Annotated list of references on Iceland spar and polarized light

Annotated list of references on Iceland spar and polarized light Annotated list of references on Iceland spar and polarized light

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-1936 Pollard, ?U.K. Usually, Nicol´s prisms are much smaller than this [i.e. 4” aperture] and even moderately sized optically perfect crystals ong>ofong> the spar have already become scarce. -1936, South African Geological Survey: Iceland spar has, in the past, been obtained almost exclusively from Iceland but owing to the falling ong>ofong>f ong>ofong> the production ong>ofong> good optical grade material from that country and the increasing demand for the mineral, attention has been directed to other possible sources ong>ofong> supply. -1938 Griggs, U.S. … Iceland spar… difficult to obtain… -1940 Kremers, U.S. Natural calcite ong>ofong> optical quality is scarce…..The acute shortage ong>ofong> calcite in the larger sizes has for several years stimulated the search for a proper substitute [he mentions sodium nitrate specifically]. -1948 Archard and Taylor, U.S. … more recently [i.e. after 1936], owing to the shortage ong>ofong> calcite,… - 1949 Evans, U.S. …Unfortunately calcite is so difficult to obtain [in large sizes] that its general use in birefringent filters is probably impossible. -1950 Schumann and Piller, D… Das Versiegen der natürlichen Vorkommen von optischem Kalkspat bildet seit langem eine beständige Sorge aller beteiligten Fachkreise…., [and] ...Kalkspatpolarisatoren, deren Beschaffung ständig schwieriger wird… - 1950 Hartshorne and Stuart, U.K. ... because large pieces ong>ofong> optical calcite are practically unobtainable nowadays, and... -1953 Rinne-Berek, 12 th ed. D… Da für optische Zwecke verwendbarer Kalkspat in den letzten Jahren immer seltener geworden ist… -1961 Zirkl, A … (summary ong>ofong> 1959 lecture) Hinzu kommt, dass die Beschaffung von Kalkspat immer schwieriger und kostspieliger wird, weil die Vorkommen in Island praktisch erschöpft sind. -1967 Nester and Schroeder, U.S. Naturally occurring calcite ong>ofong> great purity has gradually become more difficult to obtain as great use has been made ong>ofong> this material in relatively recent years. -1968 Ammann and Massey, U.S.…large natural [calcite] crystals ong>ofong> good optical quality are becoming increasingly scarce. Lensfield Cottage, Cambridge, 6 July, 1886. To his Excellency, the Minister for Iceland, Copenhagen. Sir, As I hold the ong>ofong>fice ong>ofong> president ong>ofong> the Royal Society ong>ofong> London, the oldest scientific society in this Kingdom, I hope your Excellency will excuse me for troubling you on a matter ong>ofong> scientific importance, possibly also ong>ofong> some slight commercial interest to your country. This mineral known as calcite is much used by scientific men for instruments employed in investigations and lectures relating to polarised light. This mineral is common enough: but it has nowhere, to my knowledge, been found in large, clear, 116

egularly crystallized masses except in Iceland, from which circumstance it is otherwise called Iceland spar. It is from Iceland that the supply ong>ofong> this material used by opticians has been exclusively derived. Some years ago large blocks ong>ofong> this material used to be imported into this country from Iceland, and were freely purchased, and used by opticians. But for some time the supply has altogether ceased: the stock in hand has been used up, and opticians try in vain to get more. I feared that the mines were exhausted, but I am informed that the cause ong>ofong> the cessation ong>ofong> the supply is that the mines were purchased by Government and have not since been worked. I imagine that they have been worked in a rather wasteful way, for the sake ong>ofong> quick returns, and probably at the time ong>ofong> the purchase there was a glut in the market: for though there is a steady demand for the material it is not used in large quantities, and the consumption is slow. But I hear on all sides from opticians and scientific men ong>ofong> the impossibility ong>ofong> procuring the material now, so there can be no doubt that there would be a demand for it if it could be supplied. The magnificence ong>ofong> the blocks I used to see some years ago leads me to suspect that among the heaps ong>ofong> rubbish about the mine there may be many small pieces which were not thought worth collecting, nor were they perhaps when the market was glutted. But when I mention that a piece an inch or an inch and a half long and say three eighths ong>ofong> an inch in diameter would suffice to make a prism which when made could be sold for perhaps 8 shillings, even when there was still spar to be had in the market, it will be seen that even small pieces, comparatively speaking, have their value: and the collection ong>ofong> these, if such there be lying about, might help to defray the cost ong>ofong> re-opening the mine. I enclose a translation ong>ofong> this letter into Icelandic, which my friend Mr. Magnússon has kindly undertaken to make. I have the honour ong>ofong> being your Excellency´s obedient servant G.G. Stokes (sign.) Connections between Iceland spar and Nobel prizes 1901-30 may be divided into four categories: 1. Discoveries dependent on Nicol prisms (made from Iceland spar) to a large extent: Emil Fischer, Chem. 1902 (synthesis ong>ofong> sugars and other molecules) Alfred Werner, Chem. 1913 (coordination compounds; see Kauffman 1968) 2. Discoveries where polarization played a considerable part: H.A. Lorentz and P. Zeeman, Phys. 1902 (Zeeman magneto-optic effect) J. Stark, Phys. 1919 (Stark electro-optic effect on spectra) C.V. Raman, Phys. 1930 (scattering ong>ofong> light, with change ong>ofong> wavelength). 3. Discoveries where Nicol prisms or calcite crystals played some part: The X-ray diffraction studies ong>ofong> the Braggs, Phys. 1915, M. Siegbahn, Phys. 1924, and A.H. Compton, Phys. 1927 employed calcite for accurate wavelength measurements. S. Arrhenius, Chem. 1903 and W. Ostwald, Chem. 1909, used polarimeters in some ong>ofong> their 117

egularly crystallized masses except in <strong>Icel<strong>and</strong></strong>, from which circumstance it is otherwise<br />

called <strong>Icel<strong>and</strong></strong> <strong>spar</strong>. It is from <strong>Icel<strong>and</strong></strong> that the supply <str<strong>on</strong>g>of</str<strong>on</strong>g> this material used by opticians<br />

has been exclusively derived.<br />

Some years ago large blocks <str<strong>on</strong>g>of</str<strong>on</strong>g> this material used to be imported into this country<br />

from <strong>Icel<strong>and</strong></strong>, <strong>and</strong> were freely purchased, <strong>and</strong> used by opticians. But for some time the<br />

supply has altogether ceased: the stock in h<strong>and</strong> has been used up, <strong>and</strong> opticians try in<br />

vain to get more. I feared that the mines were exhausted, but I am informed that the<br />

cause <str<strong>on</strong>g>of</str<strong>on</strong>g> the cessati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> the supply is that the mines were purchased by Government <strong>and</strong><br />

have not since been worked.<br />

I imagine that they have been worked in a rather wasteful way, for the sake <str<strong>on</strong>g>of</str<strong>on</strong>g><br />

quick returns, <strong>and</strong> probably at the time <str<strong>on</strong>g>of</str<strong>on</strong>g> the purchase there was a glut in the market:<br />

for though there is a steady dem<strong>and</strong> for the material it is not used in large quantities, <strong>and</strong><br />

the c<strong>on</strong>sumpti<strong>on</strong> is slow. But I hear <strong>on</strong> all sides from opticians <strong>and</strong> scientific men <str<strong>on</strong>g>of</str<strong>on</strong>g> the<br />

impossibility <str<strong>on</strong>g>of</str<strong>on</strong>g> procuring the material now, so there can be no doubt that there would be<br />

a dem<strong>and</strong> for it if it could be supplied.<br />

The magnificence <str<strong>on</strong>g>of</str<strong>on</strong>g> the blocks I used to see some years ago leads me to suspect<br />

that am<strong>on</strong>g the heaps <str<strong>on</strong>g>of</str<strong>on</strong>g> rubbish about the mine there may be many small pieces which<br />

were not thought worth collecting, nor were they perhaps when the market was glutted.<br />

But when I menti<strong>on</strong> that a piece an inch or an inch <strong>and</strong> a half l<strong>on</strong>g <strong>and</strong> say three eighths<br />

<str<strong>on</strong>g>of</str<strong>on</strong>g> an inch in diameter would suffice to make a prism which when made could be sold for<br />

perhaps 8 shillings, even when there was still <strong>spar</strong> to be had in the market, it will be seen<br />

that even small pieces, comparatively speaking, have their value: <strong>and</strong> the collecti<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g><br />

these, if such there be lying about, might help to defray the cost <str<strong>on</strong>g>of</str<strong>on</strong>g> re-opening the mine.<br />

I enclose a translati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> this letter into <strong>Icel<strong>and</strong></strong>ic, which my friend Mr.<br />

Magnúss<strong>on</strong> has kindly undertaken to make.<br />

I have the h<strong>on</strong>our <str<strong>on</strong>g>of</str<strong>on</strong>g> being your Excellency´s obedient servant<br />

G.G. Stokes (sign.)<br />

C<strong>on</strong>necti<strong>on</strong>s between <strong>Icel<strong>and</strong></strong> <strong>spar</strong> <strong>and</strong> Nobel prizes 1901-30 may be divided into four<br />

categories:<br />

1. Discoveries dependent <strong>on</strong> Nicol prisms (made from <strong>Icel<strong>and</strong></strong> <strong>spar</strong>) to a large extent:<br />

Emil Fischer, Chem. 1902 (synthesis <str<strong>on</strong>g>of</str<strong>on</strong>g> sugars <strong>and</strong> other molecules)<br />

Alfred Werner, Chem. 1913 (coordinati<strong>on</strong> compounds; see Kauffman 1968)<br />

2. Discoveries where polarizati<strong>on</strong> played a c<strong>on</strong>siderable part:<br />

H.A. Lorentz <strong>and</strong> P. Zeeman, Phys. 1902 (Zeeman magneto-optic effect)<br />

J. Stark, Phys. 1919 (Stark electro-optic effect <strong>on</strong> spectra)<br />

C.V. Raman, Phys. 1930 (scattering <str<strong>on</strong>g>of</str<strong>on</strong>g> <strong>light</strong>, with change <str<strong>on</strong>g>of</str<strong>on</strong>g> wavelength).<br />

3. Discoveries where Nicol prisms or calcite crystals played some part:<br />

The X-ray diffracti<strong>on</strong> studies <str<strong>on</strong>g>of</str<strong>on</strong>g> the Braggs, Phys. 1915, M. Siegbahn, Phys. 1924, <strong>and</strong><br />

A.H. Compt<strong>on</strong>, Phys. 1927 employed calcite for accurate wavelength measurements. S.<br />

Arrhenius, Chem. 1903 <strong>and</strong> W. Ostwald, Chem. 1909, used polarimeters in some <str<strong>on</strong>g>of</str<strong>on</strong>g> their<br />

117

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