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Non-dispersive wave packets in periodically driven quantum systems

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466 A. Buchleitner et al. / Physics Reports 368 (2002) 409–547<br />

Energy (10 -3 a.u.)<br />

-1.120<br />

-1.125<br />

-1.130<br />

-1.135<br />

-1.115<br />

-1.125<br />

-1.135<br />

-1.105<br />

-1.115<br />

-1.125<br />

(a)<br />

(b)<br />

(c)<br />

-1.135<br />

0 5 10<br />

p<br />

15 20<br />

Fig. 21. Comparison of the semiclassical quasienergies (circles; with N = 0, see Eq. (78)), orig<strong>in</strong>at<strong>in</strong>g from the unperturbed<br />

n0 = 21 manifold, to the exact <strong>quantum</strong> result (crosses), at di erent values of the (scaled) driv<strong>in</strong>g eld amplitude<br />

F0 = Fn 4 0 =0:02 (a), 0:03 (b), 0:04 (c). The agreement is excellent. The <strong>quantum</strong> number p =0:::20 labels the quantized<br />

classical trajectories plotted <strong>in</strong> Fig. 19, start<strong>in</strong>g from the librational state |p =0〉 at lowest energy, ris<strong>in</strong>g through the<br />

separatrix states |p=10〉 and |p=11〉, up to the rotational state |p=20〉. The dashed l<strong>in</strong>e <strong>in</strong>dicates the exact quasi-energy<br />

of the correspond<strong>in</strong>g <strong>wave</strong> packet eigenstate of the 1D model discussed <strong>in</strong> Section 3.3.1. The 1D dynamics is neatly<br />

embedded <strong>in</strong> the spectrum of the real, <strong>driven</strong> 3D atom.<br />

coupl<strong>in</strong>g vanishes identically ( 1 = 0), which shows that the semiclassical results obta<strong>in</strong>ed from our<br />

rst-order approximation (<strong>in</strong> F) for the Hamiltonian may be quite <strong>in</strong>accurate <strong>in</strong> the vic<strong>in</strong>ity of this<br />

orbit. Higher-order corrections may become important.<br />

As discussed above, the classical motion <strong>in</strong> the (L; ) plane is slower than <strong>in</strong> the (Î; ˆ ) plane. In<br />

the semiclassical approximation, the spac<strong>in</strong>g between consecutive states corresponds to the frequency<br />

of the classical motion (see also Eq. (40)). Hence, it is to be expected that states with the same<br />

<strong>quantum</strong> number N , but with successive <strong>quantum</strong> numbers p, will lie at neighbor<strong>in</strong>g energies,<br />

build<strong>in</strong>g well-separated manifolds associated with a s<strong>in</strong>gle value of N . The energy spac<strong>in</strong>g between<br />

states <strong>in</strong> the same manifold should scale as F0, while the spac<strong>in</strong>g between manifolds should scale<br />

as √ F0 (remember that F01 <strong>in</strong> the case considered here). Accurate <strong>quantum</strong> calculations fully<br />

con rm this prediction, with manifolds orig<strong>in</strong>at<strong>in</strong>g from the degenerate hydrogenic energy levels at<br />

F0 = 0, as we shall demonstrate now. We rst concentrate on the N = 0 manifold, orig<strong>in</strong>at<strong>in</strong>g from<br />

n0 = 21. Fig. 21 shows the comparison between the semiclassical and the <strong>quantum</strong> energies, for<br />

di erent values of the scaled driv<strong>in</strong>g eld amplitude F0 = Fn 4 0<br />

. The agreement is excellent, except<br />

for the lowest ly<strong>in</strong>g states <strong>in</strong> the manifold for F0 =0:02. The lowest energy level (p=0) corresponds<br />

to motion close to the stable xed po<strong>in</strong>t L =0, = =2 <strong>in</strong> Fig. 19; the highest energy level (p = 20)<br />

corresponds to rotational motion L=n0 1. The levels with the smallest energy di erence (p=10; 11)<br />

correspond to the librational and the rotational trajectories closest to the separatrix, respectively. The<br />

narrow<strong>in</strong>g of the level spac<strong>in</strong>g <strong>in</strong> their vic<strong>in</strong>ity is just a consequence of the slow<strong>in</strong>g down of the<br />

classical motion [60]. In the same gure, we also plot (as a dashed l<strong>in</strong>e) the correspond<strong>in</strong>g exact<br />

quasienergy level for the 1D model of the atom (see Section 3.3.1). As expected, it closely follows

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