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synlett 17/2009 - Thieme Chemistry

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Letters<br />

VIII Table of Contents<br />

2795 C. Praveen<br />

S. Jegatheesan<br />

P. T. Perumal*<br />

2801 M. G. Gonçalves-Martin<br />

A. Saxer<br />

P. Renaud*<br />

2803 S. Hanessian*<br />

X. Wang<br />

2809 H.-G. Lee<br />

M.-J. Kim<br />

S.-E. Park<br />

J.-J. Kim<br />

B. R. Kim<br />

S.-G. Lee<br />

Y.-J. Yoon*<br />

Gold(III) Chloride Catalyzed Intermolecular Dimerization of<br />

2-Ethynylanilines: Synthesis of Substituted Quinolines<br />

R<br />

NH2<br />

+<br />

R<br />

NH2<br />

5 mol% AuCl3, 10 mol% AgOTf<br />

MeCN, N 2, reflux<br />

A Practical Synthesis of (S)-Cyclopent-2-enol<br />

OH<br />

S<br />

O<br />

SiMe 3<br />

Applications of the N-tert-Butylsulfonyl (Bus) Protecting Group in Amino<br />

Acid and Peptide <strong>Chemistry</strong><br />

R<br />

H2N CO2Me<br />

R<br />

BusHN CO 2Me<br />

R = Me, i-Pr, CH 2CO 2Me, Bn, i-Bu, etc.<br />

R<br />

R<br />

H 2N CO 2Me<br />

Phenyl 4,5-Dichloro-6-Oxopyridazine-1(6H)-Carboxylate as Carbonyl<br />

Source: Facile and Selective Synthesis of Carbamates and Ureas under Mild<br />

Conditions<br />

R 1 R 2 NH<br />

alkyl or aryl<br />

amines<br />

Cl<br />

Cl<br />

N N<br />

O<br />

C<br />

O O<br />

THF<br />

– 4,5-dichloropyridazin-3(2H)-one<br />

O<br />

2 R 1 RN O<br />

R<br />

N<br />

1<br />

O<br />

R2 N<br />

O<br />

Me<br />

N<br />

2 R 1 RN NR 3 R 4<br />

carbamates unsymmetric ureas<br />

R 1<br />

R 2<br />

symmetric ureas<br />

NH2<br />

R

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