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Detailed table of contents (pdf)
Detailed table of contents (pdf)
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L Table <strong>of</strong> Contents<br />
17.4.6.3.5 Addition Reactions ....................................................... 867<br />
17.4.6.3.5.1 Of Hydrogen .............................................................. 867<br />
17.4.6.3.5.1.1 Method 1: By Reduction <strong>of</strong> 3-Acetyl-3H-3-benzazepine ................ 867<br />
17.4.6.3.5.2 Of Organic Groups ........................................................ 867<br />
17.4.6.3.5.2.1 Method 1: Quaternization <strong>of</strong> 1H-3-Benzazepin-2-amine with<br />
Iodomethane ............................................. 867<br />
17.4.6.3.6 Modification <strong>of</strong> Substituents .............................................. 867<br />
17.4.6.3.6.1 Method 1: Acetylation <strong>of</strong> 4-Bromo-1H-3-benzazepin-2-amine .......... 867<br />
17.4.6.4 5H-Dibenz[b,d]azepines ................................................... 868<br />
17.4.6.4.1 Synthesis by Ring-Closure Reactions ....................................... 868<br />
17.4.6.4.1.1 Method 1: By Intramolecular Cyclization under Friedel–Crafts Conditions 868<br />
17.4.6.4.2 Aromatization ............................................................ 869<br />
17.4.6.4.2.1 Method 1: Manganese(IV) Oxide Oxidation <strong>of</strong> 5,6-Dihydro-7Hdibenz[b,d]azepin-7-ones<br />
.................................. 869<br />
17.4.6.4.2.1.1 Variation 1: Lead(IV) Acetate Oxidation <strong>of</strong> 5,6-Dihydro-7Hdibenz[b,d]azepin-7-ones<br />
.................................. 869<br />
17.4.6.4.3 Synthesis by Substituent Modification ..................................... 870<br />
17.4.6.5 11H-Dibenz[b,e]azepines .................................................. 870<br />
17.4.6.5.1 Synthesis by Ring-Closure Reactions ....................................... 871<br />
17.4.6.5.1.1 By Formation <strong>of</strong> One N—C and One C—C Bond ............................. 871<br />
17.4.6.5.1.1.1 Method 1: By the Thermal Decomposition <strong>of</strong> Diphenylmethane-2diazonium<br />
Tetrafluoroborates ............................. 871<br />
17.4.6.5.1.2 By Formation <strong>of</strong> One N—C Bond ........................................... 871<br />
17.4.6.5.1.2.1 Method 1: Reduction–Cyclodehydration <strong>of</strong> 2-(2-Nitrophenyl)benzophenones<br />
................................................. 871<br />
17.4.6.5.1.3 By Formation <strong>of</strong> One C—C Bond ........................................... 872<br />
17.4.6.5.1.3.1 Method 1: By Bischler–Napieralski Cyclodehydration .................. 872<br />
17.4.6.5.2 Synthesis by Ring Transformation .......................................... 872<br />
17.4.6.5.2.1 By Ring Enlargement ..................................................... 872<br />
17.4.6.5.2.1.1 Method 1: By Beckmann Rearrangement <strong>of</strong> 10H-Anthracen-9-one<br />
Oximes ................................................... 872<br />
17.4.6.5.2.1.2 Method 2: By the Schmidt Reaction <strong>of</strong> Anthraquinones ................ 873<br />
17.4.6.5.3 Aromatization ............................................................ 874<br />
17.4.6.5.3.1 Method 1: By Dehydrogenation <strong>of</strong> 1,4-Dimethyl-6,11-dihydro-5Hdibenz[b,e]azepine<br />
........................................ 874<br />
17.4.6.5.3.2 Method 2: From 6H-Dibenz[b,e]azepin-6-ones ......................... 875<br />
17.4.6.5.4 Synthesis by Substituent Modification ..................................... 875<br />
17.4.6.5.4.1 Substitution <strong>of</strong> Existing Substituents ....................................... 875<br />
17.4.6.5.4.1.1 Method 1: By Displacement <strong>of</strong> 2-Halo Substituents .................... 875
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