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chemical physics of discharges - Argonne National Laboratory

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4<br />

I<br />

I<br />

5<br />

To find (t2)av, we assume that collisions are random events and the collision<br />

frequency is independent <strong>of</strong> speed. We can then write that the probability <strong>of</strong> a<br />

collision occurring in the interval t to t + dt following the precdding collision is<br />

. .<br />

for which the average value <strong>of</strong> t2 is 2@ where< = 112 is the mean collision time.<br />

Eq. (11) then becomes<br />

a&#<br />

t2.<br />

= ma-t<br />

If we also average over all speeds <strong>of</strong> electrons and neglect some <strong>of</strong> the finer pohts<br />

<strong>of</strong> statistics, Eq. (13) becomes<br />

where A is the mean free path and c is the mean speed <strong>of</strong> the electrons.<br />

This quantity, in the steady state, will equal the right hand side <strong>of</strong> Eq. (7)<br />

averaged over all electrons. If we let d.ls 1 -2 c<br />

2<br />

Thus we would expect that the mean speed would be given by<br />

-<br />

and the mean energy <strong>of</strong> the electrons in the steady state by<br />

(13)

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