Damage formation and annealing studies of low energy ion implants ...
Damage formation and annealing studies of low energy ion implants ... Damage formation and annealing studies of low energy ion implants ...
Concentration [at/cm 3 ] 10 22 10 21 10 20 10 19 a) b) PAI - 1 keV BF 2 as-implanted 600C 20m 1000C 5s 1025C 10s 1050C spike 30 Si 10 7 10 6 10 5 10 4 10 3 10 2 10 1 10 0 5 10 15 20 25 30 18 10 Depth [nm] 0 counts/s Concentration [at/cm 3 ] 10 0 5 10 15 20 25 30 18 10 Depth [nm] 0 Figure 7.6 shows combined depth profiles of Xe (from MEIS) and F (from SIMS), for as-implanted, 600 °C 20 min, 1000 °C 5 s and spike annealed at 1130 °C or 1050 °C sample, for both 3 keV and 1 keV BF2 implants. The figure illustrates the close link between the Xe and F. For some anneal conditions (e.g. 3keV BF2 + 1130 °C) the relative concentrations of Xe to F would appear to be ~ 1:1, but there are some minor deviations with different samples, notably the high temperature 1 keV samples. 10 22 10 21 10 20 10 19 181 No PAI - 1 keV BF 2 as-implanted 600C 20m 1000C 5s 1025C 10s 1050C spike Figure 7.5 1 keV SIMS profiles for a) PAI samples and b) non-PAI samples. 30 Si 10 7 10 6 10 5 10 4 10 3 10 2 10 1 counts/s
Yield (counts per 5 µC) 20 15 10 5 0 20 15 10 5 0 20 15 10 5 0 20 15 10 5 20 keV Xe, 3keV BF 2 F - as-implanted Xe - as-implanted F - 600C 20m Xe - 600C 20m F - 1000C 5s Xe - 1000C 5s F - 1130C spike Xe - 1130C spike 20 keV Xe, 1 keV BF 2 Figure 7.7a) shows SIMS B depth profiles for the 3 keV BF2 implants into crystalline and pre-amorphised Si, as-implanted, after 600 °C 20m, 1000 °C 5s RTA, and 1130 °C spike annealing. For the as-implanted sample the effect of channelling is visible at depths greater than 10 nm. Annealing causes several effects. Segregation of B to the surface occurs in all samples. Diffusion deeper into the bulk occurs for the 1000 °C and 1130 °C samples, the higher temperature causing a greater amount of diffusion. Using 1E18cm -3 as a reference concentration for the junction depth gives a junction at 43 nm and around 60 nm for the 1000 °C and 1130 °C samples respectively. 182 F - as-implanted Xe - as-implanted F - 600C 20m Xe - 600C 20m F - 1000C 5s Xe - 1000C 5s F - 1050C spike Xe - 1050C spike 2.0x10 20 1.5x10 20 1.0x10 20 5.0x10 19 0.0 2.0x10 20 1.5x10 20 1.0x10 20 5.0x10 19 0.0 2.0x10 20 1.5x10 20 1.0x10 20 5.0x10 19 0.0 0 0.0 0 2 4 6 8 101214160246810 12 14 16 Depth (nm) 2.0x10 20 1.5x10 20 1.0x10 20 5.0x10 19 Figure 7.6 Combined MEIS Xe depth profiles and SIMS F depth profiles for Xe preamorphised samples implanted with 3 keV BF2 + (left) and 1 keV BF2 (right), as-implanted and after various anneals. Concentration (atoms cm -3 )
- Page 149 and 150: attributed to the interference betw
- Page 151 and 152: The as-implanted sample, with a bro
- Page 153 and 154: a) b) Yield (counts per 5 µC) Yiel
- Page 155 and 156: interface, as evidenced by the high
- Page 157 and 158: duration, is observed. MEIS results
- Page 159 and 160: Yield (counts per 5µC) 500 400 300
- Page 161 and 162: ack edges of the Si peaks are very
- Page 163 and 164: underneath the SiO2 layer, iii) it
- Page 165 and 166: R s (Ω/sq) 950 900 850 800 750 60
- Page 167 and 168: As concentration (at/cm 3 ) 1E22 1E
- Page 169 and 170: R s (Ω/sq) 950 900 850 800 750 70
- Page 171 and 172: Following annealing it was observed
- Page 173 and 174: ∆a/a (x 10 -3 ) 4,0 epi550 3,5 3,
- Page 175 and 176: Yield (counts per 5 uC) 350 300 250
- Page 177 and 178: (FWHM). Concomitantly, As in the re
- Page 179 and 180: Yield (counts per 5 µC) 450 400 35
- Page 181 and 182: The higher temperature anneals carr
- Page 183 and 184: ecomes steeper for the sample annea
- Page 185 and 186: Figure 6.28 Schematic illustrations
- Page 187 and 188: and the 2D picture in Figure 6.31b)
- Page 189 and 190: 6.5 Conclusion In summary, in this
- Page 191 and 192: 20 L. Capello, T. H. Metzger, M. We
- Page 193 and 194: egarding B profiles relevant to the
- Page 195 and 196: Yield (counts per 5 µC) 400 300 20
- Page 197 and 198: TRIM AU 0.04 0.03 0.02 0.01 TRIM si
- Page 199: a) F profile PAI 3 keV BF2 b) F pro
- Page 203 and 204: the corresponding PAI sample, yield
- Page 205 and 206: amorphous matrix, (16) i.e. local c
- Page 207 and 208: 21 M. Anderle, M. Bersani, D. Giube
- Page 209 and 210: stopped at depths beyond the observ
- Page 211: the role of each individual element
Concentrat<strong>ion</strong> [at/cm 3 ]<br />
10 22<br />
10 21<br />
10 20<br />
10 19<br />
a) b)<br />
PAI - 1 keV BF 2<br />
as-implanted<br />
600C 20m<br />
1000C 5s<br />
1025C 10s<br />
1050C spike<br />
30 Si<br />
10 7<br />
10 6<br />
10 5<br />
10 4<br />
10 3<br />
10 2<br />
10 1<br />
10<br />
0 5 10 15 20 25 30<br />
18<br />
10<br />
Depth [nm]<br />
0<br />
counts/s<br />
Concentrat<strong>ion</strong> [at/cm 3 ]<br />
10<br />
0 5 10 15 20 25 30<br />
18<br />
10<br />
Depth [nm]<br />
0<br />
Figure 7.6 shows combined depth pr<strong>of</strong>iles <strong>of</strong> Xe (from MEIS) <strong>and</strong> F (from<br />
SIMS), for as-implanted, 600 °C 20 min, 1000 °C 5 s <strong>and</strong> spike annealed at 1130 °C or<br />
1050 °C sample, for both 3 keV <strong>and</strong> 1 keV BF2 <strong>implants</strong>. The figure illustrates the close<br />
link between the Xe <strong>and</strong> F. For some anneal condit<strong>ion</strong>s (e.g. 3keV BF2 + 1130 °C) the<br />
relative concentrat<strong>ion</strong>s <strong>of</strong> Xe to F would appear to be ~ 1:1, but there are some minor<br />
deviat<strong>ion</strong>s with different samples, notably the high temperature 1 keV samples.<br />
10 22<br />
10 21<br />
10 20<br />
10 19<br />
181<br />
No PAI - 1 keV BF 2<br />
as-implanted<br />
600C 20m<br />
1000C 5s<br />
1025C 10s<br />
1050C spike<br />
Figure 7.5 1 keV SIMS pr<strong>of</strong>iles for a) PAI samples <strong>and</strong> b) non-PAI samples.<br />
30 Si<br />
10 7<br />
10 6<br />
10 5<br />
10 4<br />
10 3<br />
10 2<br />
10 1<br />
counts/s