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Magnetism 1

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( )<br />

0 so Z Z<br />

B µ<br />

H = H + H + J + S H L+ 2 S = J + S since J = L+ S<br />

→ the problem is that s mixes states with different .<br />

<br />

ml, ms<br />

<br />

l, s⋅ l = i l × s)<br />

, only the Z-components are conserved.<br />

[ ] (<br />

⇒ the spin-orbit interaction lifts the degeneracy between different levels with<br />

s and l (without a magnetic field), it leads to a different kind of splitting than the<br />

<br />

Zeeman-splitting → levels with the same j-value are degenerate for some<br />

s , l .<br />

E( J) −E( J − 1) λ<br />

= ( J( J + 1) ) −<br />

2<br />

= λ ⋅J<br />

L( L+ 1) − S( S+ 1) 1<br />

−<br />

2<br />

J −1 J − L L+ 1 − S S+<br />

1<br />

for same<br />

s , l , J = l±½<br />

( ) ( ( ) ( ) ( ) )<br />

- 10 -

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