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1. Xtra Edge February 2012 - Career Point

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Matter Waves :<br />

Planck's quantum theory : Wave-particle duality -<br />

Planck gave quantum theory while explaining the<br />

radiation spectrum of a black body. According to<br />

Planck's theory, energy is always exchanged in<br />

integral multiples of a quanta of light or photon.<br />

Each photon has an energy E that depends only<br />

on the frequency ν of electromagnetic radiation<br />

and is given by :<br />

E = hν .....(1)<br />

where h = 6.6 × 10 –34 joule-sec, is Planck's<br />

constant. In any interaction, the photon either<br />

gives up all of its energy or none of it.<br />

From Einstein's mass-energy equivalence<br />

principle, we have<br />

E = mc 2 .....(2)<br />

Using equations (1) and (2), we get ;<br />

mc 2 = hν or m =<br />

hν<br />

.....(3)<br />

2<br />

c<br />

where m represents the mass of a photon in<br />

motion. The velocity v of a photon is equal to<br />

that of light, i.e., v = c.<br />

According to theory of relativity, the rest mass m0<br />

of a photon is given by :<br />

m0 =<br />

m 1−<br />

v<br />

c<br />

2<br />

2<br />

Here,<br />

hν<br />

m = and v = c<br />

2<br />

c<br />

Hence, m0 = 0 ....(4)<br />

i.e., rest mass of photon is zero, i.e., energy of<br />

photon is totally kinetic.<br />

The momentum p of each photon is given by :<br />

p = mc =<br />

PHYSICS FUNDAMENTAL FOR IIT-JEE<br />

Matter Waves, Photo-electric Effect<br />

hν hν<br />

× c = =<br />

2<br />

c c<br />

KEY CONCEPTS & PROBLEM SOLVING STRATEGY<br />

h h<br />

= ......(5)<br />

c / ν λ<br />

The left hand side of the above equation involves<br />

the particle aspect of photons (momentum) while<br />

the right hand side involves the wave aspect<br />

(wavelength) and the Planck's constant is the<br />

bridge between the two sides. This shows that<br />

electromagnetic radiation exhibits a wave-<br />

particle duality. In certain circumstances, it<br />

behaves like a wave, while in other circumstances<br />

it behaves like a particle.<br />

The wave-particle is not the sole monopoly of<br />

e.m. waves. Even a material particle in motion<br />

according to de Broglie will have a wavelength.<br />

The de Broglie wavelength λ of the matter waves<br />

is also given by :<br />

h h h<br />

λ = = =<br />

mv p 2mK<br />

where K is the kinetic energy of the particle.<br />

If a particle of mass m kg and charge q coulomb<br />

is accelerated from rest through a potential<br />

difference of V volt. Then<br />

1 2<br />

mv = qV or mv = 2 mqV<br />

2<br />

h 12.<br />

34<br />

Hence, λ = = Å<br />

2mqV<br />

V<br />

Photoelectric effect :<br />

When light of suitable frequency (electromagnetic<br />

radiation) is allowed to fall on a metal surface,<br />

electrons are emitted from the surface. These<br />

electrons are known as photoelectrons and the effect<br />

is known as photoelectric effect. Photoelectric<br />

effect, light energy is converted into electrical<br />

energy.<br />

Laws of photolectric effect :<br />

The kinetic energy of the emitted electron is<br />

independent of intensity of incident radiation.<br />

But the photoelectric current increases with the<br />

increase of intensity of incident radiation.<br />

The kinetic energy of the emitted electron<br />

depends on the frequency of the incident<br />

radiation. It increases with the increase of<br />

frequency of incident radiation.<br />

If the frequency of the incident radiation is less<br />

than a certain value, then photoelectric emission<br />

is not possible. This frequency is known as<br />

threshold frequency. This threshold frequency<br />

varies from emitter to emitter, i.e., depends on<br />

the material.<br />

There is no time lag between the arrival of light<br />

and the emission of photoelectrons, i.e., it is an<br />

instantaneous phenomenon.<br />

<strong>Xtra</strong><strong>Edge</strong> for IIT-JEE 21 FEBRUARY <strong>2012</strong>

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