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chemical physics of discharges - Argonne National Laboratory

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COAL DEASH& AND HIGH-PURITY COKE<br />

Ward J. Rloamer , The Lummus Company, Newark, Ne J, and<br />

F, L, Shea, Great Lakes Rasearch Corp., Elizabethton, Tennereea<br />

I--" tLC A O ~ Ut C 132<br />

In 1957, The Lummus Company and Great Lakee Carbon<br />

Corporation began a joint investigation into the qse <strong>of</strong> coal<br />

as a source <strong>of</strong> high-purity coke. The process involved the pro-<br />

duction <strong>of</strong> a low-ash, low-sulfur deaohed coal ao1,uaion from<br />

high volatiie bituminous coal, and the conversion <strong>of</strong> this coal<br />

solution into coke using a modification <strong>of</strong> the Lummus delayed<br />

coking operation,<br />

Experimental work on a bench scale was initiated in<br />

1953 and completed in 1961. The experimental stope was expanded<br />

to include the production <strong>of</strong> deashed coal as well ae the high-<br />

purity coke in either 'combined or alternate operetianso<br />

Bench programs were carried oat on several scales <strong>of</strong><br />

ogeration. A contifiuous (block operation) pilot plant was<br />

built and operated to conf%rm the bench work. This unit was cap-<br />

able <strong>of</strong> processing coal continuously at approximately 200 pounds<br />

per hour through the filtration step. At this point, the filtrate<br />

was stored for further continuous proceseing to either drashed<br />

coal product (performed in 150-200 pound quantities) or high-<br />

purity cake (500 pound quantities) .,<br />

-<br />

S unna rv<br />

A process has been developed to upgrade the quality <strong>of</strong><br />

coal to a low-ash, low-sulfur, low-chloride product, As a fuel,<br />

this material would result in reduced capital and operating coati<br />

for power stations, Investment costs would be reduced, due to<br />

the higher heating value and cleaner fuel. Operating costs would<br />

be reduced by charges associated with the transportatfon <strong>of</strong> ash,<br />

ash hacdling and disposal costs, lower maintenance coetr, and fly<br />

ash removal costsc The substantial reduction in eulfur, ash, and<br />

volatile matter would greatly minimize air pollution.<br />

Other potential applications are for use in gas turbine#,<br />

as a reductant, as a raw material for synthesis gas, aa an ingredien<br />

ia preparing coal blends for metallurgical coke, or for high-purity<br />

coke.<br />

)'<br />

The economic potential <strong>of</strong> the process in its present stage '<br />

<strong>of</strong> development is covered in Table 5. The process has certain i<br />

aspects requiring sustained demonstration efforts to obtain firm<br />

econonic bases.<br />

1.

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