chemical physics of discharges - Argonne National Laboratory
chemical physics of discharges - Argonne National Laboratory chemical physics of discharges - Argonne National Laboratory
4 where 0 is the angle of deflection of the electron in the collision. If the scnttering is isotropic (as it close1.v approximates at low energies) then the energy loss in a collision averaged over angle is , where for convenience we let 2m/M = h. We would expect a steady state ultimately to be achieved between the electron energy picked up from the electric field between collisions and the energy transmitted from the electron tc the heavy particles through the collisions. We proceed to evaluate these separately. For simplicity we assume that the collision frequency is independent of speed of the electrons. Since the r'--tric field acts only in the z direction, all the increase in kinetic energy of an electron will occur through increasing the z component of its velocity which is given by where voz is the value of vz immediately following the collision and t is the time elapsed since the last collision and a = (q/m)E. The energy picked up will be If we now average over all angles of direction of motion immediately following the last collision, '-0 so that If we now average over all collision times, Eq. (10) becomes I (9) I , 1
4 I I 5 To find (t2)av, we assume that collisions are random events and the collision frequency is independent of speed. We can then write that the probability of a collision occurring in the interval t to t + dt following the precdding collision is . . for which the average value of t2 is 2@ where< = 112 is the mean collision time. Eq. (11) then becomes a t2. = ma-t If we also average over all speeds of electrons and neglect some of the finer pohts of statistics, Eq. (13) becomes where A is the mean free path and c is the mean speed of the electrons. This quantity, in the steady state, will equal the right hand side of Eq. (7) averaged over all electrons. If we let d.ls 1 -2 c 2 Thus we would expect that the mean speed would be given by - and the mean energy of the electrons in the steady state by (13)
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4<br />
where 0 is the angle <strong>of</strong> deflection <strong>of</strong> the electron in the collision. If the<br />
scnttering is isotropic (as it close1.v approximates at low energies) then the<br />
energy loss in a collision averaged over angle is ,<br />
where for convenience we let 2m/M = h.<br />
We would expect a steady state ultimately to be achieved between the electron<br />
energy picked up from the electric field between collisions and the energy transmitted<br />
from the electron tc the heavy particles through the collisions. We proceed to<br />
evaluate these separately. For simplicity we assume that the collision frequency<br />
is independent <strong>of</strong> speed <strong>of</strong> the electrons.<br />
Since the r'--tric field acts only in the z direction, all the increase in<br />
kinetic energy <strong>of</strong> an electron will occur through increasing the z component <strong>of</strong> its<br />
velocity which is given by<br />
where voz is the value <strong>of</strong> vz immediately following the collision and t is the time<br />
elapsed since the last collision and a = (q/m)E. The energy picked up will be<br />
If we now average over all angles <strong>of</strong> direction <strong>of</strong> motion immediately following the<br />
last collision, '-0 so that<br />
If we now average over all collision times, Eq. (10) becomes<br />
I<br />
(9) I ,<br />
1