1. Xtra Edge February 2012 - Career Point

1. Xtra Edge February 2012 - Career Point 1. Xtra Edge February 2012 - Career Point

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22. Match the column : Column-I (A) A photon stimulates the emission of another photon of (B) Photons of electromagnetic wave of different wavelengths may have (C) Two points on a wavefront must have (D) For constructive interference the waves must have Column-II (P) Same direction (Q) Same energy (R) Same phase (S) Same frequency CHEMISTRY Questions 1 to 9 are multiple choice questions. Each question has four choices (A), (B), (C) and (D), out of which ONLY ONE is correct. Mark your response in OMR sheet against the question number of that question. + 3 marks will be given for each correct answer and – 1 mark for each wrong answer. 1. The phenomenon of optical activity will be shown by - A A B B A (A) M B B A A (C) en M A en (B) (D) 2. Titration curve of Na2CO3 and HCl is as given below. The indicators In1 and In2 respectively, must be – pH 12 10 8 6 4 2 B B en M B M en 10 20 30 40 50 60 Volume of HCl (ml) B en In1 In2 (A) phenolphthalein and methyl orange (B) methyl orange and phenolphthalein (C) methyl orange and phenol red (D) phenolphthalein and phenol red. 3. Metallic sulphates can be obtained by reacting the metals (above hydrogen in ECS), or its oxide, hydroxide or carbonate with dil.H2SO4. Gp IA metals also form hydrogen sulphates which can be isolated in solid. In general metal sulphates are soluble in water and crystallizes with water of crystallization. Sulphate are thermally more stable than nitrates. Select the stable hydrogen sulphate which can be obtained in solid state - (A) KHSO4 (B) CaHSO4 (C) FeHSO4 (D) All of these 4. Which of the following represent glyptal - O O (A) ––O–CH2–CH2–O–C C––– 4 O O (B) ––NH–(CH2)6–NH–C––(CH2)4– C––– 4 O O (C) O O 4 XtraEdge for IIT-JEE 50 FEBRUARY 2012 (D) O N H 5. In the Cannizzaro's reaction given below : ⎯ – OH 2Ph – CHO ⎯→ ⎯ Ph–CH2OH + PhCOO –- the slowest step is - (A) the attack of OH – at the carbonyl group (B) the transfer of hydride to the carbonyl group (C) the abstraction of proton from the carboxylic acid (D) the deprotonation of Ph–CH2OH 6. The relative rates of solvolysis in 80% EtOH of the following bromides is in the order – Br Br I II III (A) I > II > III (B) III > II > I (C) II > III > I (D) II > I > III 4 Br

XtraEdge for IIT-JEE 51 FEBRUARY 2012

<strong>Xtra</strong><strong>Edge</strong> for IIT-JEE 51 FEBRUARY <strong>2012</strong>

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