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ICHCA International <strong>Safe</strong>ty Panel Briefing Pamphlet No 30<br />
A2.2.13Maximum Degrees <strong>of</strong> Filling – Worked Example<br />
Paragraphs A2.2.3, A2.2.4 and A2.2.8 cover three situations for differing<br />
substances:<br />
maximum filling <strong>of</strong> lesser danger liquid substances loaded at ambient<br />
temperatures<br />
maximum filling <strong>of</strong> greater danger liquid substances or with a higher<br />
vapour pressure<br />
maximum filling <strong>of</strong> molten dangerous substances (carried above their<br />
melting point temperature)<br />
Example1: The substance ACRYLONITRILE, STABLIZED, Class 3,<br />
Subsidiary Hazard 6.1, Packing Group I, UN 1093 is to be<br />
shipped in tank containers. A shipper wishes to ship 22,500 kg.<br />
The largest suitable tank container available has a capacity <strong>of</strong><br />
26,000 litres. Can this consignment be accepted? The substance<br />
has a liquid density at the filling temperatures:<br />
<strong>of</strong> 0.812 at 15 º C (filling temperature); and<br />
<strong>of</strong> 0.772 at 50ºC (highest possible temperature).<br />
Step 1 Determine the volume represented by 22,500 kilos <strong>of</strong> the<br />
substance at the filling temperature:<br />
Cargo Net Mass<br />
Liquid Density<br />
22,500 kg<br />
0.812<br />
Page 50 ©ICHCA International Limited<br />
95<br />
1 + α(tr - tf)<br />
= Volume (litres)<br />
= 27,709 litres<br />
Conclusion: A 26,000 litre tank container is too small for the shipper’s<br />
preferred consignment. The shipper must be informed as to the<br />
maximum permitted quantity that can be loaded in this tank<br />
container.<br />
Step 2 From the Dangerous Goods List (column 14 – Portable tank<br />
provisions) UN 1093 this substance require TP2 and TP13<br />
provisions to be applied<br />
IMDG Code paragraph 4.2.5.3 indicates that TP13 requires self<br />
contained breathing apparatus shall be provides when this<br />
substance is transported (see Table A5.2), and TP2 directs th<br />
reader to 4.2.1.9.3 <strong>of</strong> the Code (see A2.2.4).<br />
Degree <strong>of</strong> filling =