Damage formation and annealing studies of low energy ion implants ...
Damage formation and annealing studies of low energy ion implants ... Damage formation and annealing studies of low energy ion implants ...
Taking data creates a data tile, i.e. a 2D plot of the yield at each point on the analyser. By stepping the pass energy down, and joining together the individual tiles, a continuous energy spectrum can be produced. Further data processing information is given in section 4.2.2.3. 4.2.2.2 Experimental Parameters Before explaining the MEIS output data, the choice of experimental parameters needs to be discussed. The main experimental parameters to consider are the scattering angle, which is determined by the crystallographic directions in and out, the beam energy and the choice of projectile mass. Changes to these parameters produce a variety of effects and often a compromise is needed to find the best overall conditions. It is useful to avoid overlap of peaks from different elements (masses) to make analysing the data more straightforward and to avoid ambiguity of the results. This may be achieved by choosing conditions with a sufficiently large variation in the kinematic factors (equation 2.10) for all the different elements present in a sample. The kinematic factor varies with scattering angle and with mass ratio of the atom and incident ion. Plots of the kinematic factor for various atom / ion combinations are shown in Figure 4.13, for He ions on the left and H ions on the right. There are several important observations. As the scattering angle is increased, there is an increased variation in K between the different masses hence there is less likelihood of peak overlap at larger scattering angles. There is less variation for high masses than light elements. Comparison between He and H shows a much larger spread of K values achieved with He. 81
Kinematic factor (K) 1.0 0.8 0.6 0.4 B/He O/He Si/He As/He Sb/He 0.2 Au/He 0 20 40 60 80 100 120 140 160 B/H O/H Si/H As/H Sb/H 0.4 Au/H 0.2 0 20 40 60 80 100 120 140 160 180 Scattering angle (deg) Figure 4.13 Variation in the kinematic factor K with scattering angle, for different atom / He or H combinations. The depth resolution can be varied with scattering angle. Increasing the path lengths of an ion in a sample produces an improvement in depth resolution; therefore using small scattering angles produces an enhancement of the depth resolution. This is evident in Table 4.1, shown later, where the depth resolutions obtained for different scattering angles is given. Once an appropriate scattering angle is chosen, to satisfy the requirements of peak overlap and depth resolution, the specific crystallographic directions need to be chosen for the channelling and blocking. More open channels produce better blocking dips which makes the set up of the double alignment up more sensitive to the surface and also makes sample alignment easier. He ions have a wider shadow cone compared to H and this means the shadowing and blocking will be more effective and hence He should give deeper channels. The choice of ion has an effect on the depth resolution, He with its higher stopping power produces better depth resolution than H + . A high scattering yield is advantageous to improve the sensitivity for detecting particles. As given in equations 4.5 and 4.6 the Z1 2 dependence of the scattering cross section shows that the scattering yield would be four times higher for He + ions than for H + ions. Likewise the Z2 2 dependence shows there is a much higher scattering yield for scattering off heavy elements such as As than light ones such as B. Since the scattering 82 1.0 0.8 0.6
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Kinematic factor (K)<br />
1.0<br />
0.8<br />
0.6<br />
0.4<br />
B/He<br />
O/He<br />
Si/He<br />
As/He<br />
Sb/He<br />
0.2<br />
Au/He<br />
0 20 40 60 80 100 120 140 160<br />
B/H<br />
O/H<br />
Si/H<br />
As/H<br />
Sb/H<br />
0.4<br />
Au/H<br />
0.2<br />
0 20 40 60 80 100 120 140 160 180<br />
Scattering angle (deg)<br />
Figure 4.13 Variat<strong>ion</strong> in the kinematic factor K with scattering angle, for different atom /<br />
He or H combinat<strong>ion</strong>s.<br />
The depth resolut<strong>ion</strong> can be varied with scattering angle. Increasing the path<br />
lengths <strong>of</strong> an <strong>ion</strong> in a sample produces an improvement in depth resolut<strong>ion</strong>; therefore<br />
using small scattering angles produces an enhancement <strong>of</strong> the depth resolut<strong>ion</strong>. This is<br />
evident in Table 4.1, shown later, where the depth resolut<strong>ion</strong>s obtained for different<br />
scattering angles is given. Once an appropriate scattering angle is chosen, to satisfy the<br />
requirements <strong>of</strong> peak overlap <strong>and</strong> depth resolut<strong>ion</strong>, the specific crystallographic<br />
direct<strong>ion</strong>s need to be chosen for the channelling <strong>and</strong> blocking. More open channels<br />
produce better blocking dips which makes the set up <strong>of</strong> the double alignment up more<br />
sensitive to the surface <strong>and</strong> also makes sample alignment easier. He <strong>ion</strong>s have a wider<br />
shadow cone compared to H <strong>and</strong> this means the shadowing <strong>and</strong> blocking will be more<br />
effective <strong>and</strong> hence He should give deeper channels. The choice <strong>of</strong> <strong>ion</strong> has an effect on<br />
the depth resolut<strong>ion</strong>, He with its higher stopping power produces better depth resolut<strong>ion</strong><br />
than H + .<br />
A high scattering yield is advantageous to improve the sensitivity for detecting<br />
particles. As given in equat<strong>ion</strong>s 4.5 <strong>and</strong> 4.6 the Z1 2 dependence <strong>of</strong> the scattering cross<br />
sect<strong>ion</strong> shows that the scattering yield would be four times higher for He + <strong>ion</strong>s than for<br />
H + <strong>ion</strong>s. Likewise the Z2 2 dependence shows there is a much higher scattering yield for<br />
scattering <strong>of</strong>f heavy elements such as As than light ones such as B. Since the scattering<br />
82<br />
1.0<br />
0.8<br />
0.6