~ ~~ - Consecutlve Reactlons
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05 1.0 15 5 Residence Time 7x10 hr.
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J I i' i P L iqud i Gas
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Acknowledgements . 303 The author i
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1 f / I 7 \ i/ '1:s The objectives
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i I. r >- .i between the electrodes
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\ / ’\ i Reactor I 300 The corona
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I 1 311 voltage divider giving an a
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31 4 ,Tet. - ~2H2 CK4 (or other hvd
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W v) a m 0 0 0 I e z v, a ? an a 0
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318 FIGURE 4 I
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0 0 0 0'0 \ D M . S ( C ) h l l l ;
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4 10 I,
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324 5 Toes u? linearallv with the K
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pl
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Under propran carried on at the.Res
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330 PPTRFKCCS 1. Leutner, 1'. l!. &
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INTRODUCI'ION 332 PRODUCl'ION OF BY
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335 I I I I I I I I 1 1 0.12 - - -
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3.0 2.5 2.0 H2'N2 15 3. - I .o Q5 '
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8 enthalpy dependence are not what
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340 . Gas flaws except for methane
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* L 1 1 1 1 I I 1 1 I I I U - 0.10
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344 Because of the use of diluent a
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about half the dlamcter of the jet
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348 and 1 atm, which were generated
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350 PLASMA COMFOSITION 1 Thermochem
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352 appeared in the literature. O'H
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354 flow rate insured good plasma s
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.. to an unmeasured small qusntity
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358 Ccxposition at the Assumed Free
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360 The phenomena ir. t:te pias::.&
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14. 15. Lc . 17. 18. 19 * 20. 21. 2
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THE CONVERSION OF i.iEEIHAiW IN AN
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_r 333 THERMAL CRACKING OF LOW-TEMP
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Distribution and yield rates of pro
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367 used as blnders, with different
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369 ' i 1. REFERENCES Berber, John
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I 7 /* i ,I { \ J 7 1/ r-' I Ia Jd
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I' p' / ! 2' 9' c u .r( Y a e, .r(
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FIGURE 375 I I I I I I I I I I I 0
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I , 1 1 I 4 9 I 1' i J 20 0 377 Lll
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Process Descrivtion 379 Figure 1 sh
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381 The bench and pilot plant opera
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383 ash content of the initial high
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385 Referencee 1. Bloomer, W. J., a
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I .- 4 -C .- .- J u 0 -- 0 N - In V
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. UI m rs m 389 . . . . t u 0 - r -
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9' -7 .I \ f- P , / ,/- 391 TABLE5
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THE HEAT OF REACTION?% HYDROGEN AND
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1 I i Design of a hydrogasification
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i Ij EPERENCES CITED 307 HJ7drOgen
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I i / - . 399 . . . I . 2’ 0 H fi
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I20 0 zo -0 SO 00 100 110 110 160 I
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3 1 403 In the Catalytic Degussa pr
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’f ’f \ ? i i k > / f j I 405 T
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I b 1 I Table 2.- Data from Tests w
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409 ECONOMIC EVALUATION The Bureau
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W 0
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Figure 3. Hydrogen cyanide reactor.
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C :G-l I I 00 1,100 1,200 TEMPERATU
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417 h6SSBAUER SPECTROSCOPY OF IRON
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I n \D r- m d c d rl rl n . aJ 2 C
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L. 421 minutes, yielding c 600,000
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I 1 1 \ ......... ...U ...... .."."
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; i 1 1 1 finely conminuted samples
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,' I t f I i I 1 $- i h 4 m 3 1 d =
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CONCLUSION 429 In sumnary, several
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-5) Sprenkel-Se@ E.L. and Hanna S.S
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1133 REACTIONS OF COAL AND RElATED
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435 interpretation of the data, Ar
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437 tube divided by a fritted Vycor
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439 Deuterium Oxide-Argon Discharge
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I2 c C 01 ? IO e 6 LL 0 z 13 0 0 hv
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443 A PPA RA TUS The corona reactor
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Product 445 TABLE 1 Product Dstribu
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I f I I " I I - 447 ~. Figure 3 Ana
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j , i 449 i 1' phenyl or benzyl sub
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Polymeric Products The material whi
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453
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1' b Scheme I fulvene 455 FIGURE 6
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- . .. . - . . . - 457 brown benzen
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459 14 G. J. Jam, J. Chem. Phys., 2
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461 fed into the vaporizer at a cer
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i 453 energy yield than for the oth
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Ldd ffl cc 3 .I+ X z \rl M O C - 0
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HYDROCARBONS AND CllRBON FROM A ROT
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J i I i I 469 The d-spacings ob ain
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Arc Enthalpy ,-) - 2500 Amps Field
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473 THE REARRANGEMENT OF METHANE AN
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4 i J 1 i 475 is due to C-H stretch
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1 I I / 10000 Y 1 - I before di sc
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L t 479
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TA?.LE 1, - StratigraphiL po:itio;.
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1. 2. 3. 4. 5. TABLE 3. - Carbowl a
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i I I , r t \ .. 4 3 I I I I I I 1
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487 ELECTRICAL PROPERTIES OF IODINE
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489 on the ovcrall electrical prope
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3' I / 3 2 b V t 491 log p = log pJ
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i' I Y ' 493 .. 10E.G ~r,~-l {i;ig.
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d :- / I i' I 495 :"ne ~CIJ hznd A:
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497 a stable complex where conducti
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499 (it Lnk>;t,icC,i: ii., ani k:ta
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'/ 925°C. x lO"2 Sn.:>Lc SL>." "Io
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503
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505 up” / U d L .-
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507 c
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I' i i C .. . i? 2 s
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, 513 THE ELECTRON SPIN RESONANCE S
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I ./ i i L \ Y' J J / 51-5 TABLE I
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z I 51.7 radicals in coals and char
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J 519 i I \ d i L 300 400 500 600 7
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521 INFRARED SPECTRA OF OXYGEN-18 L
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523 AV, cm-1 Benzoic acid (monomer)
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Y
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The phenol chars also showed no shi
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529 Recovery of Nitrogen Bases with
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I 1 I i i I The ionization constant
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1 i 533 1, I I The use of the param
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t '. I 1 3. \ 4. I 5. / i \ t J 1,
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537 I Table 111 E Extraction of Pyr
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.. 539 Table VI11 Pyridine Conceqtr
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limelight which was produced bG4kea
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I I 1 543 - , The phosphor ijas coa
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\ 'i 2 w 8 ?N4"?? I? IC9 t-OO+r(N 0
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I i t \ I/' t I activated calcium o
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I 15. ',Jise, H. and Rosser, W. ,,A
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B 549 15- '-Jise, H. and Rosser, W.
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I 0 I I I I 1 I I I I 0 R 2gDOc- 0
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1 2.2 2.0 0.8 0.6 0.4 553 0 2 4 . 6
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555 A RAPID, SIMBLE METhOD FOR THE
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557 and -k (%)= h (t-ts) AT f =R So
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559 thermocouple (x = 0; r = 0) may
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1 I A An ''P 'H I 'h I k ma "r Q R
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X 563 STANDARD CYLINDRICAL BRIQUETT
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