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ca01 only detailed ToC 1..24

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5.1.22 Product Subclass 22: Aryl- and Heteroarylgermanes<br />

A. C. Spivey and C. M. Diaper<br />

5.1.22 Product Subclass 22: Aryl- and Heteroarylgermanes ..................... 168<br />

Synthesis of Product Subclass 22 .......................................... 170<br />

5.1.22.1 Method 1:From Halogermanes by Substitution with Arylmetals ............. 170<br />

5.1.22.1.1 Variation 1:Using Preformed Arylmetals ................................... 170<br />

5.1.22.1.2 Variation 2:Using Barbier-Type Reactions .................................. 171<br />

5.1.22.2 Method 2:From Aryl Halides by Palladium(0)-Mediated Coupling<br />

with Digermanes ......................................................... 171<br />

5.1.22.3 Method 3:From Aryl Halides by Insertion of Dichlorogermylene ............. 172<br />

5.1.22.4 Method 4:Heteroarylgermanes by Cycloaddition ........................... 173<br />

Applications of Product Subclass 22 in Organic Synthesis ................... 174<br />

5.1.22.5 Method 5:Arylgermanes as Linkers for Solid-Phase Synthesis ............... 174<br />

167

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