Detailed table of contents (pdf)

XLVIII Table of Contents
17.4.6.1.3.3 Method 3: By Chlorination–Dehydrochlorination of Phenyl-2,3,4,5tetrahydro-1H-benzazepin-2-ones
......................... 841
17.4.6.1.4 Synthesis by Substituent Modification ..................................... 843
17.4.6.1.4.1 Substitution of Existing Substituents ....................................... 843
17.4.6.1.4.1.1 Method 1: Bromination of 1H-1-Benzazepines ......................... 843
17.4.6.1.4.1.2 Method 2: Acetylation of 1H-1-Benzazepine ........................... 843
17.4.6.2 2-Benzazepines .......................................................... 844
17.4.6.2.1 Synthesis by Ring-Closure Reactions ....................................... 844
17.4.6.2.1.1 By Formation of One N—C and One C—C Bond ............................. 844
17.4.6.2.1.1.1 Method 1: From (Z)-3-(Tributylstannyl)allylamine and Aryl Bromides ... 844
17.4.6.2.1.1.2 Method 2: From 1,3-Monoazabisylides and Phthalaldehyde ............ 844
17.4.6.2.1.1.3 Method 3: From Cycloaddition of Inden-2-one and 2H-Azirines ......... 845
17.4.6.2.1.2 By Formation of One N—C Bond ........................................... 846
17.4.6.2.1.2.1 Method 1: By Partial Reduction of Acetylenic Benzophenones .......... 846
17.4.6.2.1.3 By Formation of One C—C Bond ........................................... 847
17.4.6.2.1.3.1 Method 1: By Photoisomerization of 3-Phenyl-2-[(Z)-2-phenylvinyl]-2Hazirene
................................................... 847
17.4.6.2.1.3.2 Method 2: By 1,7-Electrocyclization of Diene-Conjugated Nitrile Ylides . 847
17.4.6.2.2 Synthesis by Ring Transformation .......................................... 848
17.4.6.2.2.1 By Ring Enlargement ..................................................... 848
17.4.6.2.2.1.1 Method 1: Base-Mediated Ring Expansion of 1,4-Dihydro-4-(hydroxymethyl)[c]isoquinolines
................................... 848
17.4.6.2.2.1.2 Method 2: By Thermolysis of Dihydrocyclopropa[c]isoquinolines ....... 849
17.4.6.2.2.1.2.1 Variation 1: From 1,4-Dihydro-4-(hydroxymethyl)[c]isoquinolines and
Silver(I) Trifluoroacetate ................................... 850
17.4.6.2.2.1.3 Method 3: Deoxygenation of Nitroarenes ............................. 850
17.4.6.2.2.1.4 Method 4: Photolysis of Aryl Azides ................................... 851
17.4.6.2.3 Aromatization ............................................................ 852
17.4.6.2.3.1 Method 1: By syn-Dehydrobromination ............................... 852
17.4.6.2.4 Synthesis by Substituent Modification ..................................... 853
17.4.6.2.4.1 Substitution of Existing Substituents ....................................... 853
17.4.6.2.4.1.1 Of Hydrogen ............................................................. 853
17.4.6.2.4.1.1.1 Method 1: By an Oxygen Functionality ................................ 853
17.4.6.2.4.1.1.2 Method 2: By Tautomerism .......................................... 853
17.4.6.2.4.1.2 Of Heteroatoms .......................................................... 853
17.4.6.2.4.1.2.1 Method 1: Palladium(0)-Catalyzed Carboalkoxylation of 5-Bromo-
5H-2-benzazepines ........................................ 853
17.4.6.2.4.2 Addition Reactions ....................................................... 854
17.4.6.2.4.2.1 Of Hydrogen .......................................................... 854
17.4.6.2.4.2.2 Of Organic Groups ........................................................ 854