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Damage formation and annealing studies of low energy ion implants ...

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2.2.3 Energy transferred in elastic collis<strong>ion</strong>s<br />

The amount <strong>of</strong> <strong>energy</strong> that can be transferred in an elastic collis<strong>ion</strong> is dependent<br />

on the masses <strong>of</strong> the particles <strong>and</strong> the impact parameter. The maximum <strong>energy</strong> transfer<br />

results from a head on collis<strong>ion</strong> <strong>and</strong> is given by (14):<br />

T<br />

4M<br />

M<br />

E<br />

1 2<br />

= 2 0<br />

(2.11)<br />

( M1<br />

+ M 2 )<br />

The <strong>energy</strong> transferred will decrease with increasing impact parameter <strong>and</strong> the average<br />

<strong>energy</strong> transferred is half that <strong>of</strong> the maximum value. The path <strong>of</strong> each <strong>ion</strong> depends on<br />

the individual collis<strong>ion</strong>s that it encounters <strong>and</strong> hence the final depth <strong>of</strong> an implanted <strong>ion</strong><br />

will be subject to statistical variat<strong>ion</strong>s. The nuclear stopping power (dE/dx)n gives an<br />

average rate <strong>of</strong> <strong>energy</strong> loss <strong>of</strong> the <strong>ion</strong>s through elastic collis<strong>ion</strong>s. The nuclear stopping<br />

power can be related to the scattering cross sect<strong>ion</strong>. The rate <strong>of</strong> nuclear <strong>energy</strong> loss<br />

affects both the range <strong>of</strong> an implanted <strong>ion</strong>, discussed in sect<strong>ion</strong> 2.4, <strong>and</strong> the damage to<br />

the crystal, discussed in chapter 3.<br />

2.3 Inelastic <strong>energy</strong> loss / Electronic stopping<br />

The interact<strong>ion</strong> <strong>of</strong> an energetic <strong>ion</strong> with the electrons in the target results in<br />

inelastic <strong>energy</strong> loss <strong>of</strong> the <strong>ion</strong>. As the <strong>ion</strong> passes by, each atom will be individually<br />

perturbed, leading to electron excitat<strong>ion</strong> within each participating atom, in some cases<br />

<strong>ion</strong>isat<strong>ion</strong> will occur. Electron excitat<strong>ion</strong> <strong>and</strong> <strong>ion</strong>isat<strong>ion</strong> lead to internal <strong>energy</strong><br />

consumpt<strong>ion</strong> in the colliding atom system. The <strong>energy</strong> absorbed in the excitat<strong>ion</strong><br />

process will not generally be restored to the kinetic or potential <strong>energy</strong> <strong>of</strong> the system<br />

<strong>and</strong> this leads to inelastic <strong>energy</strong> loss. An average <strong>of</strong> the individual interact<strong>ion</strong>s gives<br />

the rate <strong>of</strong> inelastic <strong>energy</strong> loss, called the stopping power or the specific <strong>energy</strong> loss,<br />

termed (dE/dx)e, <strong>and</strong> in this thesis expressed in units <strong>of</strong> eV/Å.<br />

As an <strong>ion</strong> travels through a solid it would undergo many interact<strong>ion</strong>s <strong>and</strong> as such<br />

it is not possible to know the precise details <strong>of</strong> these interact<strong>ion</strong>s. Several models exist<br />

to describe the interact<strong>ion</strong>s <strong>and</strong> provide estimates for the stopping powers. Only a brief<br />

summary <strong>of</strong> important models is given here. Further explanat<strong>ion</strong> is beyond the scope <strong>of</strong><br />

this thesis. Further details are given in (5, 8, 17). Accurate values for the inelastic<br />

<strong>energy</strong> loss rates as a funct<strong>ion</strong> <strong>of</strong> <strong>energy</strong> are essential for the correct depth scale<br />

calibrat<strong>ion</strong> <strong>of</strong> the MEIS results. This is discussed further in sect<strong>ion</strong> 4.2.3.1.<br />

21

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