chemical physics of discharges - Argonne National Laboratory

chemical physics of discharges - Argonne National Laboratory chemical physics of discharges - Argonne National Laboratory

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5 56 then t = to when e = 0 2) the final temperature of the briquette will be the temperature of the surroundings : I therefore t = t, when e = *go 3) there is no heat flow across the central plane because of symmetry: { I consequently -k (2;) - = 0 at x 0 The heat balance on the briquette surface is made by equating heattrans- ferred to the surface by conduction with heat transferred from the surfac by convect&,on.. In differential form, the heat balance is: ' -k dt = h (t - t,) at x = +a . (a4 % Newman') showed that the solution to Equations (1) through in terms of a dimensionless temperature ratio Yx is: ma (I+$ ma2 +ma) cospn where An= and pn are defined as the first, second, third, etc., roots of cendental equation: Pn TAN pn - I /ma = 0 The surface to solid thermal resistahce ratio, ma, ma = k/ha and Xa is defined as: xq = ae/a2 where the thermal diffusivity is: a = k/p Cp (5) (5) expressed the trans- Similarily , considering radial heat transfer , the .radial briquettl heat balance is The initial condition equation is: toto WHEN' 8=0 The final temperature equation is: t= 1, WHEN 8. - The boundary condition equations are: -k (g)=O AT r=O (7) (12) i

557 and -k (%)= h (t-ts) AT f =R Solving Equations (11) through (15) gives: and Pn ar,e the first, second, third, etc., roots of the equation: and . . PnJI(fin) - I/mr Jo(Pn) =.O The surface to solid thermal resistance ratio, mr is I x, = a8/R2 ~ and is : (18) frIr = k/hR (19 1 The complete differential equation for the case shown in Fig. 1 the solution to Equation (21) is: , eqn. 22 becomes: . . I If the center temperature defined at r = 0, x = 0 is tc, then tC’+S Yc= - = Yr to ’tS Y, where y, 1 and YX are evaluated at r = 0 and x = 0. i The preceding mathematical analysis shows that the rate of cooling, lor change in center temperature for a cyclindrical briquette is a function I of, time (8 ) , density ( e) , thermal conductivity (k) , the surface heat ) transfer coefficient (h) , specific heat (C,) and the briquette dimensions I as expressed by Equation (23). The experimental technique can now be described in terms of th; ~p~vious discussion. If the change in center temperature with time is Rsa- ,sued experimentally for a material of known thermal and physical prop- ‘erties (standard briquette) , the surface heat transfer coefficient can be calculated from Equation (23), since it is the only unknown. (20)

5 56<br />

then t = to when e = 0<br />

2) the final temperature <strong>of</strong> the briquette will be the temperature <strong>of</strong><br />

the surroundings : I<br />

therefore t = t, when e = *go<br />

3) there is no heat flow across the central plane because <strong>of</strong> symmetry: {<br />

I<br />

consequently -k (2;) - = 0 at x 0<br />

The heat balance on the briquette surface is made by equating heattrans-<br />

ferred to the surface by conduction with heat transferred from the surfac<br />

by convect&,on.. In differential form, the heat balance is: '<br />

-k dt = h (t - t,) at x = +a<br />

. (a4 %<br />

Newman') showed that the solution to Equations (1) through<br />

in terms <strong>of</strong> a dimensionless temperature ratio Yx is:<br />

ma<br />

(I+$ ma2 +ma) cospn<br />

where An= and<br />

pn are defined as the first, second, third, etc., roots <strong>of</strong><br />

cendental equation:<br />

Pn TAN pn - I /ma = 0<br />

The surface to solid thermal resistahce ratio, ma,<br />

ma = k/ha<br />

and Xa is defined as: xq = ae/a2<br />

where the thermal diffusivity is: a = k/p Cp<br />

(5)<br />

(5) expressed<br />

the trans-<br />

Similarily , considering radial heat transfer , the .radial briquettl<br />

heat balance is<br />

The initial condition equation is:<br />

toto WHEN' 8=0<br />

The final temperature equation is:<br />

t= 1, WHEN 8. -<br />

The boundary condition equations are:<br />

-k (g)=O AT r=O<br />

(7)<br />

(12) i

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