chemical physics of discharges - Argonne National Laboratory

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I- I - t d m a .rl Y x c, t-' d k
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)i 1 reesonably complete and accura
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3 inquire about the component of ve
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4 I I 5 To find (t2)av, we assume t
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\ vnich, it is noted can be negativ
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I 7 than or smaller than the second
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i I i I I I ) ) i L , I I . INT1:OD
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13 field per electron is and per co
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. 11. 5. CharRe-Transfer and Ion-Mo
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17 In the followin:: sections much
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above. With that EIN, an estimate o
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21 region in w!iich large, nighlv l
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i ’ understanding: 23 (a) Electro
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Obviously, the secondary ion must h
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27 (22) Franklin, J. L., Munson, M.
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Tables 1-6 present examples of rela
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Table 8 Some Ions Formed by Process
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33 velocity of the reacting partn r
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35 must be added to the Langevin cr
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37 In our laboratory a microwave di
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+ . 4 . r 39 as well as N in a cor0
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ION-MOIECULE REACTION RATES MEASUFI
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43 excitntion 2onditions so that th
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45 In 2 like manner Fig. 3, showing
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47 Absorption Spectra of Transient
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50 maximum fiela. In this manner, a
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52 3 % %- %- 5- a- 7 h W P H 0 L v)
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References I I . A.B.Callear, J.A.G
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._ . _-.. - , , . . ,. . The Pyrex
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58 0 0 0 VI J > I cv . u H a
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.... . 0 2 e I / m 0 H F4 : 1
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\ 0.9 0.8 0.7 06 0.5 0.4 0.3 0.2 01
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65 ' cause of the reduction in the
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INTRODUCTION I' Attachment of polar
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I 69 EXPERIMENTAL The mass spectrom
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+ Figure 1 Mixed water and methanol
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73 ' , radius might be expected bec
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75 Negative Ion Mass Spectra of Som
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A b 1 1 I H I I I FILAMEN T CONTINU
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79 for positive and negative ions,
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51 out to answer some of the questi
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93 INTERACTIONS OF EXCITED SPECIES
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L 4 I*C z 0'2 = a, a U x I m 4 m 0
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I L I, ; > > E Fig. 3 I50 200 150 1
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I 300 r 1 - 200 i io ;' a cn I I. 0
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where DISCUSSION OF XESULTS PERTAIN
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93 where the bar indicates values c
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'I i 'I 0 2. 4 6 8 2 [ N]* x' I 0-2
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Fig. 14 IO 8 6 4F [NO] x IO-" (mole
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for chemiluminescent excitation in
Page 101 and 102: 101 Chemiluminescent Reactions of E
Page 103 and 104: 103 All gases were taken directly f
Page 106 and 107: 10; He: + N2 -. 2He + h': (8) whi!?
Page 108 and 109: description for both diffusion and
Page 110 and 111: B. Ions and Electrons I Consider a
Page 112 and 113: ' 112 axial diffusion through the d
Page 114 and 115: the tube walls occurs continuously
Page 116 and 117: E2R M ' $6"
Page 118 and 119: 1. 2. 3. 4. 5. 6. 7. 8. 9- 10. u. -
Page 120 and 121: 120 . Dlschorge zone Reactor zone 1
Page 122 and 123: 122 In radiation chemistry the cust
Page 124 and 125: 124 4. chemistry seem limited essen
Page 126 and 127: 126 Conversion of Mixtures into Mor
Page 128 and 129: Hydrazine Synthesis in A Silent dle
Page 130 and 131: {;I . - . .. . - .., . . .. _- .. .
Page 132 and 133: 1 \ \ \ , \ , \ \ Pmer hnrity K.W.
Page 134 and 135: . I operating fact that the sloGe i
Page 136 and 137: _- of ' . 8. - 7 6, Residence Time
Page 138 and 139: 135 Ionic Reactions in Corona Disch
Page 140 and 141: GAS OUT GAS IN i.ho QUADRUPOLE MASS
Page 142 and 143: - + ( ~ ~ + 0 H ) ~ O ~ ( H~o)~H+ +
Page 144 and 145: 144 i I , , , , . + 1- u 3c w Inu c
Page 146 and 147: 146 SYNTHESIS OF ORGANIC COIGhTDS B
Page 148 and 149: mi5 a- dz CI n I a I n +4 - 0 -I- k
Page 150 and 151: 0 z cu I I I
Page 154 and 155: 0 0 AI r 0 z a rc) I Z c. * I 0 z 0
Page 156 and 157: 156 The Dissociation of Metal Halid
Page 158 and 159: Table 2 Dissociation of NaCl in H2
Page 160 and 161: 160 Group I11 compounds. No in esti
Page 162 and 163: 162 EXPERIMENTAL WORK Apparatus. Th
Page 164 and 165: 164 apparatus for 10 min to remove
Page 166 and 167: 166 (a) Filament Emerging From Brok
Page 168 and 169: la lb H&i GASFLOW GROUND IC ‘-0 G
Page 170 and 171: 1 6 170 Fig. 5 Filaments Produced a
Page 172 and 173: 172 the formation of small particle
Page 174 and 175: Fig. 6 Longitudinal Cross Section o
Page 176 and 177: 4 176 Fig. 8 Boron-Coated Quartz Mo
Page 178 and 179: 5. F. Weintraub, Trans. Am. Electro
Page 180 and 181: 160 change in field through the cor
Page 182 and 183: Deposition Utilizing Altcrnating Cu
Page 184 and 185: 184 Bromine was a product when heli
Page 186 and 187: 125 I I The C'orol;:~. In tiic Iiig
Page 188 and 189: 188 obtained in the experiments pre
Page 190 and 191: 0 5 .d 3 v) * .d 3 0 u a 6 .d E *g
Page 192 and 193: 192 (a) 604x Fig. 7 Boron Deposit o
Page 194 and 195: N LI Y 0) ucd + 194 mol 0 rl 7 s I
Page 196 and 197: (-1) \'ariation of 1'l;iting Condit
Page 198 and 199: H2 --1 DE-OXO DRYING TOWER TAKE-UP
Page 200 and 201: .- c 0 c m A ' r n rn C .d 44 C 0 V
Page 202 and 203:
202 CONCLUSIONS Chemical reacticns
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and type of reaction products, (2)
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206 RESULTS AND DISCUSSION Prelimin
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chamber within the boundaries of th
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21 0 References 1. R. A. Mickelson,
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212 the principal axis 43 cm from t
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214 states of molecular oqgen are a
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. 216 the output coil further reduc
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- Tracer Fe59 Fe59 ' ~e75 se75 ,887
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220 THE EFFECT OF CORONA ON THE REA
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222 Figure 1.- Unit for studying ch
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224 Figure 3.- Siemen's type reacto
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J 4 226 ( 1 Table 1.- Factorial des
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228 W h 3 tn .r( w rn 5 w W > 3 U 9
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230 The decrease in equilibrium con
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232 9. Glockler, G., and S.C. Lind.
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234 The Plasma Induced Reaction of
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236 Results and Discussion When hyd
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238 The extensive literature of "ac
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( rot-1 -!y-roccrbon) 240 xprr2nc &
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242 result is well within the range
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244 RESULTS Figure 1 shows the resu
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20 15 IO 5 0 0 0 L 0 0 I 2 3 4 TIME
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d r- 0 r- ,-I d N 2 N 2 co Ln N 0 m
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250 TABLE 2. - Effect of adding wat
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252 One unusual finding of Epple an
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254 RADIOFREQUENCY ELECTRODELESS SY
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256 with a helium mass spectrometer
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Spectroscopy Run 70 Element Found C
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Acknowledgement 260 The authcrs are
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2152 TOLUENE ULTRAVIOLET EMISSION P
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254 A summary of the products forme
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1. 266 PARTIAL MASS SPECTRA OF mn B
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significant reaction int-ermedia te
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270 R .ACTION OF 'bI.4LEI.C J.NI?Y?
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~ tation 272 It is reasonable to ex
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274 The Polymerization of Benzene i
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276 Figure 1 czb Raoio Frequency Di
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h B C D 2-'? Figure 2. Infrared Spe
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280 Both ionic and free radical mec
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INTRODUCTION Chemistrv of Electrica
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254 removed from the glass surfaces
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t- z W 0 LL W 4 2 LL w 1.0 O.! 5 -
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'603 ~---~ _-_- T_--r.- Figure 5 10
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230 . . One of the unexpected resul
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i .; Chemical Engineering Aspects o
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ELECTRODE ARRANGEMENT PLRALLEL CO-A
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295 '' that they can be sustained a
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\ , , ~ ~~ - Consecutlve Reactlons
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05 1.0 15 5 Residence Time 7x10 hr.
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J I i' i P L iqud i Gas
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Acknowledgements . 303 The author i
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1 f / I 7 \ i/ '1:s The objectives
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i I. r >- .i between the electrodes
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\ / ’\ i Reactor I 300 The corona
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I 1 311 voltage divider giving an a
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31 4 ,Tet. - ~2H2 CK4 (or other hvd
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W v) a m 0 0 0 I e z v, a ? an a 0
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318 FIGURE 4 I
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0 0 0 0'0 \ D M . S ( C ) h l l l ;
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4 10 I,
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324 5 Toes u? linearallv with the K
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pl
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Under propran carried on at the.Res
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330 PPTRFKCCS 1. Leutner, 1'. l!. &
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INTRODUCI'ION 332 PRODUCl'ION OF BY
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335 I I I I I I I I 1 1 0.12 - - -
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3.0 2.5 2.0 H2'N2 15 3. - I .o Q5 '
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8 enthalpy dependence are not what
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340 . Gas flaws except for methane
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* L 1 1 1 1 I I 1 1 I I I U - 0.10
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344 Because of the use of diluent a
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about half the dlamcter of the jet
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348 and 1 atm, which were generated
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350 PLASMA COMFOSITION 1 Thermochem
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352 appeared in the literature. O'H
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354 flow rate insured good plasma s
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.. to an unmeasured small qusntity
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358 Ccxposition at the Assumed Free
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360 The phenomena ir. t:te pias::.&
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14. 15. Lc . 17. 18. 19 * 20. 21. 2
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THE CONVERSION OF i.iEEIHAiW IN AN
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_r 333 THERMAL CRACKING OF LOW-TEMP
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Distribution and yield rates of pro
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367 used as blnders, with different
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369 ' i 1. REFERENCES Berber, John
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I 7 /* i ,I { \ J 7 1/ r-' I Ia Jd
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I' p' / ! 2' 9' c u .r( Y a e, .r(
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FIGURE 375 I I I I I I I I I I I 0
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I , 1 1 I 4 9 I 1' i J 20 0 377 Lll
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Process Descrivtion 379 Figure 1 sh
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381 The bench and pilot plant opera
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383 ash content of the initial high
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385 Referencee 1. Bloomer, W. J., a
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I .- 4 -C .- .- J u 0 -- 0 N - In V
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. UI m rs m 389 . . . . t u 0 - r -
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9' -7 .I \ f- P , / ,/- 391 TABLE5
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THE HEAT OF REACTION?% HYDROGEN AND
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1 I i Design of a hydrogasification
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i Ij EPERENCES CITED 307 HJ7drOgen
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I i / - . 399 . . . I . 2’ 0 H fi
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I20 0 zo -0 SO 00 100 110 110 160 I
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3 1 403 In the Catalytic Degussa pr
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’f ’f \ ? i i k > / f j I 405 T
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I b 1 I Table 2.- Data from Tests w
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409 ECONOMIC EVALUATION The Bureau
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W 0
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Figure 3. Hydrogen cyanide reactor.
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C :G-l I I 00 1,100 1,200 TEMPERATU
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417 h6SSBAUER SPECTROSCOPY OF IRON
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I n \D r- m d c d rl rl n . aJ 2 C
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L. 421 minutes, yielding c 600,000
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I 1 1 \ ......... ...U ...... .."."
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; i 1 1 1 finely conminuted samples
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,' I t f I i I 1 $- i h 4 m 3 1 d =
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CONCLUSION 429 In sumnary, several
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-5) Sprenkel-Se@ E.L. and Hanna S.S
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1133 REACTIONS OF COAL AND RElATED
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435 interpretation of the data, Ar
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437 tube divided by a fritted Vycor
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439 Deuterium Oxide-Argon Discharge
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I2 c C 01 ? IO e 6 LL 0 z 13 0 0 hv
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443 A PPA RA TUS The corona reactor
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Product 445 TABLE 1 Product Dstribu
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I f I I " I I - 447 ~. Figure 3 Ana
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j , i 449 i 1' phenyl or benzyl sub
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Polymeric Products The material whi
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453
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1' b Scheme I fulvene 455 FIGURE 6
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- . .. . - . . . - 457 brown benzen
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459 14 G. J. Jam, J. Chem. Phys., 2
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461 fed into the vaporizer at a cer
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i 453 energy yield than for the oth
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Ldd ffl cc 3 .I+ X z \rl M O C - 0
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HYDROCARBONS AND CllRBON FROM A ROT
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J i I i I 469 The d-spacings ob ain
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Arc Enthalpy ,-) - 2500 Amps Field
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473 THE REARRANGEMENT OF METHANE AN
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4 i J 1 i 475 is due to C-H stretch
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1 I I / 10000 Y 1 - I before di sc
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L t 479
Page 485 and 486:
TA?.LE 1, - StratigraphiL po:itio;.
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1. 2. 3. 4. 5. TABLE 3. - Carbowl a
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i I I , r t \ .. 4 3 I I I I I I 1
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487 ELECTRICAL PROPERTIES OF IODINE
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489 on the ovcrall electrical prope
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3' I / 3 2 b V t 491 log p = log pJ
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i' I Y ' 493 .. 10E.G ~r,~-l {i;ig.
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d :- / I i' I 495 :"ne ~CIJ hznd A:
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497 a stable complex where conducti
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499 (it Lnk>;t,icC,i: ii., ani k:ta
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'/ 925°C. x lO"2 Sn.:>Lc SL>." "Io
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503
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505 up” / U d L .-
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507 c
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I' i i C .. . i? 2 s
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, 513 THE ELECTRON SPIN RESONANCE S
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I ./ i i L \ Y' J J / 51-5 TABLE I
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z I 51.7 radicals in coals and char
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J 519 i I \ d i L 300 400 500 600 7
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521 INFRARED SPECTRA OF OXYGEN-18 L
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523 AV, cm-1 Benzoic acid (monomer)
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Y
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The phenol chars also showed no shi
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529 Recovery of Nitrogen Bases with
Page 535 and 536:
I 1 I i i I The ionization constant
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1 i 533 1, I I The use of the param
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t '. I 1 3. \ 4. I 5. / i \ t J 1,
Page 541 and 542:
537 I Table 111 E Extraction of Pyr
Page 543 and 544:
.. 539 Table VI11 Pyridine Conceqtr
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limelight which was produced bG4kea
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I I 1 543 - , The phosphor ijas coa
Page 549 and 550:
\ 'i 2 w 8 ?N4"?? I? IC9 t-OO+r(N 0
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I i t \ I/' t I activated calcium o
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I 15. ',Jise, H. and Rosser, W. ,,A
Page 555 and 556:
B 549 15- '-Jise, H. and Rosser, W.
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I 0 I I I I 1 I I I I 0 R 2gDOc- 0
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1 2.2 2.0 0.8 0.6 0.4 553 0 2 4 . 6
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555 A RAPID, SIMBLE METhOD FOR THE
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557 and -k (%)= h (t-ts) AT f =R So
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559 thermocouple (x = 0; r = 0) may
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1 I A An ''P 'H I 'h I k ma "r Q R
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X 563 STANDARD CYLINDRICAL BRIQUETT
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