Detailed table of contents (pdf)

LXII Table of Contents
17.7.4.1.1.1.2 Method 2: Reaction of Cyclopenta[c]quinolizine with Dimethyl
Acetylenedicarboxylate ................................... 1058
17.7.4.1.2 Synthesis by Ring Transformation ......................................... 1059
17.7.4.1.2.1 Method 1: Using Diels–Alder Reaction of Acetylenedicarboxylate ..... 1059
17.7.4.1.3 Synthesis by Substituent Modification .................................... 1059
17.7.4.1.3.1 Substitution of Existing Substituents ...................................... 1059
17.7.4.1.3.1.1 Of Hydrogen ............................................................. 1059
17.7.4.1.3.1.1.1 Method 1: Nitration Using Copper(II) Nitrate ......................... 1059
17.7.4.1.3.1.2 Of Carbon Functionalities ................................................ 1060
17.7.4.1.3.1.2.1 Method 1: Thermolysis of a Pyrido[2,1,6- de]quinolizine-4,5dicarboxylate
............................................ 1060
17.7.4.1.3.1.2.2 Method 2: Decarboxylation of Dimethyl Cyclopenta[ij]pyrido[2,1,6-de]quinolizine-4,5-dicarboxylate
................. 1061
17.7.4.2 Aza- and Polyaza[3.3.3]cyclazines ........................................ 1061
17.7.4.2.1 Synthesis by Ring-Closure Reactions ...................................... 1062
17.7.4.2.1.1 By Formation of Three N—C Bonds ........................................ 1062
17.7.4.2.1.1.1 Method 1: By Using Ethoxymethylene Compounds ................... 1062
17.7.4.2.1.1.1.1 Variation 1: By Using Methoxymethylene Compounds ................. 1063
17.7.4.2.1.1.2 Method 2: By Condensation with Acid Anhydrides .................... 1064
17.7.4.2.1.2 By Formation of One N—C and Two C—C Bonds ............................ 1064
17.7.4.2.1.2.1 Method 1: By Using Ethoxymethylene Compounds ................... 1064
17.7.4.2.1.3 By Formation of One N—C and One C—C Bond ............................ 1065
17.7.4.2.1.3.1 Method 1: By Condensation with Acid Anhydrides .................... 1065
17.7.4.2.1.3.2 Method 2: By Condensation of a Dihydro-4H-quinolizin-4-imine with
an Acid Anhydride ....................................... 1066
17.7.4.2.1.4 By Formation of Two C—C Bonds ......................................... 1066
17.7.4.2.1.4.1 Method 1: Cycloaddition of Imino Compounds with Dimethyl
Acetylenedicarboxylate ................................... 1066
17.7.4.2.2 Synthesis by Ring Transformation ......................................... 1067
17.7.4.2.2.1 Method 1: Using Diels–Alder Reaction of Dimethyl
Acetylenedicarboxylate ................................... 1067
17.7.4.2.2.2 Method 2: By Dehydrogenation Using Palladium on Carbon ........... 1068
17.7.5 Product Subclass 5: [2.2.4]Cyclazines (Azepino[2,1,7-cd]pyrrolizines) ... 1069
17.7.5.1 Synthesis by Ring-Closure Reactions ...................................... 1069
17.7.5.1.1 By Formation of Two C—C Bonds ......................................... 1069
17.7.5.1.1.1 Method 1: Reaction of a Saturated Compound with a Perchlorate ..... 1069
17.7.5.1.2 Synthesis by Substituent Modification .................................... 1070
17.7.5.1.2.1 Substitution of Existing Substituents ...................................... 1070
17.7.5.1.2.1.1 Of Hydrogen ............................................................. 1070