1. Xtra Edge February 2012 - Career Point

1. Xtra Edge February 2012 - Career Point 1. Xtra Edge February 2012 - Career Point

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18. A light ring which can slip frictionlessly over wire is slipped over wire. When a tuning fork start resonating with wire, ring is found to be at rest at a distance 15 cm from one end. If velocity of wave in wire is 10 m/s, minimum frequency of tuning fork is- (A) 50 Hz (B) 60 Hz (C) 70 Hz (D) None of these 19. Now two light rings are slipped on wire which can move frictionlessly. When wire is plucked, the two rings are found to be at rest separated by 12 cm. Maximum wavelength of wave in wire is - (A) 4 cm (B) 8 cm (C) 12 cm (D) 24 cm This section contains 3 questions (Questions 20 to 22). Each question contains statements given in two columns which have to be matched. Statements (A, B, C, D) in Column I have to be matched with statements (P, Q, R, S) in Column II. The answers to these questions have to be appropriately bubbled as illustrated in the following example. If the correct matches are A-P, A-S, B-Q, B-R, C-P, C-Q and D-S, then the correctly bubbled 4 × 4 matrix should be as follows : P Q R S A P Q R S B P Q R S C P Q R S D P Q R S Mark your response in OMR sheet against the question number of that question in section-II. + 6 marks will be given for complete correct answer and No Negative marks for wrong answer. However, 1 mark will be given for a correctly marked answer in any row. 20. A small ring of mass m passes through a smooth wire bent in form of horizontal circle. The ring is connected to a spring whose other end is fixed at A on the wire as shown. The natural length of spring is mg R and spring constant is where m is mass of the R ring and R is also the radius of circle. Initially the ring is released from rest from position B and it moves towards C as in the figure. (N = Normal reaction between wire and ring, v = speed of ring) C wire A 60º Column-I Column-II (A) N = mg (P) at position B (B) N = zero (Q) at position C (C) N = 2 mg (R) some where between position B and position C (D) v = gR (S) never B 21. A body of mass ‘m’ is acted upon by net force F r . r and v be their initial position and velocity. All quantity are in S.I. unit . Then match the following. Column-I Column-II 2 (A) F = −4x î , r = 0 , (P) Motion : S.H.M. v = 2î, m = 2 (B) j ˆ F = ( 2 − 4y) , r = 0 (Q) Motion : Non-periodic v = 0 , m = 1 3 (C) F = − 2( x + x ) î , (R) Path : Straight line XtraEdge for IIT-JEE 62 FEBRUARY 2012 – 2 r = 10 î v = 0 , m = 1 (D) F = − 4( xî + yjˆ ) j (S) Time period : π ˆ r = 2 , v = 6î, m = 1 22. The cubical container filled with water is given acceleration → a = a0 î + a0 j ˆ + a0 k ˆ , then : (neglect the effect of gravity) E F C H D G B A z Column-I Column-II (A) Pressure at point A is (P) less than pressure at point G (B) Pressure at point D is (Q) less than pressure at point F (C) Pressure at point E is (R) Greater than pressure at point C (D) Pressure at point H is (S) Greater than pressure at point B CHEMISTRY Questions 1 to 9 are multiple choice questions. Each question has four choices (A), (B), (C) and (D), out of which ONLY ONE is correct. Mark your response in OMR sheet against the question number of that question. + 3 marks will be given for each correct answer and – 1 mark for each wrong answer. 1. Which of the substance has maximum number of hydrogen atoms per gm of the substance ? At. wts. : Cu – 63.5 ; S – 32 ; O –16 ; H –1 (A) CH4 (B) CuSO4 . 5H2O (C) H2O2 (D) H2O y x

2. In the reaction 3 Cu + 8 HNO3 → 3 Cu(NO3)2 + 2NO + 4 H2O what is the equivalent weight of HNO3? if molecular weight of HNO3 is M - M 3 (A) M (B) (C) M 3 4 4 (D) M 3 3. The order of magnitude of ionic radii of ions Na + , Mg 2+ , Al 3+ and Si 4+ is : (A) Na + > Si 4+ > Al 3+ > Mg 2+ (B) Mg 2+ > Na + > Al 3+ > Si 4+ (C) Na + > Mg 2+ > Al 3+ > Si 4+ (D) Si 4+ > Al 3+ > Mg 2+ > Na + 4. The correct order of tendency of polymerization is - (A) SiO4 4– < PO4 3– < SO4 2– < ClO4 – (B) PO4 3– < SiO4 4– < SO4 2– < ClO4 – (C) ClO4 – < SO4 2– < SiO4 4– < PO4 3– (D) SiO4 4– > PO4 3– > SO4 2– > ClO4 – 5. K P for the gaseous reaction – K C (a) 2 A + 3 B 2C (b) 2 A 4B (c) A + B + 2C 4D would be respectively - (A) (RT) –3 , (RT) 2 , (RT)º (B) (RT) –3 , (RT) –2 , (RT) –1 (C) (RT) –3 , (RT) 2 , (RT) (D) None of the above 6. No. of heteroatoms (other than C) present in the following heterocyclic compound is – O N–H O (A) 3 (B) 2 (C) 1 (D) 0 7. & are – (A) Tautomers (B) Functional (C) Position (D) All the above 8. Which does not exists in solid state - (A) LiHCO3 (B) CaCO3 (C) NaHCO3 (D) Na2CO3 9. Decomposition of H2O2 is retarded by - (A) Acetanilide (B) MnO 2 (C) Zinc (D) Finely divided metals This section contains 4 questions numbered 10 to 13, (Reason and Assertion type question). Each question contains Assertion (A) and Reason (R). Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. Mark your response in OMR sheet against the question number of that question. +3 marks will be given for each correct answer and – 1 mark for each wrong answer. The following questions given below consist of an "Assertion" (A) and "Reason" (R) Type questions. Use the following Key to choose the appropriate answer. (A) If both (A) and (R) are true, and (R) is the correct explanation of (A). (B) If both (A) and (R) are true but (R) is not the correct explanation of (A). (C) If (A) is true but (R) is false. (D) If (A) is false but (R) is true. 10. Assertion (A) : F atom has a less negative electron gain enthalpy than Cl atom. Reason (R) : Additional electron are repelled more effectively by 3p electron in Cl atom than by 2p electron in F atom. 11. Assertion (A) : When a non-volatile solute is added to water ice equilibrium, some ice melts. Reason (R) : Ice melts to dilute the solution in order to increase the vapour pressure in accordance to Le-Chatelier's principle. 12. Assertion (A) : cyclohexancarbonitrile. H CN is called Reason (R) : It is an aromatic compound. 13. Assertion (A) : The following compounds are optically inactive. CH3 H Cl H Cl CH3 CH3 H Cl CH2 H Cl XtraEdge for IIT-JEE 63 FEBRUARY 2012 CH3 H CH3 CH2 CH3 Cl CH2 H Cl CH3 H Cl CH2 CH2 CH2 H Cl CH3 Reason (R) : the meso compounds do not have any chiral C atom so have optical rotation is zero. This section contains 2 paragraphs; each has 3 multiple choice questions. (Questions 14 to 19) Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. Mark your response in OMR sheet against the question number of that question. +4 marks will be given for each correct answer and – 1 mark for each wrong answer.

18. A light ring which can slip frictionlessly over wire is<br />

slipped over wire. When a tuning fork start<br />

resonating with wire, ring is found to be at rest at a<br />

distance 15 cm from one end. If velocity of wave in<br />

wire is 10 m/s, minimum frequency of tuning fork is-<br />

(A) 50 Hz (B) 60 Hz<br />

(C) 70 Hz (D) None of these<br />

19. Now two light rings are slipped on wire which can<br />

move frictionlessly. When wire is plucked, the two<br />

rings are found to be at rest separated by 12 cm.<br />

Maximum wavelength of wave in wire is -<br />

(A) 4 cm (B) 8 cm<br />

(C) 12 cm (D) 24 cm<br />

This section contains 3 questions (Questions 20 to 22).<br />

Each question contains statements given in two columns<br />

which have to be matched. Statements (A, B, C, D) in<br />

Column I have to be matched with statements (P, Q, R, S)<br />

in Column II. The answers to these questions have to be<br />

appropriately bubbled as illustrated in the following<br />

example. If the correct matches are A-P, A-S, B-Q, B-R,<br />

C-P, C-Q and D-S, then the correctly bubbled 4 × 4<br />

matrix should be as follows :<br />

P Q R S<br />

A P Q R S<br />

B P Q R S<br />

C P Q R S<br />

D P Q R S<br />

Mark your response in OMR sheet against the question<br />

number of that question in section-II. + 6 marks will be<br />

given for complete correct answer and No Negative<br />

marks for wrong answer. However, 1 mark will be<br />

given for a correctly marked answer in any row.<br />

20. A small ring of mass m passes through a smooth wire<br />

bent in form of horizontal circle. The ring is<br />

connected to a spring whose other end is fixed at A<br />

on the wire as shown. The natural length of spring is<br />

mg<br />

R and spring constant is where m is mass of the<br />

R<br />

ring and R is also the radius of circle. Initially the<br />

ring is released from rest from position B and it<br />

moves towards C as in the figure. (N = Normal<br />

reaction between wire and ring, v = speed of ring)<br />

C<br />

wire<br />

A<br />

60º<br />

Column-I Column-II<br />

(A) N = mg (P) at position B<br />

(B) N = zero (Q) at position C<br />

(C) N = 2 mg (R) some where between<br />

position B and position C<br />

(D) v = gR (S) never<br />

B<br />

2<strong>1.</strong> A body of mass ‘m’ is acted upon by net force F r .<br />

r and v be their initial position and velocity. All<br />

quantity are in S.I. unit . Then match the following.<br />

Column-I Column-II<br />

2<br />

(A) F = −4x<br />

î , r = 0 , (P) Motion : S.H.M.<br />

v = 2î,<br />

m = 2<br />

(B) j ˆ<br />

F = ( 2 − 4y)<br />

, r = 0 (Q) Motion : Non-periodic<br />

v = 0 , m = 1<br />

3<br />

(C) F = − 2(<br />

x + x ) î , (R) Path : Straight line<br />

<strong>Xtra</strong><strong>Edge</strong> for IIT-JEE 62 FEBRUARY <strong>2012</strong><br />

– 2<br />

r = 10 î v = 0 , m = 1<br />

(D) F = − 4(<br />

xî<br />

+ yjˆ<br />

)<br />

j<br />

(S) Time period : π<br />

ˆ r = 2 , v = 6î,<br />

m = 1<br />

22. The cubical container filled with water is given<br />

acceleration →<br />

a = a0 î + a0 j ˆ + a0 k ˆ , then : (neglect<br />

the effect of gravity)<br />

E F<br />

C<br />

H<br />

D<br />

G<br />

B<br />

A z<br />

Column-I Column-II<br />

(A) Pressure at point A is (P) less than pressure<br />

at point G<br />

(B) Pressure at point D is (Q) less than pressure<br />

at point F<br />

(C) Pressure at point E is (R) Greater than<br />

pressure at point C<br />

(D) Pressure at point H is (S) Greater than pressure<br />

at point B<br />

CHEMISTRY<br />

Questions 1 to 9 are multiple choice questions. Each<br />

question has four choices (A), (B), (C) and (D), out of<br />

which ONLY ONE is correct. Mark your response in<br />

OMR sheet against the question number of that<br />

question. + 3 marks will be given for each correct<br />

answer and – 1 mark for each wrong answer.<br />

<strong>1.</strong> Which of the substance has maximum number of<br />

hydrogen atoms per gm of the substance ?<br />

At. wts. : Cu – 63.5 ; S – 32 ; O –16 ; H –1<br />

(A) CH4 (B) CuSO4 . 5H2O<br />

(C) H2O2 (D) H2O<br />

y<br />

x

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