ca01 only detailed ToC 1..24

88
2.6.4.2.2 Variation 2: Two-Electron Oxidative Additions .......................... 114
2.6.4.3 Method 3: By Oxidative Addition of Alkanes and Arenes ............... 115
2.6.4.4 Method 4: By Protonation of Carbene and Carbyne Ligands ............ 116
Applications of Product Subclass 4 in Organic Synthesis .................... 116
2.6.4.5 Method 5: Addition of Organochromium(III) Compounds to
Carbonyl Compounds ..................................... 117
2.6.4.5.1 Variation 1: Reaction of Organochromium(III) Compounds Prepared
from Organochromium(III) Chloride by Transmetalation ..... 117
2.6.4.5.2 Variation 2: Reaction of Organochromium(III) Compounds Prepared
from Chromium(II) Chloride by Oxidative Addition
(The Nozaki–Hiyama–Kishi Procedure) ..................... 118
2.6.4.5.3 Variation 3: Catalytic Nozaki–Hiyama–Kishi Reaction
(The Fürstner Procedure) .................................. 119
2.6.4.6 Method 6: Additive–Reductive Carbonyl Dimerization ................. 119
2.6.5 Product Subclass 5: Metallacyclic Complexes ............................ 120
Synthesis of Product Subclass 5 ........................................... 121
2.6.5.1 Method 1: By Transmetalation ........................................ 121
2.6.5.2 Method 2: By Reductive Coupling of Alkenes .......................... 122
2.6.5.3 Method 3: By Addition of Alkenes to Carbene Complexes .............. 123
2.6.6 Product Subclass 6: Complexes with Triply Bonded
Heteroelement Ligands .................................................. 123
2.6.7 Product Subclass 7: Complexes with Doubly Bonded
Heteroelement Ligands .................................................. 124
Synthesis of Product Subclass 7 ........................................... 125
2.6.7.1 Method 1: From Complexes Containing Singly Bonded
Heteroelement Ligands ................................... 125
2.6.7.2 Method 2: From Other Complexes Containing Doubly Bonded
Heteroelement Ligands ................................... 126
2.6.7.3 Method 3: From Complexes Containing Triply Bonded
Heteroelement Ligands ................................... 127
2.6.7.4 Method 4: By Oxidative Processes .................................... 128
Applications of Product Subclass 7 in Organic Synthesis .................... 129
2.6.7.5 Method 5: Catalytic Epoxidation of Alkenes ........................... 129
2.6.8 Product Subclass 8: Complexes with Singly Bonded
Heteroelement Ligands .................................................. 130
Synthesis of Product Subclass 8 ........................................... 130
2.6.8.1 Method 1: By Oxidative Addition of Compounds with Single Bonds
between Heteroelements ................................. 130
2.6.8.2 Method 2: By Transmetalation ........................................ 131
2.6.8.3 Method 3: From ó-Alkyl Complexes ................................... 131
2.6.8.4 Method 4: From Carbene or Carbyne Complexes ...................... 132