23.03.2013 Views

Damage formation and annealing studies of low energy ion implants ...

Damage formation and annealing studies of low energy ion implants ...

Damage formation and annealing studies of low energy ion implants ...

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

3.2.2.6 Other models 40<br />

3.2.3 Other implantat<strong>ion</strong> effects 41<br />

3.2.3.1 Sputtering 41<br />

3.2.3.2 Atomic mixing 41<br />

3.2.3.3 Range shortening 42<br />

3.3 Annealing 42<br />

3.3.1 Introduct<strong>ion</strong> 42<br />

3.3.2 Solid phase epitaxial regrowth (SPER) 43<br />

3.3.2.1 Intrinsic Si 43<br />

3.3.2.2 Dopant <strong>and</strong> other impurity Atoms 45<br />

3.3.2.3 Models for SPER 47<br />

3.3.3 R<strong>and</strong>om Nucleat<strong>ion</strong> <strong>and</strong> growth (RNG) 49<br />

3.3.4 Annealing ambient considerat<strong>ion</strong>s 49<br />

3.4 Defects after <strong>annealing</strong> <strong>and</strong> evolut<strong>ion</strong> during <strong>annealing</strong> 49<br />

3.4.1 Classificat<strong>ion</strong> <strong>of</strong> Defects 49<br />

3.4.2 End <strong>of</strong> Range defects <strong>and</strong> their evolut<strong>ion</strong> upon <strong>annealing</strong> 51<br />

3.4.3 Bubbles 54<br />

3.5 Dopant movement <strong>and</strong> Diffus<strong>ion</strong> 55<br />

3.5.1 Introduct<strong>ion</strong> 55<br />

3.5.2 Models <strong>of</strong> diffus<strong>ion</strong> 55<br />

3.5.2.1 St<strong>and</strong>ard Fickian diffus<strong>ion</strong> 57<br />

3.5.2.2 Transient enhanced diffus<strong>ion</strong> 58<br />

References 58<br />

Chapter 4 Experimental Techniques <strong>and</strong> sample preparat<strong>ion</strong> 63<br />

4.1 Introduct<strong>ion</strong> 63<br />

4.2 MEIS 64<br />

4.2.1 MEIS Introduct<strong>ion</strong> <strong>and</strong> basic principles 64<br />

4.2.1.1 Mass sensitivity – elastic collis<strong>ion</strong>s 65<br />

4.2.1.2 Depth sensitivity <strong>and</strong> inelastic <strong>energy</strong> loss 65<br />

4.2.1.3 Convers<strong>ion</strong> <strong>of</strong> <strong>energy</strong> scale to depth 67<br />

4.2.1.4 Surface Approximat<strong>ion</strong> method 68<br />

4.2.1.5 Dose <strong>and</strong> concentrat<strong>ion</strong> calculat<strong>ion</strong>s 70<br />

4.2.1.6 Crystallography – Channelling, shadowing, blocking<br />

<strong>and</strong> dechannelling 72<br />

4.2.1.7 Energy straggling <strong>and</strong> system resolut<strong>ion</strong>, resulting in a<br />

convolut<strong>ion</strong> <strong>of</strong> the peaks with Gaussian distribut<strong>ion</strong>s 75<br />

4.2.2 Experimental 78<br />

4.2.2.1 MEIS system 78<br />

4.2.2.2 Experimental Parameters 81<br />

4.2.2.3 Experimental output 85<br />

4.2.2.4 Interpretat<strong>ion</strong> <strong>of</strong> spectra 86<br />

4.2.3 Improvements to methodology 87<br />

4.2.3.1 Stopping powers 88<br />

4.2.3.2 Determinat<strong>ion</strong> <strong>of</strong> beam <strong>energy</strong> 90<br />

4.2.3.3 Numerical solut<strong>ion</strong> to depth scale 91<br />

4.2.3.4 Changes to the data acquisit<strong>ion</strong> 95<br />

4.3 SIMS introduct<strong>ion</strong> <strong>and</strong> basic principles 95<br />

4.4 Other analysis techniques used 98<br />

4.4.1 X-ray techniques 98<br />

4.4.2 TEM 98<br />

4.4.3 Electrical measurements 99<br />

iii

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!