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HANSER Hanser Publishers, Munich • Hanser Gardner Publications ...

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The power law exponent is obtained from Equation 1.37<br />

Using the values for A0, A v and so on<br />

n = 3.196<br />

1.3.7.4 Carreau's Viscosity Equation [11]<br />

As shown in Figure 1.14 [12], the Carreau equation provides the best fit for the viscosity<br />

function, reproducing the asymptotic form of the plot at high and low shear rates correctly.<br />

The equation is expressed as<br />

(1.38)<br />

where A, B, C are resin-dependent constants. By introducing the shift factor aT into<br />

Equation 1.38, the temperature-invariant form of the Carreau equation can be given as<br />

(1.39)<br />

For a number of resins the shift factor can be calculated as a function of temperature<br />

from the following equation with good approximation [9,10]<br />

(1.40)<br />

where T1 ( 0 C) is the temperature at which the viscosity is given and T2 ( 0 C) the temperature<br />

at which the viscosity is calculated.<br />

The standard temperature TST is given by [9]<br />

TST=Tg +50 0 C (1.41)<br />

Viscosity 7?<br />

Vo=*<br />

Shear rate f<br />

/=1/B<br />

Slope: -C<br />

Figure 1.14 Determination of Carreau-parameters from a viscosity function [12]

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